Polyurethanes from the crystalline prepolymers resistant to abrasive wear

The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resi...

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Main Authors: Domańska Agata, Boczkowska Anna, Izydorzak-Woźniak Marta, Jaegermann Zbigniew, Grądzka-Dahlke Małgorzata
Format: Article
Language:English
Published: Sciendo 2014-12-01
Series:Polish Journal of Chemical Technology
Subjects:
Online Access:https://doi.org/10.2478/pjct-2014-0063
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author Domańska Agata
Boczkowska Anna
Izydorzak-Woźniak Marta
Jaegermann Zbigniew
Grądzka-Dahlke Małgorzata
author_facet Domańska Agata
Boczkowska Anna
Izydorzak-Woźniak Marta
Jaegermann Zbigniew
Grądzka-Dahlke Małgorzata
author_sort Domańska Agata
collection DOAJ
description The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to abrasive wear and degradation for bio-medical application. Polyurethanes were fabricated from crystalline prepolymers extended by water. The paper presents preliminary results on polyurethane surface wettability, friction coefficient for different couples of the co-working materials such as polyurethane-polyurethane, polyurethane-titanium alloy, polyurethane-alumina, in comparison to commonly used polyethylene-titanium alloy. Shear strength of polyurethane-alumina joint, as well as viscosity of prepolymers were also measured. The values of friction coefficient were compared to literature data on commercially available polyurethane with the trade name Pellethane. Polyurethanes obtained are characterized by low abrasive wear and low friction coefficient in couple with the titanium alloy, what makes them attractive as possible components of ceramic-polymer endoprosthesis joints.
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spelling doaj.art-bdf414c1d922488e8ca3b2313765d9362022-12-21T22:00:53ZengSciendoPolish Journal of Chemical Technology1899-47412014-12-01164142010.2478/pjct-2014-0063pjct-2014-0063Polyurethanes from the crystalline prepolymers resistant to abrasive wearDomańska Agata0Boczkowska Anna1Izydorzak-Woźniak Marta2Jaegermann Zbigniew3Grądzka-Dahlke Małgorzata4Warsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, PolandWarsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, PolandWarsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, PolandInstitute of Ceramics and Building Materials, Postepu 9, 02-676 Warsaw, PolandBialystok University of Technology, Faculty of Mechanical Engineering, Wiejska 45C, 15-351 Białystok, PolandThe research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to abrasive wear and degradation for bio-medical application. Polyurethanes were fabricated from crystalline prepolymers extended by water. The paper presents preliminary results on polyurethane surface wettability, friction coefficient for different couples of the co-working materials such as polyurethane-polyurethane, polyurethane-titanium alloy, polyurethane-alumina, in comparison to commonly used polyethylene-titanium alloy. Shear strength of polyurethane-alumina joint, as well as viscosity of prepolymers were also measured. The values of friction coefficient were compared to literature data on commercially available polyurethane with the trade name Pellethane. Polyurethanes obtained are characterized by low abrasive wear and low friction coefficient in couple with the titanium alloy, what makes them attractive as possible components of ceramic-polymer endoprosthesis joints.https://doi.org/10.2478/pjct-2014-0063polyurethanecrystalline prepolymerabrasive wearadhesionfriction coefficientendoprosthesis
spellingShingle Domańska Agata
Boczkowska Anna
Izydorzak-Woźniak Marta
Jaegermann Zbigniew
Grądzka-Dahlke Małgorzata
Polyurethanes from the crystalline prepolymers resistant to abrasive wear
Polish Journal of Chemical Technology
polyurethane
crystalline prepolymer
abrasive wear
adhesion
friction coefficient
endoprosthesis
title Polyurethanes from the crystalline prepolymers resistant to abrasive wear
title_full Polyurethanes from the crystalline prepolymers resistant to abrasive wear
title_fullStr Polyurethanes from the crystalline prepolymers resistant to abrasive wear
title_full_unstemmed Polyurethanes from the crystalline prepolymers resistant to abrasive wear
title_short Polyurethanes from the crystalline prepolymers resistant to abrasive wear
title_sort polyurethanes from the crystalline prepolymers resistant to abrasive wear
topic polyurethane
crystalline prepolymer
abrasive wear
adhesion
friction coefficient
endoprosthesis
url https://doi.org/10.2478/pjct-2014-0063
work_keys_str_mv AT domanskaagata polyurethanesfromthecrystallineprepolymersresistanttoabrasivewear
AT boczkowskaanna polyurethanesfromthecrystallineprepolymersresistanttoabrasivewear
AT izydorzakwozniakmarta polyurethanesfromthecrystallineprepolymersresistanttoabrasivewear
AT jaegermannzbigniew polyurethanesfromthecrystallineprepolymersresistanttoabrasivewear
AT gradzkadahlkemałgorzata polyurethanesfromthecrystallineprepolymersresistanttoabrasivewear