Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications

Despite great success in generation of ultralong organic phosphorescence (UOP) by suppressing non-radiative transitions through attractive interactions, consideration of repulsive interactions on UOP remains largely unexplored. Here, the authors introduce carboxyl groups into organic phosphors, enab...

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Main Authors: Xiaokang Yao, Huili Ma, Xiao Wang, He Wang, Qian Wang, Xin Zou, Zhicheng Song, Wenyong Jia, Yuxin Li, Yufeng Mao, Manjeet Singh, Wenpeng Ye, Jian Liang, Yanyun Zhang, Zhuang Liu, Yixiao He, Jingjie Li, Zixing Zhou, Zhu Zhao, Yuan Zhang, Guowei Niu, Chengzhu Yin, Shasha Zhang, Huifang Shi, Wei Huang, Zhongfu An
Format: Article
Language:English
Published: Nature Portfolio 2022-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-32029-1
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author Xiaokang Yao
Huili Ma
Xiao Wang
He Wang
Qian Wang
Xin Zou
Zhicheng Song
Wenyong Jia
Yuxin Li
Yufeng Mao
Manjeet Singh
Wenpeng Ye
Jian Liang
Yanyun Zhang
Zhuang Liu
Yixiao He
Jingjie Li
Zixing Zhou
Zhu Zhao
Yuan Zhang
Guowei Niu
Chengzhu Yin
Shasha Zhang
Huifang Shi
Wei Huang
Zhongfu An
author_facet Xiaokang Yao
Huili Ma
Xiao Wang
He Wang
Qian Wang
Xin Zou
Zhicheng Song
Wenyong Jia
Yuxin Li
Yufeng Mao
Manjeet Singh
Wenpeng Ye
Jian Liang
Yanyun Zhang
Zhuang Liu
Yixiao He
Jingjie Li
Zixing Zhou
Zhu Zhao
Yuan Zhang
Guowei Niu
Chengzhu Yin
Shasha Zhang
Huifang Shi
Wei Huang
Zhongfu An
author_sort Xiaokang Yao
collection DOAJ
description Despite great success in generation of ultralong organic phosphorescence (UOP) by suppressing non-radiative transitions through attractive interactions, consideration of repulsive interactions on UOP remains largely unexplored. Here, the authors introduce carboxyl groups into organic phosphors, enabling formation of the intense repulsive interactions between the isolated molecules and the matrix in rigid environment.
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spelling doaj.art-bd4ed5936d444e2a881265f87b8cd62d2022-12-22T01:26:31ZengNature PortfolioNature Communications2041-17232022-08-011311810.1038/s41467-022-32029-1Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applicationsXiaokang Yao0Huili Ma1Xiao Wang2He Wang3Qian Wang4Xin Zou5Zhicheng Song6Wenyong Jia7Yuxin Li8Yufeng Mao9Manjeet Singh10Wenpeng Ye11Jian Liang12Yanyun Zhang13Zhuang Liu14Yixiao He15Jingjie Li16Zixing Zhou17Zhu Zhao18Yuan Zhang19Guowei Niu20Chengzhu Yin21Shasha Zhang22Huifang Shi23Wei Huang24Zhongfu An25Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityFrontiers Science Center for Flexible Electronics, MIIT Key Laboratory of Flexible Electronics, Northwestern Polytechnical UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityKey Laboratory of Flexible Electronics & Institute of Advanced Materials, Nanjing Tech UniversityDespite great success in generation of ultralong organic phosphorescence (UOP) by suppressing non-radiative transitions through attractive interactions, consideration of repulsive interactions on UOP remains largely unexplored. Here, the authors introduce carboxyl groups into organic phosphors, enabling formation of the intense repulsive interactions between the isolated molecules and the matrix in rigid environment.https://doi.org/10.1038/s41467-022-32029-1
spellingShingle Xiaokang Yao
Huili Ma
Xiao Wang
He Wang
Qian Wang
Xin Zou
Zhicheng Song
Wenyong Jia
Yuxin Li
Yufeng Mao
Manjeet Singh
Wenpeng Ye
Jian Liang
Yanyun Zhang
Zhuang Liu
Yixiao He
Jingjie Li
Zixing Zhou
Zhu Zhao
Yuan Zhang
Guowei Niu
Chengzhu Yin
Shasha Zhang
Huifang Shi
Wei Huang
Zhongfu An
Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
Nature Communications
title Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
title_full Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
title_fullStr Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
title_full_unstemmed Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
title_short Ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
title_sort ultralong organic phosphorescence from isolated molecules with repulsive interactions for multifunctional applications
url https://doi.org/10.1038/s41467-022-32029-1
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