Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking
The improvement in the design of mordenite-based catalysts focuses on the present study to fulfill the massive demand for bio-aviation fuel (BAF) as renewable energy. Modification of the mordenite through ionic impregnation of Fe, Cu, and Cr, has supported the mordenite to perform with better effici...
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| Format: | Article |
| Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2022-06-01
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| Series: | Indonesian Journal of Chemistry |
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| Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/71126 |
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| author | Abdulloh Abdulloh Ulfa Rahmah Satya Candra Wibawa Sakti Alfa Akustia Widati Ahmadi Jaya Permana Rochadi Prasetya Musbahu Adam Ahmad Mochamad Zakki Fahmi |
| author_facet | Abdulloh Abdulloh Ulfa Rahmah Satya Candra Wibawa Sakti Alfa Akustia Widati Ahmadi Jaya Permana Rochadi Prasetya Musbahu Adam Ahmad Mochamad Zakki Fahmi |
| author_sort | Abdulloh Abdulloh |
| collection | DOAJ |
| description | The improvement in the design of mordenite-based catalysts focuses on the present study to fulfill the massive demand for bio-aviation fuel (BAF) as renewable energy. Modification of the mordenite through ionic impregnation of Fe, Cu, and Cr, has supported the mordenite to perform with better efficiency and activity in catalyzing the cracking process of stearic acid. The adjustment on catalytic activity was carried out by simply reacting the catalyst with stearic acid at 190 °C and investigating cracking products with Gas Chromatography-Mass Spectroscopy. The results of the GC-MS test of the cracking product showed the formation of alkane-alkene and aromatic compounds. BAF was selectively obtained (30.27%) when the reaction was catalyzed by FeCuCr/mordenite catalyst. The BAF derived from FeCuCr/mordenite contained hydrocarbons that include xylene, mesitylene, dodecane, tridecane, tetradecane, and pentadecane. However, reduced selectivity was realized (19.85%) when the reaction was catalyzed by nano FeCuCr/mordenite. Its hydrocarbon constituents include benzene, tetradecane, and pentadecane compounds. |
| first_indexed | 2024-04-13T19:09:39Z |
| format | Article |
| id | doaj.art-bd907dfb3662488ea250e64866c10605 |
| institution | Directory Open Access Journal |
| issn | 1411-9420 2460-1578 |
| language | English |
| last_indexed | 2024-04-13T19:09:39Z |
| publishDate | 2022-06-01 |
| publisher | Department of Chemistry, Universitas Gadjah Mada |
| record_format | Article |
| series | Indonesian Journal of Chemistry |
| spelling | doaj.art-bd907dfb3662488ea250e64866c106052022-12-22T02:33:54ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782022-06-0122378079010.22146/ijc.7112631917Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid CrackingAbdulloh Abdulloh0Ulfa Rahmah1Satya Candra Wibawa Sakti2Alfa Akustia Widati3Ahmadi Jaya Permana4Rochadi Prasetya5Musbahu Adam Ahmad6Mochamad Zakki Fahmi7Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaDepartment of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, IndonesiaThe improvement in the design of mordenite-based catalysts focuses on the present study to fulfill the massive demand for bio-aviation fuel (BAF) as renewable energy. Modification of the mordenite through ionic impregnation of Fe, Cu, and Cr, has supported the mordenite to perform with better efficiency and activity in catalyzing the cracking process of stearic acid. The adjustment on catalytic activity was carried out by simply reacting the catalyst with stearic acid at 190 °C and investigating cracking products with Gas Chromatography-Mass Spectroscopy. The results of the GC-MS test of the cracking product showed the formation of alkane-alkene and aromatic compounds. BAF was selectively obtained (30.27%) when the reaction was catalyzed by FeCuCr/mordenite catalyst. The BAF derived from FeCuCr/mordenite contained hydrocarbons that include xylene, mesitylene, dodecane, tridecane, tetradecane, and pentadecane. However, reduced selectivity was realized (19.85%) when the reaction was catalyzed by nano FeCuCr/mordenite. Its hydrocarbon constituents include benzene, tetradecane, and pentadecane compounds.https://jurnal.ugm.ac.id/ijc/article/view/71126mordenitestearic acidmetal impregnationcracking |
| spellingShingle | Abdulloh Abdulloh Ulfa Rahmah Satya Candra Wibawa Sakti Alfa Akustia Widati Ahmadi Jaya Permana Rochadi Prasetya Musbahu Adam Ahmad Mochamad Zakki Fahmi Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking Indonesian Journal of Chemistry mordenite stearic acid metal impregnation cracking |
| title | Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking |
| title_full | Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking |
| title_fullStr | Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking |
| title_full_unstemmed | Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking |
| title_short | Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking |
| title_sort | ion impregnation effect of fe cu cr attributed mordenite on stearic acid cracking |
| topic | mordenite stearic acid metal impregnation cracking |
| url | https://jurnal.ugm.ac.id/ijc/article/view/71126 |
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