Phase equilibria in Ho-Fe-Sn ternary system at 670 K

Interaction between the components in the Ho-Fe-Sn ternary system was studied using X-ray diffractometry, metallography and electron microprobe analysis. Isothermal section of the phase diagram was constructed at 670 K over the whole concentration range. Component interaction in the Ho-Fe-Sn system...

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Main Authors: L. Romaka, Yu. Stadnyk, V. V. Romaka, A. Horpenyuk
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2020-06-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/3578
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author L. Romaka
Yu. Stadnyk
V. V. Romaka
A. Horpenyuk
author_facet L. Romaka
Yu. Stadnyk
V. V. Romaka
A. Horpenyuk
author_sort L. Romaka
collection DOAJ
description Interaction between the components in the Ho-Fe-Sn ternary system was studied using X-ray diffractometry, metallography and electron microprobe analysis. Isothermal section of the phase diagram was constructed at 670 K over the whole concentration range. Component interaction in the Ho-Fe-Sn system at 670 K results in the existence of one ternary compound HoFe6Sn6 which crystallizes in the YCo6Ge6 structure type (space group P6/mmm, a=0.53797(2),   c= 0.44446(2) nm). The interstitial-type solid solution HoFexSn2 (up to 8 at.% Fe) based on the HoSn2 (ZrSi2-type structure) binary compound was found. Solubility of Sn in the HoFe2 binary (MgCu2 structure type) extends up to 5 at. %.
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spelling doaj.art-bdaba063f46e4a3e809f14b2cc664ad52022-12-21T19:17:13ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892020-06-0121227227810.15330/pcss.21.2.272-2783578Phase equilibria in Ho-Fe-Sn ternary system at 670 KL. Romaka0Yu. Stadnyk1V. V. Romaka2A. Horpenyuk3Ivan Franko L’viv National UniversityIvan Franko L’viv National UniversityLviv Polytechnic National University; Institute for Solid State ResearchLviv Polytechnic National UniversityInteraction between the components in the Ho-Fe-Sn ternary system was studied using X-ray diffractometry, metallography and electron microprobe analysis. Isothermal section of the phase diagram was constructed at 670 K over the whole concentration range. Component interaction in the Ho-Fe-Sn system at 670 K results in the existence of one ternary compound HoFe6Sn6 which crystallizes in the YCo6Ge6 structure type (space group P6/mmm, a=0.53797(2),   c= 0.44446(2) nm). The interstitial-type solid solution HoFexSn2 (up to 8 at.% Fe) based on the HoSn2 (ZrSi2-type structure) binary compound was found. Solubility of Sn in the HoFe2 binary (MgCu2 structure type) extends up to 5 at. %.https://journals.pnu.edu.ua/index.php/pcss/article/view/3578intermetallicsstannidesphase diagramscrystal structurex-ray diffraction
spellingShingle L. Romaka
Yu. Stadnyk
V. V. Romaka
A. Horpenyuk
Phase equilibria in Ho-Fe-Sn ternary system at 670 K
Фізика і хімія твердого тіла
intermetallics
stannides
phase diagrams
crystal structure
x-ray diffraction
title Phase equilibria in Ho-Fe-Sn ternary system at 670 K
title_full Phase equilibria in Ho-Fe-Sn ternary system at 670 K
title_fullStr Phase equilibria in Ho-Fe-Sn ternary system at 670 K
title_full_unstemmed Phase equilibria in Ho-Fe-Sn ternary system at 670 K
title_short Phase equilibria in Ho-Fe-Sn ternary system at 670 K
title_sort phase equilibria in ho fe sn ternary system at 670 k
topic intermetallics
stannides
phase diagrams
crystal structure
x-ray diffraction
url https://journals.pnu.edu.ua/index.php/pcss/article/view/3578
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AT yustadnyk phaseequilibriainhofesnternarysystemat670k
AT vvromaka phaseequilibriainhofesnternarysystemat670k
AT ahorpenyuk phaseequilibriainhofesnternarysystemat670k