Structural, thermal and optical properties of oxy-fluoro borotellurite glasses

Oxy-Fluoro Boro Tellurite glasses with formula (85-x) TeO2-xB2O3-5Bi2O3-5BaO-5LiF, where x = 0, 10, 20, 30, 40, 50 and 60 mol% were prepared by melt-quenching method. All the prepared glasses were extensively studied by several apparatus such as, X-ray diffraction (XRD), Fourier transform infrared s...

Full description

Bibliographic Details
Main Authors: N. Elkhoshkhany, Nora Samir, El Sayed Yousef
Format: Article
Language:English
Published: Elsevier 2020-05-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785419315315
_version_ 1828443035806990336
author N. Elkhoshkhany
Nora Samir
El Sayed Yousef
author_facet N. Elkhoshkhany
Nora Samir
El Sayed Yousef
author_sort N. Elkhoshkhany
collection DOAJ
description Oxy-Fluoro Boro Tellurite glasses with formula (85-x) TeO2-xB2O3-5Bi2O3-5BaO-5LiF, where x = 0, 10, 20, 30, 40, 50 and 60 mol% were prepared by melt-quenching method. All the prepared glasses were extensively studied by several apparatus such as, X-ray diffraction (XRD), Fourier transform infrared spectroscopy, UV-Vis-NIR spectroscopy and differential scanning calorimetric (DSC). The optical energy gap and refractive index of the prepared glasses were estimated by UV-Vis spectra. Moreover, the thermal stability, transition activation energy, crystallization activation energy and Avrami parameter of prepared glasses were determined. The optical and thermal properties of the prepared glasses were found to be attributed to the concentrations of phase TeO4 and BO4 units in the glass network. From these results, Oxy-Fluoro Boro Tellurite glass could be used in the optical application such as fiber laser with doping rare earth.
first_indexed 2024-12-10T21:23:17Z
format Article
id doaj.art-bdb99de37ed044fbb3c893ea62576bce
institution Directory Open Access Journal
issn 2238-7854
language English
last_indexed 2024-12-10T21:23:17Z
publishDate 2020-05-01
publisher Elsevier
record_format Article
series Journal of Materials Research and Technology
spelling doaj.art-bdb99de37ed044fbb3c893ea62576bce2022-12-22T01:33:04ZengElsevierJournal of Materials Research and Technology2238-78542020-05-019329462959Structural, thermal and optical properties of oxy-fluoro borotellurite glassesN. Elkhoshkhany0Nora Samir1El Sayed Yousef2Physics Dept., College of Arts and Sciences at Tabrjal, Jouf University, Al-Jouf, Saudi Arabia; Department of Material Science, Institute of Graduate Studies and Researches, Alexandria University, 163 Horreya Avenue, Shatby 21526, Egypt; Corresponding author.Department of Material Science, Institute of Graduate Studies and Researches, Alexandria University, 163 Horreya Avenue, Shatby 21526, EgyptResearch Center for Advanced Materials Science (RCAMS), King Khalid University, Abha 61413, P. O. Box 9004, Saudi Arabia; Physics Dept., Faculty of Science, King Khalid University, P. O. Box 9004, Abha, Saudi Arabia; Corresponding author.Oxy-Fluoro Boro Tellurite glasses with formula (85-x) TeO2-xB2O3-5Bi2O3-5BaO-5LiF, where x = 0, 10, 20, 30, 40, 50 and 60 mol% were prepared by melt-quenching method. All the prepared glasses were extensively studied by several apparatus such as, X-ray diffraction (XRD), Fourier transform infrared spectroscopy, UV-Vis-NIR spectroscopy and differential scanning calorimetric (DSC). The optical energy gap and refractive index of the prepared glasses were estimated by UV-Vis spectra. Moreover, the thermal stability, transition activation energy, crystallization activation energy and Avrami parameter of prepared glasses were determined. The optical and thermal properties of the prepared glasses were found to be attributed to the concentrations of phase TeO4 and BO4 units in the glass network. From these results, Oxy-Fluoro Boro Tellurite glass could be used in the optical application such as fiber laser with doping rare earth.http://www.sciencedirect.com/science/article/pii/S2238785419315315Oxy-Fluoro boro tellurite glassFTIRThermal stabilityOptical energy gapRefractive index
spellingShingle N. Elkhoshkhany
Nora Samir
El Sayed Yousef
Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
Journal of Materials Research and Technology
Oxy-Fluoro boro tellurite glass
FTIR
Thermal stability
Optical energy gap
Refractive index
title Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
title_full Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
title_fullStr Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
title_full_unstemmed Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
title_short Structural, thermal and optical properties of oxy-fluoro borotellurite glasses
title_sort structural thermal and optical properties of oxy fluoro borotellurite glasses
topic Oxy-Fluoro boro tellurite glass
FTIR
Thermal stability
Optical energy gap
Refractive index
url http://www.sciencedirect.com/science/article/pii/S2238785419315315
work_keys_str_mv AT nelkhoshkhany structuralthermalandopticalpropertiesofoxyfluoroborotelluriteglasses
AT norasamir structuralthermalandopticalpropertiesofoxyfluoroborotelluriteglasses
AT elsayedyousef structuralthermalandopticalpropertiesofoxyfluoroborotelluriteglasses