Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions
The review presents recent examples of heterogenic catalysts based on porphyrins and phthalocyanines loaded on mesoporous materials, such as MCM-41, SBA-15, MCM-48, SBA-16 or Al-MCM-41. Heterogenic approach to catalysis eases recovery, reuse and prevent macrocycle aggregation. In this application, m...
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MDPI AG
2022-03-01
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| Online Access: | https://www.mdpi.com/1996-1944/15/7/2532 |
| _version_ | 1797438612141244416 |
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| author | Joanna Szymczak Michal Kryjewski |
| author_facet | Joanna Szymczak Michal Kryjewski |
| author_sort | Joanna Szymczak |
| collection | DOAJ |
| description | The review presents recent examples of heterogenic catalysts based on porphyrins and phthalocyanines loaded on mesoporous materials, such as MCM-41, SBA-15, MCM-48, SBA-16 or Al-MCM-41. Heterogenic approach to catalysis eases recovery, reuse and prevent macrocycle aggregation. In this application, mesoporous silica is a promising candidate for anchoring macrocycle and obtaining a new catalyst. Introduction of porphyrin or phthalocyanine into the mesoporous material may be performed through adsorption of the macrocycle, or by its in situ formation—by reaction of substrates introduced to the pores of the catalytic material. Catalytic reactions studied are oxidation processes, focused on alkane, alkene or arene as substrates. The products obtained are usually epoxides, alcohols, ketones, aldehydes or acids. The greatest interest lies in oxidation of cyclohexane and cyclohexene, as a source of adypic acid and derivatives. Some of the reactions may be viewed as biomimetic processes, resembling processes that occur in vivo and are catalyzed by cytochrome P450 enzyme family. |
| first_indexed | 2024-03-09T11:40:34Z |
| format | Article |
| id | doaj.art-bce85d7bc6a84f57aedc7c785bd8ccdb |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-09T11:40:34Z |
| publishDate | 2022-03-01 |
| publisher | MDPI AG |
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| series | Materials |
| spelling | doaj.art-bce85d7bc6a84f57aedc7c785bd8ccdb2023-11-30T23:33:26ZengMDPI AGMaterials1996-19442022-03-01157253210.3390/ma15072532Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation ReactionsJoanna Szymczak0Michal Kryjewski1Chair and Department of Inorganic and Analytical Chemistry, Poznan University of Medical Sciences, Rokietnicka 3, 60-806 Poznan, PolandChair and Department of Inorganic and Analytical Chemistry, Poznan University of Medical Sciences, Rokietnicka 3, 60-806 Poznan, PolandThe review presents recent examples of heterogenic catalysts based on porphyrins and phthalocyanines loaded on mesoporous materials, such as MCM-41, SBA-15, MCM-48, SBA-16 or Al-MCM-41. Heterogenic approach to catalysis eases recovery, reuse and prevent macrocycle aggregation. In this application, mesoporous silica is a promising candidate for anchoring macrocycle and obtaining a new catalyst. Introduction of porphyrin or phthalocyanine into the mesoporous material may be performed through adsorption of the macrocycle, or by its in situ formation—by reaction of substrates introduced to the pores of the catalytic material. Catalytic reactions studied are oxidation processes, focused on alkane, alkene or arene as substrates. The products obtained are usually epoxides, alcohols, ketones, aldehydes or acids. The greatest interest lies in oxidation of cyclohexane and cyclohexene, as a source of adypic acid and derivatives. Some of the reactions may be viewed as biomimetic processes, resembling processes that occur in vivo and are catalyzed by cytochrome P450 enzyme family.https://www.mdpi.com/1996-1944/15/7/2532catalysismesoporous silicaoxidationphthalocyanineporphyrin |
| spellingShingle | Joanna Szymczak Michal Kryjewski Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions Materials catalysis mesoporous silica oxidation phthalocyanine porphyrin |
| title | Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions |
| title_full | Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions |
| title_fullStr | Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions |
| title_full_unstemmed | Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions |
| title_short | Porphyrins and Phthalocyanines on Solid-State Mesoporous Matrices as Catalysts in Oxidation Reactions |
| title_sort | porphyrins and phthalocyanines on solid state mesoporous matrices as catalysts in oxidation reactions |
| topic | catalysis mesoporous silica oxidation phthalocyanine porphyrin |
| url | https://www.mdpi.com/1996-1944/15/7/2532 |
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