Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor
In this article, hierarchical porous carbon (HPC) with high surface area of 1604.9 m<sup>2</sup>/g is prepared by the pyrolysis of rubberwood sawdust using CaCO<sub>3</sub> as a hard template. The bio-oil pyrolyzed from the rubber sawdust, followed by the polymerization react...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-01-01
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| Series: | Polymers |
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| Online Access: | https://www.mdpi.com/2073-4360/14/3/575 |
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| author | Er-Chieh Cho Cai-Wan Chang-Jian Cheng-Zhang Lu Jen-Hsien Huang Tzu-Hsien Hsieh Nian-Jheng Wu Kuen-Chan Lee Shih-Chieh Hsu Huei Chu Weng |
| author_facet | Er-Chieh Cho Cai-Wan Chang-Jian Cheng-Zhang Lu Jen-Hsien Huang Tzu-Hsien Hsieh Nian-Jheng Wu Kuen-Chan Lee Shih-Chieh Hsu Huei Chu Weng |
| author_sort | Er-Chieh Cho |
| collection | DOAJ |
| description | In this article, hierarchical porous carbon (HPC) with high surface area of 1604.9 m<sup>2</sup>/g is prepared by the pyrolysis of rubberwood sawdust using CaCO<sub>3</sub> as a hard template. The bio-oil pyrolyzed from the rubber sawdust, followed by the polymerization reaction to form resole phenolic resin, can be used as a carbon source to prepare HPC. The biomass-derived HPC shows a three-dimensionally interconnected morphology which can offer a continuous pathway for ionic transport. The symmetrical supercapacitors based on the as-prepared HPC were tested in 1.0 M tetraethylammonium tetrafluoroborate/propylene carbonate electrolyte. The results of electrochemical analysis show that the HPC-based supercapacitor exhibits a high specific capacitance of 113.3 F/g at 0.5 A/g with superior rate capability and cycling stability up to 5000 cycles. Hybrid lithium-ion capacitors (LICs) based on the HPC and Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> (LTO) were also fabricated. The LICs have a maximum energy density of 113.3 Wh/kg at a power density of 281 W/kg. Moreover, the LIC also displays a remarkable cycling performance with a retention of 92.8% after 3000 cycles at a large current density of 0.75 A/g, suggesting great potential application in the energy storage of the LIC. |
| first_indexed | 2024-03-09T23:15:56Z |
| format | Article |
| id | doaj.art-bcff796a63944a79a03f139b52b10589 |
| institution | Directory Open Access Journal |
| issn | 2073-4360 |
| language | English |
| last_indexed | 2024-03-09T23:15:56Z |
| publishDate | 2022-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Polymers |
| spelling | doaj.art-bcff796a63944a79a03f139b52b105892023-11-23T17:36:08ZengMDPI AGPolymers2073-43602022-01-0114357510.3390/polym14030575Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion CapacitorEr-Chieh Cho0Cai-Wan Chang-Jian1Cheng-Zhang Lu2Jen-Hsien Huang3Tzu-Hsien Hsieh4Nian-Jheng Wu5Kuen-Chan Lee6Shih-Chieh Hsu7Huei Chu Weng8Department of Clinical Pharmacy, School of Pharmacy, College of Pharmacy, Taipei Medical University, 250 Wuxing Street, Taipei City 110, TaiwanDepartment of Mechanical and Automation Engineering, I-Shou University, No. 1, Sec. 1, Syuecheng Rd., Dashu District, Kaohsiung City 84001, TaiwanMaterial and Chemical Research Laboratories, Industrial Technology Research Institute, No. 195, Chung Hsing Road, Chutung, Hsinchu 31040, TaiwanDepartment of Green Material Technology, Green Technology Research Institute, CPC Corporation, No. 2, Zuonan Rd., Nanzi District, Kaohsiung City 81126, TaiwanDepartment of Green Material Technology, Green Technology Research Institute, CPC Corporation, No. 2, Zuonan Rd., Nanzi District, Kaohsiung City 81126, TaiwanCNRS, Institut des Sciences Moléculaires d’Orsay, Université Paris-Saclay, 91405 Orsay, FranceDepartment of Science Education, National Taipei University of Education, No. 134, Sec. 2, Heping E. Rd., Da-an District, Taipei City 106, TaiwanDepartment of Chemical and Materials Engineering, Tamkang University, No. 151, Yingzhuan Road, Tamsui District, New Taipei City 25137, TaiwanDepartment of Mechanical Engineering, Chung Yuan Christian University, No. 200, Chungpei Road, Chungli District, Taoyuan City 32023, TaiwanIn this article, hierarchical porous carbon (HPC) with high surface area of 1604.9 m<sup>2</sup>/g is prepared by the pyrolysis of rubberwood sawdust using CaCO<sub>3</sub> as a hard template. The bio-oil pyrolyzed from the rubber sawdust, followed by the polymerization reaction to form resole phenolic resin, can be used as a carbon source to prepare HPC. The biomass-derived HPC shows a three-dimensionally interconnected morphology which can offer a continuous pathway for ionic transport. The symmetrical supercapacitors based on the as-prepared HPC were tested in 1.0 M tetraethylammonium tetrafluoroborate/propylene carbonate electrolyte. The results of electrochemical analysis show that the HPC-based supercapacitor exhibits a high specific capacitance of 113.3 F/g at 0.5 A/g with superior rate capability and cycling stability up to 5000 cycles. Hybrid lithium-ion capacitors (LICs) based on the HPC and Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> (LTO) were also fabricated. The LICs have a maximum energy density of 113.3 Wh/kg at a power density of 281 W/kg. Moreover, the LIC also displays a remarkable cycling performance with a retention of 92.8% after 3000 cycles at a large current density of 0.75 A/g, suggesting great potential application in the energy storage of the LIC.https://www.mdpi.com/2073-4360/14/3/575biomassporous carbonLi<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub>supercapacitorlithium-ion battery |
| spellingShingle | Er-Chieh Cho Cai-Wan Chang-Jian Cheng-Zhang Lu Jen-Hsien Huang Tzu-Hsien Hsieh Nian-Jheng Wu Kuen-Chan Lee Shih-Chieh Hsu Huei Chu Weng Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor Polymers biomass porous carbon Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> supercapacitor lithium-ion battery |
| title | Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor |
| title_full | Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor |
| title_fullStr | Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor |
| title_full_unstemmed | Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor |
| title_short | Bio-Phenolic Resin Derived Porous Carbon Materials for High-Performance Lithium-Ion Capacitor |
| title_sort | bio phenolic resin derived porous carbon materials for high performance lithium ion capacitor |
| topic | biomass porous carbon Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> supercapacitor lithium-ion battery |
| url | https://www.mdpi.com/2073-4360/14/3/575 |
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