In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance

A quartz crystal microbalance (QCM) was utilized to measure the water content in ethanol. For the improvement of measurement sensitivity, the QCM was modified by applying zeolite particles on the surface with poly(methyl methacrylate) (PMMA) binder. The measurement performance was examined with etha...

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Main Authors: Byoung Chul Kim, Takuji Yamamoto, Young Han Kim
Format: Article
Language:English
Published: MDPI AG 2015-10-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/15/10/27273
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author Byoung Chul Kim
Takuji Yamamoto
Young Han Kim
author_facet Byoung Chul Kim
Takuji Yamamoto
Young Han Kim
author_sort Byoung Chul Kim
collection DOAJ
description A quartz crystal microbalance (QCM) was utilized to measure the water content in ethanol. For the improvement of measurement sensitivity, the QCM was modified by applying zeolite particles on the surface with poly(methyl methacrylate) (PMMA) binder. The measurement performance was examined with ethanol of 1% to 5% water content in circulation. The experimental results showed that the frequency drop of the QCM was related with the water content though there was some deviation. The sensitivity of the zeolite-coated QCM was sufficient to be implemented in water content determination, and a higher ratio of silicon to aluminum in the molecular structure of the zeolite gave better performance. The coated surface was inspected by microscopy to show the distribution of zeolite particles and PMMA spread.
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spelling doaj.art-bd24002042c14f83a5119860ba9c887e2022-12-22T01:56:17ZengMDPI AGSensors1424-82202015-10-011510272732728210.3390/s151027273s151027273In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal MicrobalanceByoung Chul Kim0Takuji Yamamoto1Young Han Kim2Department of Advanced Materials and Chemical Engineering, Kyungnam College of Information & Technology, Pusan 617-701, KoreaDepartment of Chemical Engineering, University of Hyogo, Himeji 671-2201, JapanDepartment of Chemical Engineering, Dong-A University, Pusan 604-714, KoreaA quartz crystal microbalance (QCM) was utilized to measure the water content in ethanol. For the improvement of measurement sensitivity, the QCM was modified by applying zeolite particles on the surface with poly(methyl methacrylate) (PMMA) binder. The measurement performance was examined with ethanol of 1% to 5% water content in circulation. The experimental results showed that the frequency drop of the QCM was related with the water content though there was some deviation. The sensitivity of the zeolite-coated QCM was sufficient to be implemented in water content determination, and a higher ratio of silicon to aluminum in the molecular structure of the zeolite gave better performance. The coated surface was inspected by microscopy to show the distribution of zeolite particles and PMMA spread.http://www.mdpi.com/1424-8220/15/10/27273quartz crystal microbalanceethanol dehydrationzeolite-coated sensor
spellingShingle Byoung Chul Kim
Takuji Yamamoto
Young Han Kim
In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance
Sensors
quartz crystal microbalance
ethanol dehydration
zeolite-coated sensor
title In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance
title_full In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance
title_fullStr In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance
title_full_unstemmed In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance
title_short In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance
title_sort in line measurement of water contents in ethanol using a zeolite coated quartz crystal microbalance
topic quartz crystal microbalance
ethanol dehydration
zeolite-coated sensor
url http://www.mdpi.com/1424-8220/15/10/27273
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