Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol
Two new and similar cobalt(III) complexes, [CoL2]·NO3 (1) and [CoL2]·Cl (2), where L is 5-bromo-2-((2-(phenylamino)ethylimino)methyl)phenolate, have been synthesized and characterized by IR and UV-Vis spectra. Structures of the complexes were confirmed by single crystal X-ray determination. The Co a...
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2021-12-01
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| Series: | Acta Chimica Slovenica |
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| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/6979 |
| _version_ | 1828911158793338880 |
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| author | Cheng Liu |
| author_facet | Cheng Liu |
| author_sort | Cheng Liu |
| collection | DOAJ |
| description | Two new and similar cobalt(III) complexes, [CoL2]·NO3 (1) and [CoL2]·Cl (2), where L is 5-bromo-2-((2-(phenylamino)ethylimino)methyl)phenolate, have been synthesized and characterized by IR and UV-Vis spectra. Structures of the complexes were confirmed by single crystal X-ray determination. The Co atoms in the complexes are in octahedral coordination, with the donor atoms come from the two Schiff base ligands, viz. phenolate oxygen, and imino and amino nitrogen. The anions of the cobalt salts crystallized as counteranions in the complexes. The complexes were assayed for antibacterial activities by MTT method. |
| first_indexed | 2024-12-13T18:57:55Z |
| format | Article |
| id | doaj.art-be0fbd64d2fb453784ea88c9f16ff4ad |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-13T18:57:55Z |
| publishDate | 2021-12-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-be0fbd64d2fb453784ea88c9f16ff4ad2022-12-21T23:34:46ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552021-12-0168498398910.17344/acsi.2021.69791024Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenolCheng Liu0Huaqiao UniversityTwo new and similar cobalt(III) complexes, [CoL2]·NO3 (1) and [CoL2]·Cl (2), where L is 5-bromo-2-((2-(phenylamino)ethylimino)methyl)phenolate, have been synthesized and characterized by IR and UV-Vis spectra. Structures of the complexes were confirmed by single crystal X-ray determination. The Co atoms in the complexes are in octahedral coordination, with the donor atoms come from the two Schiff base ligands, viz. phenolate oxygen, and imino and amino nitrogen. The anions of the cobalt salts crystallized as counteranions in the complexes. The complexes were assayed for antibacterial activities by MTT method.https://journals.matheo.si/index.php/ACSi/article/view/6979schiff basecobalt complexsynthesisx-ray diffractionantibacterial activity |
| spellingShingle | Cheng Liu Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol Acta Chimica Slovenica schiff base cobalt complex synthesis x-ray diffraction antibacterial activity |
| title | Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol |
| title_full | Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol |
| title_fullStr | Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol |
| title_full_unstemmed | Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol |
| title_short | Synthesis, Characterization, X-Ray Crystal Structures and Antibacterial Activity of Cobalt(III) Complexes Derived from 5-Bromo-2-((2-(phenylamino)ethylimino)methyl)phenol |
| title_sort | synthesis characterization x ray crystal structures and antibacterial activity of cobalt iii complexes derived from 5 bromo 2 2 phenylamino ethylimino methyl phenol |
| topic | schiff base cobalt complex synthesis x-ray diffraction antibacterial activity |
| url | https://journals.matheo.si/index.php/ACSi/article/view/6979 |
| work_keys_str_mv | AT chengliu synthesischaracterizationxraycrystalstructuresandantibacterialactivityofcobaltiiicomplexesderivedfrom5bromo22phenylaminoethyliminomethylphenol |