Cross-Coupling Reaction with Lithium Methyltriolborate
We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [Me...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-12-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/18/1/430 |
| _version_ | 1818692395026350080 |
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| author | Norio Miyaura Hajime Ito Yasunori Yamamoto Kazuya Ikizakura |
| author_facet | Norio Miyaura Hajime Ito Yasunori Yamamoto Kazuya Ikizakura |
| author_sort | Norio Miyaura |
| collection | DOAJ |
| description | We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)3CCH3]Li with aryl halides occurred in the presence of Pd(OAc)2/RuPhos complex in refluxing MeOH/H2O and the absence of bases. |
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| format | Article |
| id | doaj.art-bd1fe0ad24144a6e841b3e020fb3d271 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-17T12:57:06Z |
| publishDate | 2012-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-bd1fe0ad24144a6e841b3e020fb3d2712022-12-21T21:47:27ZengMDPI AGMolecules1420-30492012-12-0118143043910.3390/molecules18010430Cross-Coupling Reaction with Lithium MethyltriolborateNorio MiyauraHajime ItoYasunori YamamotoKazuya IkizakuraWe newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)3CCH3]Li with aryl halides occurred in the presence of Pd(OAc)2/RuPhos complex in refluxing MeOH/H2O and the absence of bases.http://www.mdpi.com/1420-3049/18/1/430cross-coupling reactionpalladium catalystmethyltrioolborate |
| spellingShingle | Norio Miyaura Hajime Ito Yasunori Yamamoto Kazuya Ikizakura Cross-Coupling Reaction with Lithium Methyltriolborate Molecules cross-coupling reaction palladium catalyst methyltrioolborate |
| title | Cross-Coupling Reaction with Lithium Methyltriolborate |
| title_full | Cross-Coupling Reaction with Lithium Methyltriolborate |
| title_fullStr | Cross-Coupling Reaction with Lithium Methyltriolborate |
| title_full_unstemmed | Cross-Coupling Reaction with Lithium Methyltriolborate |
| title_short | Cross-Coupling Reaction with Lithium Methyltriolborate |
| title_sort | cross coupling reaction with lithium methyltriolborate |
| topic | cross-coupling reaction palladium catalyst methyltrioolborate |
| url | http://www.mdpi.com/1420-3049/18/1/430 |
| work_keys_str_mv | AT noriomiyaura crosscouplingreactionwithlithiummethyltriolborate AT hajimeito crosscouplingreactionwithlithiummethyltriolborate AT yasunoriyamamoto crosscouplingreactionwithlithiummethyltriolborate AT kazuyaikizakura crosscouplingreactionwithlithiummethyltriolborate |