Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules

A heterogeneous catalyst for the oxidation of small molecules has been prepared by the immobilization of Pt II and Pt IV complex compounds on the surface of amorphous macroporous silica. The structure of the surface platinum complex compounds has been established by means of vibrational and electron...

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Main Authors: Ludmila P. Oleksenko, Vitaly K. Yatsimirsky, Ludmila A. Belyakova, Ol'ga Yu, Ol'ga Boldyreva
Format: Article
Language:English
Published: SAGE Publications 1999-06-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749901700605
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author Ludmila P. Oleksenko
Vitaly K. Yatsimirsky
Ludmila A. Belyakova
Ol'ga Yu
Ol'ga Boldyreva
author_facet Ludmila P. Oleksenko
Vitaly K. Yatsimirsky
Ludmila A. Belyakova
Ol'ga Yu
Ol'ga Boldyreva
author_sort Ludmila P. Oleksenko
collection DOAJ
description A heterogeneous catalyst for the oxidation of small molecules has been prepared by the immobilization of Pt II and Pt IV complex compounds on the surface of amorphous macroporous silica. The structure of the surface platinum complex compounds has been established by means of vibrational and electronic spectroscopy while the catalytic activity of the catalyst was investigated for the hydrogen (or carbon monoxide) oxidation reaction by molecular oxygen under mild conditions.
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spelling doaj.art-bdefe7876b8140939f61cb5fb91a27fc2024-03-02T09:46:10ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381999-06-011710.1177/026361749901700605Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small MoleculesLudmila P. Oleksenko0Vitaly K. Yatsimirsky1Ludmila A. Belyakova2Ol'ga YuOl'ga Boldyreva Department of Chemistry, Kiev Shevchenko University, Vladimirskaya Str. 64, 252033 Kiev, Ukraine Department of Chemistry, Kiev Shevchenko University, Vladimirskaya Str. 64, 252033 Kiev, Ukraine Institute of Surface Chemistry. National Academy of Sciences of Ukraine, Prospekt Nauki 31, 252650 Kiev, UkraineA heterogeneous catalyst for the oxidation of small molecules has been prepared by the immobilization of Pt II and Pt IV complex compounds on the surface of amorphous macroporous silica. The structure of the surface platinum complex compounds has been established by means of vibrational and electronic spectroscopy while the catalytic activity of the catalyst was investigated for the hydrogen (or carbon monoxide) oxidation reaction by molecular oxygen under mild conditions.https://doi.org/10.1177/026361749901700605
spellingShingle Ludmila P. Oleksenko
Vitaly K. Yatsimirsky
Ludmila A. Belyakova
Ol'ga Yu
Ol'ga Boldyreva
Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules
Adsorption Science & Technology
title Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules
title_full Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules
title_fullStr Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules
title_full_unstemmed Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules
title_short Immobilized Pt Complex Compounds as Catalysts for the Oxidation Reactions of Small Molecules
title_sort immobilized pt complex compounds as catalysts for the oxidation reactions of small molecules
url https://doi.org/10.1177/026361749901700605
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AT olgayu immobilizedptcomplexcompoundsascatalystsfortheoxidationreactionsofsmallmolecules
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