Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys

The Cu-Ti-Si alloys containing in-situ formed Ti5Si3 are prepared. In order to clarify the Ti5Si3 formation processes and its microstructure characteristics, the as-cast and deeply etched Cu-Ti-Si alloys with different compositions and cooling rates were investigated using scanning electron microsco...

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Main Authors: Qing Liu, Xiao-cui Zhang, Qiang Wang
Format: Article
Language:English
Published: Foundry Journal Agency 2020-07-01
Series:China Foundry
Subjects:
Online Access:https://link.springer.com/article/10.1007/s41230-020-9140-4
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author Qing Liu
Xiao-cui Zhang
Qiang Wang
author_facet Qing Liu
Xiao-cui Zhang
Qiang Wang
author_sort Qing Liu
collection DOAJ
description The Cu-Ti-Si alloys containing in-situ formed Ti5Si3 are prepared. In order to clarify the Ti5Si3 formation processes and its microstructure characteristics, the as-cast and deeply etched Cu-Ti-Si alloys with different compositions and cooling rates were investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). It is found that the eutectic Ti5Si3 phases in Cu-Ti-Si alloys are rod-like with hexagonal cross section which tend to intertwine with each other to form a firm skeleton like a bird nest structure which can make the alloys keep their original shape even after etching off the Cu matrix. In addition, there is Cu in the center of many Ti5Si3 rods, resulting in a core-shell structure. With the increase of the cooling rate, Ti5Si3 distributes more uniformly, and the diameter of Ti5Si3 significantly decreases, with a minimum size of less than 100 nm, while the aspect ratio of Ti5Si3 increases.
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spelling doaj.art-bd26de1190ea41a4a0324a65b2e2dee22022-12-22T01:47:35ZengFoundry Journal AgencyChina Foundry1672-64211672-64212020-07-0117428629210.1007/s41230-020-9140-4Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloysQing Liu0Xiao-cui Zhang1Qiang Wang2School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, ChinaState Grid Shandong Electric Power Maintenance Company, Jinan 250021, ChinaSchool of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, ChinaThe Cu-Ti-Si alloys containing in-situ formed Ti5Si3 are prepared. In order to clarify the Ti5Si3 formation processes and its microstructure characteristics, the as-cast and deeply etched Cu-Ti-Si alloys with different compositions and cooling rates were investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). It is found that the eutectic Ti5Si3 phases in Cu-Ti-Si alloys are rod-like with hexagonal cross section which tend to intertwine with each other to form a firm skeleton like a bird nest structure which can make the alloys keep their original shape even after etching off the Cu matrix. In addition, there is Cu in the center of many Ti5Si3 rods, resulting in a core-shell structure. With the increase of the cooling rate, Ti5Si3 distributes more uniformly, and the diameter of Ti5Si3 significantly decreases, with a minimum size of less than 100 nm, while the aspect ratio of Ti5Si3 increases.https://link.springer.com/article/10.1007/s41230-020-9140-4microstructures; cu alloys; ti5si3; intermetallic compounds
spellingShingle Qing Liu
Xiao-cui Zhang
Qiang Wang
Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys
China Foundry
microstructures; cu alloys; ti5si3; intermetallic compounds
title Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys
title_full Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys
title_fullStr Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys
title_full_unstemmed Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys
title_short Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys
title_sort microstructure evolution of ti5si3 in cu ti si alloys
topic microstructures; cu alloys; ti5si3; intermetallic compounds
url https://link.springer.com/article/10.1007/s41230-020-9140-4
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AT xiaocuizhang microstructureevolutionofti5si3incutisialloys
AT qiangwang microstructureevolutionofti5si3incutisialloys