Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling

Hydrodynamic hysteresis exists widely in agglomerated heaps with well-developed intra-pores, and it directly affects solute transports and bioleaching reaction. In this paper, the dynamic liquid retention behavior under different heap porosity and irrigation condition is quantified via a novel real-...

Full description

Bibliographic Details
Main Authors: Leiming Wang, Shenghua Yin, Xuelan Zhang, Zepeng Yan, Wensheng Liao
Format: Article
Language:English
Published: MDPI AG 2022-12-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/12/12/1623
_version_ 1797456172933971968
author Leiming Wang
Shenghua Yin
Xuelan Zhang
Zepeng Yan
Wensheng Liao
author_facet Leiming Wang
Shenghua Yin
Xuelan Zhang
Zepeng Yan
Wensheng Liao
author_sort Leiming Wang
collection DOAJ
description Hydrodynamic hysteresis exists widely in agglomerated heaps with well-developed intra-pores, and it directly affects solute transports and bioleaching reaction. In this paper, the dynamic liquid retention behavior under different heap porosity and irrigation condition is quantified via a novel real-time, in-situ liquid retention characterizing system (RILRCS), and the potential effects of initial liquid retention on solute transport and leaching reaction are carefully discussed. The results show that the immobile liquid is dominant in agglomerated heaps. The ratio of immobile and mobile liquid (<i>η</i>) dynamically changes due to mineral dissolution and new flow path appearances. The <i>η</i> normally increases and mobile liquid occupies a higher proportion due to acidic leaching reactions, especially at a smaller <i>R<sub>g</sub></i> (10.32 mm) and a larger <i>u</i> (0.10 mm/s). The dynamic liquid retention is more sensitive to the diameter of packed feeds (<i>R<sub>g</sub></i>) and superficial flow rate (<i>u</i>) instead of leaching reactions. This might be because the damage of leaching reaction on minerals pores/voids is limited and cannot extensively change the potential pore channels or fluid flow paths. Based on pulse tracing and conductivity tests, we reveal that the solute resides longer under a slower <i>u</i> and smaller packed <i>R<sub>g</sub></i> condition, which corresponds well with desirable copper leaching efficiency. Specifically, the liquid hysteresis behavior is more obvious at a lower <i>u</i> (0.01 mm/s) and smaller <i>R<sub>g</sub></i> (10.32 mm). This paper gives a good reference to ascertain the liquid retention and hydrodynamic hysteresis and promote mineral leaching performance.
first_indexed 2024-03-09T16:03:35Z
format Article
id doaj.art-bd58003c4def4faebc8aa92bb5643a85
institution Directory Open Access Journal
issn 2075-163X
language English
last_indexed 2024-03-09T16:03:35Z
publishDate 2022-12-01
publisher MDPI AG
record_format Article
series Minerals
spelling doaj.art-bd58003c4def4faebc8aa92bb5643a852023-11-24T16:52:58ZengMDPI AGMinerals2075-163X2022-12-011212162310.3390/min12121623Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching ControllingLeiming Wang0Shenghua Yin1Xuelan Zhang2Zepeng Yan3Wensheng Liao4Key Laboratory of Ministry of Education for High-Efficient Mining and Safety of Metal, University of Science and Technology Beijing, Beijing 100083, ChinaKey Laboratory of Ministry of Education for High-Efficient Mining and Safety of Metal, University of Science and Technology Beijing, Beijing 100083, ChinaSchool of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083, ChinaKey Laboratory of Ministry of Education for High-Efficient Mining and Safety of Metal, University of Science and Technology Beijing, Beijing 100083, ChinaBeijing Research Institute of Chemical Engineering Metallurgy, Beijing 101149, ChinaHydrodynamic hysteresis exists widely in agglomerated heaps with well-developed intra-pores, and it directly affects solute transports and bioleaching reaction. In this paper, the dynamic liquid retention behavior under different heap porosity and irrigation condition is quantified via a novel real-time, in-situ liquid retention characterizing system (RILRCS), and the potential effects of initial liquid retention on solute transport and leaching reaction are carefully discussed. The results show that the immobile liquid is dominant in agglomerated heaps. The ratio of immobile and mobile liquid (<i>η</i>) dynamically changes due to mineral dissolution and new flow path appearances. The <i>η</i> normally increases and mobile liquid occupies a higher proportion due to acidic leaching reactions, especially at a smaller <i>R<sub>g</sub></i> (10.32 mm) and a larger <i>u</i> (0.10 mm/s). The dynamic liquid retention is more sensitive to the diameter of packed feeds (<i>R<sub>g</sub></i>) and superficial flow rate (<i>u</i>) instead of leaching reactions. This might be because the damage of leaching reaction on minerals pores/voids is limited and cannot extensively change the potential pore channels or fluid flow paths. Based on pulse tracing and conductivity tests, we reveal that the solute resides longer under a slower <i>u</i> and smaller packed <i>R<sub>g</sub></i> condition, which corresponds well with desirable copper leaching efficiency. Specifically, the liquid hysteresis behavior is more obvious at a lower <i>u</i> (0.01 mm/s) and smaller <i>R<sub>g</sub></i> (10.32 mm). This paper gives a good reference to ascertain the liquid retention and hydrodynamic hysteresis and promote mineral leaching performance.https://www.mdpi.com/2075-163X/12/12/1623agglomerated heapliquid retentionhysteresis behaviorsolute transportfluid flow
spellingShingle Leiming Wang
Shenghua Yin
Xuelan Zhang
Zepeng Yan
Wensheng Liao
Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling
Minerals
agglomerated heap
liquid retention
hysteresis behavior
solute transport
fluid flow
title Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling
title_full Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling
title_fullStr Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling
title_full_unstemmed Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling
title_short Hydrodynamic Hysteresis and Solute Transport in Agglomerated Heaps under Irrigation, Stacking, and Bioleaching Controlling
title_sort hydrodynamic hysteresis and solute transport in agglomerated heaps under irrigation stacking and bioleaching controlling
topic agglomerated heap
liquid retention
hysteresis behavior
solute transport
fluid flow
url https://www.mdpi.com/2075-163X/12/12/1623
work_keys_str_mv AT leimingwang hydrodynamichysteresisandsolutetransportinagglomeratedheapsunderirrigationstackingandbioleachingcontrolling
AT shenghuayin hydrodynamichysteresisandsolutetransportinagglomeratedheapsunderirrigationstackingandbioleachingcontrolling
AT xuelanzhang hydrodynamichysteresisandsolutetransportinagglomeratedheapsunderirrigationstackingandbioleachingcontrolling
AT zepengyan hydrodynamichysteresisandsolutetransportinagglomeratedheapsunderirrigationstackingandbioleachingcontrolling
AT wenshengliao hydrodynamichysteresisandsolutetransportinagglomeratedheapsunderirrigationstackingandbioleachingcontrolling