Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II)
The asymmetric unit of the title compound, [Cd(CH3COO)(C24H15N5)], comprises one-half of the centrosymmetric molecule. The CdII ion, situated on a centre of inversion, is coordinated by two O atoms from two acetate ligands and four N atoms from two 2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]p...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016-01-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616000638 |
| _version_ | 1818484255586516992 |
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| author | Lei-Qun Guo Yin-Hua Jiang |
| author_facet | Lei-Qun Guo Yin-Hua Jiang |
| author_sort | Lei-Qun Guo |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Cd(CH3COO)(C24H15N5)], comprises one-half of the centrosymmetric molecule. The CdII ion, situated on a centre of inversion, is coordinated by two O atoms from two acetate ligands and four N atoms from two 2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline (L) ligands in a distorted octahedral geometry. In the L ligand, the terminal phenyl and pyridine rings are turned away from the mean plane of the imidazo[4,5-f][1,10]phenanthroline fragment in opposite directions, at 11.1 (1) and 10.5 (1)°, respectively. In the crystal, N—H...O hydrogen bonds link molecules related by translation along the a axis into linear chains, and weak C—H...N interactions link these chains into layers parallel to the (011) plane. |
| first_indexed | 2024-12-10T15:52:43Z |
| format | Article |
| id | doaj.art-bda85e4ce2ca4c3a9ee76d2fa79f4064 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-10T15:52:43Z |
| publishDate | 2016-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-bda85e4ce2ca4c3a9ee76d2fa79f40642022-12-22T01:42:44ZengInternational Union of CrystallographyIUCrData2414-31462016-01-0111x16006310.1107/S2414314616000638cv4002Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II)Lei-Qun Guo0Yin-Hua Jiang1School of Chemistry and Chemical Engineering, Jiangsu University, 212013 Zhenjiang, Jiangsu, People's Republic of ChinaSchool of Chemistry and Chemical Engineering, Jiangsu University, 212013 Zhenjiang, Jiangsu, People's Republic of ChinaThe asymmetric unit of the title compound, [Cd(CH3COO)(C24H15N5)], comprises one-half of the centrosymmetric molecule. The CdII ion, situated on a centre of inversion, is coordinated by two O atoms from two acetate ligands and four N atoms from two 2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline (L) ligands in a distorted octahedral geometry. In the L ligand, the terminal phenyl and pyridine rings are turned away from the mean plane of the imidazo[4,5-f][1,10]phenanthroline fragment in opposite directions, at 11.1 (1) and 10.5 (1)°, respectively. In the crystal, N—H...O hydrogen bonds link molecules related by translation along the a axis into linear chains, and weak C—H...N interactions link these chains into layers parallel to the (011) plane.http://scripts.iucr.org/cgi-bin/paper?S2414314616000638crystal structureCdII complexhydrogen bonds |
| spellingShingle | Lei-Qun Guo Yin-Hua Jiang Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II) IUCrData crystal structure CdII complex hydrogen bonds |
| title | Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II) |
| title_full | Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II) |
| title_fullStr | Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II) |
| title_full_unstemmed | Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II) |
| title_short | Bis(acetato-κO)bis{2-[4-(pyridin-2-yl)phenyl]-1H-imidazo[4,5-f][1,10]phenanthroline-κ2N,N′}cadmium(II) |
| title_sort | bis acetato κo bis 2 4 pyridin 2 yl phenyl 1h imidazo 4 5 f 1 10 phenanthroline κ2n n cadmium ii |
| topic | crystal structure CdII complex hydrogen bonds |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616000638 |
| work_keys_str_mv | AT leiqunguo bisacetatokobis24pyridin2ylphenyl1himidazo45f110phenanthrolinek2nncadmiumii AT yinhuajiang bisacetatokobis24pyridin2ylphenyl1himidazo45f110phenanthrolinek2nncadmiumii |