Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend
Polycaprolactone (PCL) and poly(butylene terephthalate) (PBT) blend was prepared by melt processing. The PCL/PBT blend showed similar morphology with that of pure PCL.The crystallization temperature of PCL was increased by the incorporation of PBT. It was also observed that the peak height in the DS...
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Format: | Article |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2010-09-01
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Series: | Iranian Journal of Chemistry & Chemical Engineering |
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Online Access: | http://www.ijcce.ac.ir/article_6639_a86491fe3fd4c8efee4e7f7438fb064a.pdf |
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author | Khalid Saeed Soo -Young Park |
author_facet | Khalid Saeed Soo -Young Park |
author_sort | Khalid Saeed |
collection | DOAJ |
description | Polycaprolactone (PCL) and poly(butylene terephthalate) (PBT) blend was prepared by melt processing. The PCL/PBT blend showed similar morphology with that of pure PCL.The crystallization temperature of PCL was increased by the incorporation of PBT. It was also observed that the peak height in the DSC thermograms decreased and then disappeared by adding 40 % or more PBT which might be due to the transestrification between –OH end groups of PCL and ester groups of PBT. The size of PCL spherulites was about 13 µm which decreased highly in the case of blends due to the nucleation effect. The thermal stability of the PCL/PBT blend was higher than pure PCL. |
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format | Article |
id | doaj.art-bdd7582d72994b8e9860e5ef96f4c208 |
institution | Directory Open Access Journal |
issn | 1021-9986 1021-9986 |
language | English |
last_indexed | 2024-12-19T02:40:33Z |
publishDate | 2010-09-01 |
publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
record_format | Article |
series | Iranian Journal of Chemistry & Chemical Engineering |
spelling | doaj.art-bdd7582d72994b8e9860e5ef96f4c2082022-12-21T20:39:08ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862010-09-0129377816639Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) BlendKhalid Saeed0Soo -Young Park1Department of Chemistry, University of Malakand, Chakdara dir (L), Khyber Pukhtoonkhwa, PAKISTANDepartment of Polymer Science, Kyungpook National University, # 1370 Sankyuk-Dong, Buk-gu, Daegu 702-701, SOUTH KOREAPolycaprolactone (PCL) and poly(butylene terephthalate) (PBT) blend was prepared by melt processing. The PCL/PBT blend showed similar morphology with that of pure PCL.The crystallization temperature of PCL was increased by the incorporation of PBT. It was also observed that the peak height in the DSC thermograms decreased and then disappeared by adding 40 % or more PBT which might be due to the transestrification between –OH end groups of PCL and ester groups of PBT. The size of PCL spherulites was about 13 µm which decreased highly in the case of blends due to the nucleation effect. The thermal stability of the PCL/PBT blend was higher than pure PCL.http://www.ijcce.ac.ir/article_6639_a86491fe3fd4c8efee4e7f7438fb064a.pdfpolycaprolactoneblendmorphologythermal properties |
spellingShingle | Khalid Saeed Soo -Young Park Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend Iranian Journal of Chemistry & Chemical Engineering polycaprolactone blend morphology thermal properties |
title | Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend |
title_full | Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend |
title_fullStr | Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend |
title_full_unstemmed | Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend |
title_short | Preparation and Properties of Polycaprolactone/Poly (Butylene Terephthalate) Blend |
title_sort | preparation and properties of polycaprolactone poly butylene terephthalate blend |
topic | polycaprolactone blend morphology thermal properties |
url | http://www.ijcce.ac.ir/article_6639_a86491fe3fd4c8efee4e7f7438fb064a.pdf |
work_keys_str_mv | AT khalidsaeed preparationandpropertiesofpolycaprolactonepolybutyleneterephthalateblend AT sooyoungpark preparationandpropertiesofpolycaprolactonepolybutyleneterephthalateblend |