Determination of solubility of chlorides of d-elements in chloroaluminate melts
Solubility of several transition metal chlorides (NiCl2, CrCl2, MoCl3, FeCl2) was measured in KCl-AlCl3 based melts. It was found that the solubility of studied metal chlorides depends on K : Al mole ratio. MoCl3 solubility decreases with increasing AlCl3 content. Solubility of CrCl2 and FeCl2 reach...
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| Format: | Article |
| Language: | English |
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Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
2014-09-01
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| Series: | Chimica Techno Acta |
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| Online Access: | https://chimicatechnoacta.ru/article/view/699 |
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| author | V. V. Karpov V. A. Volkovich I. B. Polovov O. I. Rebrin |
| author_facet | V. V. Karpov V. A. Volkovich I. B. Polovov O. I. Rebrin |
| author_sort | V. V. Karpov |
| collection | DOAJ |
| description | Solubility of several transition metal chlorides (NiCl2, CrCl2, MoCl3, FeCl2) was measured in KCl-AlCl3 based melts. It was found that the solubility of studied metal chlorides depends on K : Al mole ratio. MoCl3 solubility decreases with increasing AlCl3 content. Solubility of CrCl2 and FeCl2 reaches maximum at K : Al ratio of 1 and decreases when this ratio either de-creases or increases. The dependence of NiCl2 solubility on K : Al mole ratio is V-shaped with the maximum near 0.9-0.95. The effect of temperature on solubility of transition metal chlorides in KCl-AlCl3 melts was also investigated. Increasing temperature does not alter the character of «solubility – K : Al mole ratio» dependences. |
| first_indexed | 2024-12-21T23:34:26Z |
| format | Article |
| id | doaj.art-bcf699aed2f249a3b4ec18f5c70d6daa |
| institution | Directory Open Access Journal |
| issn | 2411-1414 |
| language | English |
| last_indexed | 2025-02-17T13:53:29Z |
| publishDate | 2014-09-01 |
| publisher | Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina |
| record_format | Article |
| series | Chimica Techno Acta |
| spelling | doaj.art-bcf699aed2f249a3b4ec18f5c70d6daa2024-12-25T09:36:53ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142014-09-0112566010.15826/chimtech.2014.1.2.6991013Determination of solubility of chlorides of d-elements in chloroaluminate meltsV. V. Karpov0V. A. Volkovich1I. B. Polovov2O. I. Rebrin3Уральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургSolubility of several transition metal chlorides (NiCl2, CrCl2, MoCl3, FeCl2) was measured in KCl-AlCl3 based melts. It was found that the solubility of studied metal chlorides depends on K : Al mole ratio. MoCl3 solubility decreases with increasing AlCl3 content. Solubility of CrCl2 and FeCl2 reaches maximum at K : Al ratio of 1 and decreases when this ratio either de-creases or increases. The dependence of NiCl2 solubility on K : Al mole ratio is V-shaped with the maximum near 0.9-0.95. The effect of temperature on solubility of transition metal chlorides in KCl-AlCl3 melts was also investigated. Increasing temperature does not alter the character of «solubility – K : Al mole ratio» dependences.https://chimicatechnoacta.ru/article/view/699хлоралюминатные расплавыхлорид никеляхлорид хромахлорид железа |
| spellingShingle | V. V. Karpov V. A. Volkovich I. B. Polovov O. I. Rebrin Determination of solubility of chlorides of d-elements in chloroaluminate melts Chimica Techno Acta хлоралюминатные расплавы хлорид никеля хлорид хрома хлорид железа |
| title | Determination of solubility of chlorides of d-elements in chloroaluminate melts |
| title_full | Determination of solubility of chlorides of d-elements in chloroaluminate melts |
| title_fullStr | Determination of solubility of chlorides of d-elements in chloroaluminate melts |
| title_full_unstemmed | Determination of solubility of chlorides of d-elements in chloroaluminate melts |
| title_short | Determination of solubility of chlorides of d-elements in chloroaluminate melts |
| title_sort | determination of solubility of chlorides of d elements in chloroaluminate melts |
| topic | хлоралюминатные расплавы хлорид никеля хлорид хрома хлорид железа |
| url | https://chimicatechnoacta.ru/article/view/699 |
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