Polyurethanes from the crystalline prepolymers resistant to abrasive wear
The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resi...
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Format: | Article |
Language: | English |
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Sciendo
2014-12-01
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Series: | Polish Journal of Chemical Technology |
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Online Access: | https://doi.org/10.2478/pjct-2014-0063 |
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author | Domańska Agata Boczkowska Anna Izydorzak-Woźniak Marta Jaegermann Zbigniew Grądzka-Dahlke Małgorzata |
author_facet | Domańska Agata Boczkowska Anna Izydorzak-Woźniak Marta Jaegermann Zbigniew Grądzka-Dahlke Małgorzata |
author_sort | Domańska Agata |
collection | DOAJ |
description | The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to abrasive wear and degradation for bio-medical application. Polyurethanes were fabricated from crystalline prepolymers extended by water. The paper presents preliminary results on polyurethane surface wettability, friction coefficient for different couples of the co-working materials such as polyurethane-polyurethane, polyurethane-titanium alloy, polyurethane-alumina, in comparison to commonly used polyethylene-titanium alloy. Shear strength of polyurethane-alumina joint, as well as viscosity of prepolymers were also measured. The values of friction coefficient were compared to literature data on commercially available polyurethane with the trade name Pellethane. Polyurethanes obtained are characterized by low abrasive wear and low friction coefficient in couple with the titanium alloy, what makes them attractive as possible components of ceramic-polymer endoprosthesis joints. |
first_indexed | 2024-12-17T06:01:22Z |
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id | doaj.art-bdf414c1d922488e8ca3b2313765d936 |
institution | Directory Open Access Journal |
issn | 1899-4741 |
language | English |
last_indexed | 2024-12-17T06:01:22Z |
publishDate | 2014-12-01 |
publisher | Sciendo |
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series | Polish Journal of Chemical Technology |
spelling | doaj.art-bdf414c1d922488e8ca3b2313765d9362022-12-21T22:00:53ZengSciendoPolish Journal of Chemical Technology1899-47412014-12-01164142010.2478/pjct-2014-0063pjct-2014-0063Polyurethanes from the crystalline prepolymers resistant to abrasive wearDomańska Agata0Boczkowska Anna1Izydorzak-Woźniak Marta2Jaegermann Zbigniew3Grądzka-Dahlke Małgorzata4Warsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, PolandWarsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, PolandWarsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, PolandInstitute of Ceramics and Building Materials, Postepu 9, 02-676 Warsaw, PolandBialystok University of Technology, Faculty of Mechanical Engineering, Wiejska 45C, 15-351 Białystok, PolandThe research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to abrasive wear and degradation for bio-medical application. Polyurethanes were fabricated from crystalline prepolymers extended by water. The paper presents preliminary results on polyurethane surface wettability, friction coefficient for different couples of the co-working materials such as polyurethane-polyurethane, polyurethane-titanium alloy, polyurethane-alumina, in comparison to commonly used polyethylene-titanium alloy. Shear strength of polyurethane-alumina joint, as well as viscosity of prepolymers were also measured. The values of friction coefficient were compared to literature data on commercially available polyurethane with the trade name Pellethane. Polyurethanes obtained are characterized by low abrasive wear and low friction coefficient in couple with the titanium alloy, what makes them attractive as possible components of ceramic-polymer endoprosthesis joints.https://doi.org/10.2478/pjct-2014-0063polyurethanecrystalline prepolymerabrasive wearadhesionfriction coefficientendoprosthesis |
spellingShingle | Domańska Agata Boczkowska Anna Izydorzak-Woźniak Marta Jaegermann Zbigniew Grądzka-Dahlke Małgorzata Polyurethanes from the crystalline prepolymers resistant to abrasive wear Polish Journal of Chemical Technology polyurethane crystalline prepolymer abrasive wear adhesion friction coefficient endoprosthesis |
title | Polyurethanes from the crystalline prepolymers resistant to abrasive wear |
title_full | Polyurethanes from the crystalline prepolymers resistant to abrasive wear |
title_fullStr | Polyurethanes from the crystalline prepolymers resistant to abrasive wear |
title_full_unstemmed | Polyurethanes from the crystalline prepolymers resistant to abrasive wear |
title_short | Polyurethanes from the crystalline prepolymers resistant to abrasive wear |
title_sort | polyurethanes from the crystalline prepolymers resistant to abrasive wear |
topic | polyurethane crystalline prepolymer abrasive wear adhesion friction coefficient endoprosthesis |
url | https://doi.org/10.2478/pjct-2014-0063 |
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