Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials

The activity of zinc is between that of magnesium and iron, and it has a suitable degradation rate and good biocompatibility. It has been regarded as a very promising biodegradable metal material for biomedicine. However, the insufficient mechanical properties of pure Zn limit its practical applicat...

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Main Authors: Mei Fan, Fei Zhao, Yuan Liu, Sheng Yin, Shanshan Peng, Zongkui Zhang
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/8/1110
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author Mei Fan
Fei Zhao
Yuan Liu
Sheng Yin
Shanshan Peng
Zongkui Zhang
author_facet Mei Fan
Fei Zhao
Yuan Liu
Sheng Yin
Shanshan Peng
Zongkui Zhang
author_sort Mei Fan
collection DOAJ
description The activity of zinc is between that of magnesium and iron, and it has a suitable degradation rate and good biocompatibility. It has been regarded as a very promising biodegradable metal material for biomedicine. However, the insufficient mechanical properties of pure Zn limit its practical application in the field of orthopedic implants. In this paper, partially unzipped carbon nanotubes (PUCNTs) obtained by meridionally cutting multi-walled carbon nanotubes (MWCNTs) were used as reinforcements and combined with spark plasma sintering to prepare partially unzipped carbon nanotube reinforced Zn matrix composites. The effects of PUCNT addition on the microstructure and the mechanical properties of Zn matrix composites were investigated. The microstructure analysis showed the good interface bonding between PUCNTs and the Zn matrix. Additionally, the strength of PUCNTs/Zn composites showed a trend of increasing first and then decreasing with the PUCNT content increases. When the PUCNT content was 0.2 wt%, the tensile strength and yield strength of composites were about 78.4% and 64.4% higher than that of pure Zn, respectively, while maintaining a high elongation (62.6%).
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spelling doaj.art-be146e87bf0f4550a20bd781d78a78ea2023-12-01T23:35:13ZengMDPI AGCrystals2073-43522022-08-01128111010.3390/cryst12081110Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant MaterialsMei Fan0Fei Zhao1Yuan Liu2Sheng Yin3Shanshan Peng4Zongkui Zhang5College of Materials and Metallurgy, Guizhou University, Guiyang 550025, ChinaCollege of Materials and Metallurgy, Guizhou University, Guiyang 550025, ChinaCollege of Materials and Metallurgy, Guizhou University, Guiyang 550025, ChinaCollege of Materials and Metallurgy, Guizhou University, Guiyang 550025, ChinaHospital of Guizhou University, Guiyang 550025, ChinaHospital of Guizhou University, Guiyang 550025, ChinaThe activity of zinc is between that of magnesium and iron, and it has a suitable degradation rate and good biocompatibility. It has been regarded as a very promising biodegradable metal material for biomedicine. However, the insufficient mechanical properties of pure Zn limit its practical application in the field of orthopedic implants. In this paper, partially unzipped carbon nanotubes (PUCNTs) obtained by meridionally cutting multi-walled carbon nanotubes (MWCNTs) were used as reinforcements and combined with spark plasma sintering to prepare partially unzipped carbon nanotube reinforced Zn matrix composites. The effects of PUCNT addition on the microstructure and the mechanical properties of Zn matrix composites were investigated. The microstructure analysis showed the good interface bonding between PUCNTs and the Zn matrix. Additionally, the strength of PUCNTs/Zn composites showed a trend of increasing first and then decreasing with the PUCNT content increases. When the PUCNT content was 0.2 wt%, the tensile strength and yield strength of composites were about 78.4% and 64.4% higher than that of pure Zn, respectively, while maintaining a high elongation (62.6%).https://www.mdpi.com/2073-4352/12/8/1110partially unzipped carbon nanotubesmechanical propertieszinc matrix composites
spellingShingle Mei Fan
Fei Zhao
Yuan Liu
Sheng Yin
Shanshan Peng
Zongkui Zhang
Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials
Crystals
partially unzipped carbon nanotubes
mechanical properties
zinc matrix composites
title Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials
title_full Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials
title_fullStr Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials
title_full_unstemmed Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials
title_short Zinc Matrix Composites Reinforced with Partially Unzipped Carbon Nanotubes as Biodegradable Implant Materials
title_sort zinc matrix composites reinforced with partially unzipped carbon nanotubes as biodegradable implant materials
topic partially unzipped carbon nanotubes
mechanical properties
zinc matrix composites
url https://www.mdpi.com/2073-4352/12/8/1110
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AT feizhao zincmatrixcompositesreinforcedwithpartiallyunzippedcarbonnanotubesasbiodegradableimplantmaterials
AT yuanliu zincmatrixcompositesreinforcedwithpartiallyunzippedcarbonnanotubesasbiodegradableimplantmaterials
AT shengyin zincmatrixcompositesreinforcedwithpartiallyunzippedcarbonnanotubesasbiodegradableimplantmaterials
AT shanshanpeng zincmatrixcompositesreinforcedwithpartiallyunzippedcarbonnanotubesasbiodegradableimplantmaterials
AT zongkuizhang zincmatrixcompositesreinforcedwithpartiallyunzippedcarbonnanotubesasbiodegradableimplantmaterials