Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
Oxy-Fluoro Boro Tellurite glasses with formula (85-x) TeO2-xB2O3-5Bi2O3-5BaO-5LiF, where x = 0, 10, 20, 30, 40, 50 and 60 mol% were prepared by melt-quenching method. All the prepared glasses were extensively studied by several apparatus such as, X-ray diffraction (XRD), Fourier transform infrared s...
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Elsevier
2020-05-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785419315315 |
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author | N. Elkhoshkhany Nora Samir El Sayed Yousef |
author_facet | N. Elkhoshkhany Nora Samir El Sayed Yousef |
author_sort | N. Elkhoshkhany |
collection | DOAJ |
description | Oxy-Fluoro Boro Tellurite glasses with formula (85-x) TeO2-xB2O3-5Bi2O3-5BaO-5LiF, where x = 0, 10, 20, 30, 40, 50 and 60 mol% were prepared by melt-quenching method. All the prepared glasses were extensively studied by several apparatus such as, X-ray diffraction (XRD), Fourier transform infrared spectroscopy, UV-Vis-NIR spectroscopy and differential scanning calorimetric (DSC). The optical energy gap and refractive index of the prepared glasses were estimated by UV-Vis spectra. Moreover, the thermal stability, transition activation energy, crystallization activation energy and Avrami parameter of prepared glasses were determined. The optical and thermal properties of the prepared glasses were found to be attributed to the concentrations of phase TeO4 and BO4 units in the glass network. From these results, Oxy-Fluoro Boro Tellurite glass could be used in the optical application such as fiber laser with doping rare earth. |
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issn | 2238-7854 |
language | English |
last_indexed | 2024-12-10T21:23:17Z |
publishDate | 2020-05-01 |
publisher | Elsevier |
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spelling | doaj.art-bdb99de37ed044fbb3c893ea62576bce2022-12-22T01:33:04ZengElsevierJournal of Materials Research and Technology2238-78542020-05-019329462959Structural, thermal and optical properties of oxy-fluoro borotellurite glassesN. Elkhoshkhany0Nora Samir1El Sayed Yousef2Physics Dept., College of Arts and Sciences at Tabrjal, Jouf University, Al-Jouf, Saudi Arabia; Department of Material Science, Institute of Graduate Studies and Researches, Alexandria University, 163 Horreya Avenue, Shatby 21526, Egypt; Corresponding author.Department of Material Science, Institute of Graduate Studies and Researches, Alexandria University, 163 Horreya Avenue, Shatby 21526, EgyptResearch Center for Advanced Materials Science (RCAMS), King Khalid University, Abha 61413, P. O. Box 9004, Saudi Arabia; Physics Dept., Faculty of Science, King Khalid University, P. O. Box 9004, Abha, Saudi Arabia; Corresponding author.Oxy-Fluoro Boro Tellurite glasses with formula (85-x) TeO2-xB2O3-5Bi2O3-5BaO-5LiF, where x = 0, 10, 20, 30, 40, 50 and 60 mol% were prepared by melt-quenching method. All the prepared glasses were extensively studied by several apparatus such as, X-ray diffraction (XRD), Fourier transform infrared spectroscopy, UV-Vis-NIR spectroscopy and differential scanning calorimetric (DSC). The optical energy gap and refractive index of the prepared glasses were estimated by UV-Vis spectra. Moreover, the thermal stability, transition activation energy, crystallization activation energy and Avrami parameter of prepared glasses were determined. The optical and thermal properties of the prepared glasses were found to be attributed to the concentrations of phase TeO4 and BO4 units in the glass network. From these results, Oxy-Fluoro Boro Tellurite glass could be used in the optical application such as fiber laser with doping rare earth.http://www.sciencedirect.com/science/article/pii/S2238785419315315Oxy-Fluoro boro tellurite glassFTIRThermal stabilityOptical energy gapRefractive index |
spellingShingle | N. Elkhoshkhany Nora Samir El Sayed Yousef Structural, thermal and optical properties of oxy-fluoro borotellurite glasses Journal of Materials Research and Technology Oxy-Fluoro boro tellurite glass FTIR Thermal stability Optical energy gap Refractive index |
title | Structural, thermal and optical properties of oxy-fluoro borotellurite glasses |
title_full | Structural, thermal and optical properties of oxy-fluoro borotellurite glasses |
title_fullStr | Structural, thermal and optical properties of oxy-fluoro borotellurite glasses |
title_full_unstemmed | Structural, thermal and optical properties of oxy-fluoro borotellurite glasses |
title_short | Structural, thermal and optical properties of oxy-fluoro borotellurite glasses |
title_sort | structural thermal and optical properties of oxy fluoro borotellurite glasses |
topic | Oxy-Fluoro boro tellurite glass FTIR Thermal stability Optical energy gap Refractive index |
url | http://www.sciencedirect.com/science/article/pii/S2238785419315315 |
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