New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides
The complexes with manganese(II), iron(II), cobalt(II), nickel(II) and copper(II) of 2-(4, 4’-bipyridin-1-ium-1-yl)-1-(4-bromophenylamino)-3-(4-methoxyphenyl)-3-oxo-1-thioxopropan-2-ide (ylide, Y) were synthesized and characterized. The obtained compounds with 1 : 2 metal/ligand ratios have been cha...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Croatian Chemical Society
2015-12-01
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| Series: | Croatica Chemica Acta |
| Online Access: | http://hrcak.srce.hr/file/221501 |
| _version_ | 1811192987314552832 |
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| author | Rodica Postolachi Ramona Danac Aurel Pui |
| author_facet | Rodica Postolachi Ramona Danac Aurel Pui |
| author_sort | Rodica Postolachi |
| collection | DOAJ |
| description | The complexes with manganese(II), iron(II), cobalt(II), nickel(II) and copper(II) of 2-(4, 4’-bipyridin-1-ium-1-yl)-1-(4-bromophenylamino)-3-(4-methoxyphenyl)-3-oxo-1-thioxopropan-2-ide (ylide, Y) were synthesized and characterized. The obtained compounds with 1 : 2 metal/ligand ratios have been characterized by FTIR, UV Vis spectroscopy, ESI MS spectrometry, molecular conductance, magnetic measurements and thermal analysis. The ylide ligand forms chelates with metallic (II) ions through their amide nitrogen and oxygen atoms. |
| first_indexed | 2024-04-11T23:59:53Z |
| format | Article |
| id | doaj.art-bd84634dc3d64feb9b91b25261c1dec9 |
| institution | Directory Open Access Journal |
| issn | 0011-1643 1334-417X |
| language | English |
| last_indexed | 2024-04-11T23:59:53Z |
| publishDate | 2015-12-01 |
| publisher | Croatian Chemical Society |
| record_format | Article |
| series | Croatica Chemica Acta |
| spelling | doaj.art-bd84634dc3d64feb9b91b25261c1dec92022-12-22T03:56:15ZengCroatian Chemical SocietyCroatica Chemica Acta0011-16431334-417X2015-12-0188320721110.5562/cca2451150523New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted MonoylidesRodica Postolachi0Ramona Danac1Aurel Pui2Faculty of Chemistry, “Al. I. Cuza” University of Iasi, 11 Carol I, Iasi 700506, RomaniaFaculty of Chemistry, “Al. I. Cuza” University of Iasi, 11 Carol I, Iasi 700506, RomaniaFaculty of Chemistry, “Al. I. Cuza” University of Iasi, 11 Carol I, Iasi 700506, RomaniaThe complexes with manganese(II), iron(II), cobalt(II), nickel(II) and copper(II) of 2-(4, 4’-bipyridin-1-ium-1-yl)-1-(4-bromophenylamino)-3-(4-methoxyphenyl)-3-oxo-1-thioxopropan-2-ide (ylide, Y) were synthesized and characterized. The obtained compounds with 1 : 2 metal/ligand ratios have been characterized by FTIR, UV Vis spectroscopy, ESI MS spectrometry, molecular conductance, magnetic measurements and thermal analysis. The ylide ligand forms chelates with metallic (II) ions through their amide nitrogen and oxygen atoms.http://hrcak.srce.hr/file/221501 |
| spellingShingle | Rodica Postolachi Ramona Danac Aurel Pui New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides Croatica Chemica Acta |
| title | New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides |
| title_full | New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides |
| title_fullStr | New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides |
| title_full_unstemmed | New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides |
| title_short | New Coordinative Compounds with 4-(4’-pyridyl)pyridinium Disubstituted Monoylides |
| title_sort | new coordinative compounds with 4 4 pyridyl pyridinium disubstituted monoylides |
| url | http://hrcak.srce.hr/file/221501 |
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