Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing

UV–digital printing belongs to the commonly used method for custom large-area substrate decoration. Despite low surface energy and adhesion, transparent polymer materials, such as polymethylmethacrylate (PMMA) and polycarbonate (PC), represent an ideal substrate for such purposes. The diffuse coplan...

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Main Authors: Michal Fleischer, Zlata Kelar Tučeková, Oleksandr Galmiz, Eva Baťková, Tomáš Plšek, Tatiana Kolářová, Dušan Kováčik, Jakub Kelar
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/14/5/426
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author Michal Fleischer
Zlata Kelar Tučeková
Oleksandr Galmiz
Eva Baťková
Tomáš Plšek
Tatiana Kolářová
Dušan Kováčik
Jakub Kelar
author_facet Michal Fleischer
Zlata Kelar Tučeková
Oleksandr Galmiz
Eva Baťková
Tomáš Plšek
Tatiana Kolářová
Dušan Kováčik
Jakub Kelar
author_sort Michal Fleischer
collection DOAJ
description UV–digital printing belongs to the commonly used method for custom large-area substrate decoration. Despite low surface energy and adhesion, transparent polymer materials, such as polymethylmethacrylate (PMMA) and polycarbonate (PC), represent an ideal substrate for such purposes. The diffuse coplanar surface barrier discharge (DCSBD) in a novel compact configuration was used for substrate activation to improve ink adhesion to the polymer surface. This industrially applicable version of DCSBD was prepared, tested, and successfully implemented for the UV–digital printing process. Furthermore, wettability and surface free energy measurement, X-ray photoelectron spectroscopy, atomic force, and scanning electron microscopy evaluated the surface chemistry and morphology changes. The changes in the adhesion of the surface and of ink were analyzed by a peel-force and a crosscut test, respectively. A short plasma treatment (1–5 s) enhanced the substrate’s properties of PMMA and PC while providing the pre-treatment suitable for further in-line UV–digital printing. Furthermore, we did not observe damage of or significant change in roughness affecting the substrate’s initial transparency.
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spelling doaj.art-bdf4364ff6f04e11956b60d29ddb17872024-03-12T16:51:32ZengMDPI AGNanomaterials2079-49912024-02-0114542610.3390/nano14050426Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital PrintingMichal Fleischer0Zlata Kelar Tučeková1Oleksandr Galmiz2Eva Baťková3Tomáš Plšek4Tatiana Kolářová5Dušan Kováčik6Jakub Kelar7Department of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicDepartment of Plasma Physics and Technology, CEPLANT—R&D Centre for Plasma and Nanotechnology Surface Modifications, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech RepublicUV–digital printing belongs to the commonly used method for custom large-area substrate decoration. Despite low surface energy and adhesion, transparent polymer materials, such as polymethylmethacrylate (PMMA) and polycarbonate (PC), represent an ideal substrate for such purposes. The diffuse coplanar surface barrier discharge (DCSBD) in a novel compact configuration was used for substrate activation to improve ink adhesion to the polymer surface. This industrially applicable version of DCSBD was prepared, tested, and successfully implemented for the UV–digital printing process. Furthermore, wettability and surface free energy measurement, X-ray photoelectron spectroscopy, atomic force, and scanning electron microscopy evaluated the surface chemistry and morphology changes. The changes in the adhesion of the surface and of ink were analyzed by a peel-force and a crosscut test, respectively. A short plasma treatment (1–5 s) enhanced the substrate’s properties of PMMA and PC while providing the pre-treatment suitable for further in-line UV–digital printing. Furthermore, we did not observe damage of or significant change in roughness affecting the substrate’s initial transparency.https://www.mdpi.com/2079-4991/14/5/426UV–digital printingtransparent polymerslow-temperature plasmasurface functionalizationink adhesion
spellingShingle Michal Fleischer
Zlata Kelar Tučeková
Oleksandr Galmiz
Eva Baťková
Tomáš Plšek
Tatiana Kolářová
Dušan Kováčik
Jakub Kelar
Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing
Nanomaterials
UV–digital printing
transparent polymers
low-temperature plasma
surface functionalization
ink adhesion
title Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing
title_full Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing
title_fullStr Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing
title_full_unstemmed Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing
title_short Plasma Treatment of Large-Area Polymer Substrates for the Enhanced Adhesion of UV–Digital Printing
title_sort plasma treatment of large area polymer substrates for the enhanced adhesion of uv digital printing
topic UV–digital printing
transparent polymers
low-temperature plasma
surface functionalization
ink adhesion
url https://www.mdpi.com/2079-4991/14/5/426
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