Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application

Abstract There is a mounting demand for nonlinear optical materials with superior optical limiting performance which has a noticeable impact on protecting the delicate optical components from laser-induced damage. Transition metal molybdates have garnered attention in the nonlinear optics field due...

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Main Authors: B. Binish, B. Lokesh, Yukesh Veer, Silda Peters, M. Abith, T. C. Sabari Girisun, K. Mani Rahulan
Format: Article
Language:English
Published: Nature Portfolio 2024-03-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-024-53690-0
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author B. Binish
B. Lokesh
Yukesh Veer
Silda Peters
M. Abith
T. C. Sabari Girisun
K. Mani Rahulan
author_facet B. Binish
B. Lokesh
Yukesh Veer
Silda Peters
M. Abith
T. C. Sabari Girisun
K. Mani Rahulan
author_sort B. Binish
collection DOAJ
description Abstract There is a mounting demand for nonlinear optical materials with superior optical limiting performance which has a noticeable impact on protecting the delicate optical components from laser-induced damage. Transition metal molybdates have garnered attention in the nonlinear optics field due to their outstanding optical and luminescent properties, which give rise to widespread applications in next-generation optoelectronics devices. The structural confirmation of the as prepared silver molybdate nanoparticles were made by XRD and Raman spectroscopy analysis. The linear optical properties and the band gap of the synthesized material were studied using UV–Visible and photoluminescence spectroscopy. SEM analysis revealed the pebble like morphology of the silver molybdate nanostructures. The nonlinear responses of the samples were studied using open aperture z-scan approach with Nd:YAG pulsed laser (532 nm, 9 ns, 10 Hz). The sample exhibits reverse saturable absorption pattern attributed to the two photon absorption (2PA) mechanism. The obtained OL threshold value is in the order of 1012 which is suitable for fabricating optical limiters in nano second pulsed laser regime.
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spelling doaj.art-bda63c8b701c4d8a8685ac9b56d3481d2024-03-10T12:10:38ZengNature PortfolioScientific Reports2045-23222024-03-0114111410.1038/s41598-024-53690-0Silver molybdate: an excellent optical limiting material under nanoregime for photonic device applicationB. Binish0B. Lokesh1Yukesh Veer2Silda Peters3M. Abith4T. C. Sabari Girisun5K. Mani Rahulan6Nanophotonics Research Laboratory, Department of Physics & Nanotechnology, SRM Institute of Science and TechnologyNanophotonics Research Laboratory, Department of Physics & Nanotechnology, SRM Institute of Science and TechnologyNanophotonics Research Laboratory, Department of Physics & Nanotechnology, SRM Institute of Science and TechnologyDepartment of Chemistry, SRM Institute of Science and TechnologyNanophotonics Laboratory, Department of Physics, Bharathidasan UniversityNanophotonics Laboratory, Department of Physics, Bharathidasan UniversityNanophotonics Research Laboratory, Department of Physics & Nanotechnology, SRM Institute of Science and TechnologyAbstract There is a mounting demand for nonlinear optical materials with superior optical limiting performance which has a noticeable impact on protecting the delicate optical components from laser-induced damage. Transition metal molybdates have garnered attention in the nonlinear optics field due to their outstanding optical and luminescent properties, which give rise to widespread applications in next-generation optoelectronics devices. The structural confirmation of the as prepared silver molybdate nanoparticles were made by XRD and Raman spectroscopy analysis. The linear optical properties and the band gap of the synthesized material were studied using UV–Visible and photoluminescence spectroscopy. SEM analysis revealed the pebble like morphology of the silver molybdate nanostructures. The nonlinear responses of the samples were studied using open aperture z-scan approach with Nd:YAG pulsed laser (532 nm, 9 ns, 10 Hz). The sample exhibits reverse saturable absorption pattern attributed to the two photon absorption (2PA) mechanism. The obtained OL threshold value is in the order of 1012 which is suitable for fabricating optical limiters in nano second pulsed laser regime.https://doi.org/10.1038/s41598-024-53690-0Silver molybdateZ-scanReverse saturable absorptionOptical limiting
spellingShingle B. Binish
B. Lokesh
Yukesh Veer
Silda Peters
M. Abith
T. C. Sabari Girisun
K. Mani Rahulan
Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application
Scientific Reports
Silver molybdate
Z-scan
Reverse saturable absorption
Optical limiting
title Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application
title_full Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application
title_fullStr Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application
title_full_unstemmed Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application
title_short Silver molybdate: an excellent optical limiting material under nanoregime for photonic device application
title_sort silver molybdate an excellent optical limiting material under nanoregime for photonic device application
topic Silver molybdate
Z-scan
Reverse saturable absorption
Optical limiting
url https://doi.org/10.1038/s41598-024-53690-0
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