Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils

Toxic metal pollution in soil and the associated health risk is a global problem, with the majority of cases occurring in developing nations. The current work focuses on a contaminated site in Mexico which is used for recreational purposes. The contaminated site in Cerrito Blanco in San Luis Potosi,...

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Main Authors: Arnab Saha, Bhaskar Sen Gupta, Sandhya Patidar, Nadia Martínez-Villegas
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Chemistry Proceedings
Subjects:
Online Access:https://www.mdpi.com/2673-4583/10/1/59
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author Arnab Saha
Bhaskar Sen Gupta
Sandhya Patidar
Nadia Martínez-Villegas
author_facet Arnab Saha
Bhaskar Sen Gupta
Sandhya Patidar
Nadia Martínez-Villegas
author_sort Arnab Saha
collection DOAJ
description Toxic metal pollution in soil and the associated health risk is a global problem, with the majority of cases occurring in developing nations. The current work focuses on a contaminated site in Mexico which is used for recreational purposes. The contaminated site in Cerrito Blanco in San Luis Potosi, Mexico is close to an abandoned mining area surrounded by non-cultivated farmland. Analyses of topsoil samples indicated the presence of arsenic (As), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn). This work has estimated the potential harmful impacts of toxic metals by using the Contamination factor (<i>C<sub>f</sub></i>), Ecological risk factor (<i>E<sub>r</sub></i>), and Potential ecological risk index (<i>RI</i>) by Hakanson’s method. The results indicated that the soil contamination factors (<i>C<sub>f</sub></i>) of toxic metals were: As > Zn > Cu > Pb > Ni. It is concluded that Cu, Pb, and Zn have been found in the soil samples because of past mining activities. The highest contamination factor (<i>C<sub>f</sub></i>) of As (11.94 mg/kg) in the soil was in the extremely high contamination category. It is also believed that the As concentration in the soil was high because arsenic-contaminated water was regularly used to irrigate the land. The Ecological risk factors (<i>E<sub>r</sub></i>) for toxic metals were: As > Cu > Pb > Zn > Ni. In the surface soils of this region, As was a considerable ecological concern and contributed the most to potential ecological risk indices (<i>RI</i>). It is also acknowledged that various anthropogenic factors contributed significantly to the potential ecological risk index (<i>RI</i>). The spatial distribution of toxic metal contamination in the soil was also mapped using a Geographic Information System (GIS). This study concludes that a regular assessment is needed to estimate the risk level of toxic metal contamination in soil.
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spelling doaj.art-bc98d55e5a104dec87c93535778836012023-11-17T10:17:31ZengMDPI AGChemistry Proceedings2673-45832022-02-011015910.3390/IOCAG2022-12214Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the SoilsArnab Saha0Bhaskar Sen Gupta1Sandhya Patidar2Nadia Martínez-Villegas3Institute of Infrastructure and Environment, School of Energy, Geoscience, Infrastructure & Society, Heriot-Watt University, Edinburgh EH14 4AS, UKInstitute of Infrastructure and Environment, School of Energy, Geoscience, Infrastructure & Society, Heriot-Watt University, Edinburgh EH14 4AS, UKInstitute of Infrastructure and Environment, School of Energy, Geoscience, Infrastructure & Society, Heriot-Watt University, Edinburgh EH14 4AS, UKApplied Geosciences Department, IPICyT, San Luis Potosi 78216, MexicoToxic metal pollution in soil and the associated health risk is a global problem, with the majority of cases occurring in developing nations. The current work focuses on a contaminated site in Mexico which is used for recreational purposes. The contaminated site in Cerrito Blanco in San Luis Potosi, Mexico is close to an abandoned mining area surrounded by non-cultivated farmland. Analyses of topsoil samples indicated the presence of arsenic (As), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn). This work has estimated the potential harmful impacts of toxic metals by using the Contamination factor (<i>C<sub>f</sub></i>), Ecological risk factor (<i>E<sub>r</sub></i>), and Potential ecological risk index (<i>RI</i>) by Hakanson’s method. The results indicated that the soil contamination factors (<i>C<sub>f</sub></i>) of toxic metals were: As > Zn > Cu > Pb > Ni. It is concluded that Cu, Pb, and Zn have been found in the soil samples because of past mining activities. The highest contamination factor (<i>C<sub>f</sub></i>) of As (11.94 mg/kg) in the soil was in the extremely high contamination category. It is also believed that the As concentration in the soil was high because arsenic-contaminated water was regularly used to irrigate the land. The Ecological risk factors (<i>E<sub>r</sub></i>) for toxic metals were: As > Cu > Pb > Zn > Ni. In the surface soils of this region, As was a considerable ecological concern and contributed the most to potential ecological risk indices (<i>RI</i>). It is also acknowledged that various anthropogenic factors contributed significantly to the potential ecological risk index (<i>RI</i>). The spatial distribution of toxic metal contamination in the soil was also mapped using a Geographic Information System (GIS). This study concludes that a regular assessment is needed to estimate the risk level of toxic metal contamination in soil.https://www.mdpi.com/2673-4583/10/1/59toxic metalssoil contaminationpotential ecological risk index (<i>RI</i>)GISSan Luis Potosi
spellingShingle Arnab Saha
Bhaskar Sen Gupta
Sandhya Patidar
Nadia Martínez-Villegas
Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils
Chemistry Proceedings
toxic metals
soil contamination
potential ecological risk index (<i>RI</i>)
GIS
San Luis Potosi
title Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils
title_full Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils
title_fullStr Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils
title_full_unstemmed Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils
title_short Evaluation of Potential Ecological Risk Index of Toxic Metals Contamination in the Soils
title_sort evaluation of potential ecological risk index of toxic metals contamination in the soils
topic toxic metals
soil contamination
potential ecological risk index (<i>RI</i>)
GIS
San Luis Potosi
url https://www.mdpi.com/2673-4583/10/1/59
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AT bhaskarsengupta evaluationofpotentialecologicalriskindexoftoxicmetalscontaminationinthesoils
AT sandhyapatidar evaluationofpotentialecologicalriskindexoftoxicmetalscontaminationinthesoils
AT nadiamartinezvillegas evaluationofpotentialecologicalriskindexoftoxicmetalscontaminationinthesoils