Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids
Abstract The present work reports facile synthesis of CuFe2O4 nanoparticles via co-precipitation method and formulation of its nanohybrids with polythiophene (PTh). The structural and morphological properties were investigated using fourier transform infrared spectroscopy (FT-IR), X-ray diffraction...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2023-03-01
|
| Series: | Scientific Reports |
| Online Access: | https://doi.org/10.1038/s41598-023-30669-x |
| _version_ | 1827974659195273216 |
|---|---|
| author | Ufana Riaz Shayista Gaffar Kristen Hauser Fei Yan |
| author_facet | Ufana Riaz Shayista Gaffar Kristen Hauser Fei Yan |
| author_sort | Ufana Riaz |
| collection | DOAJ |
| description | Abstract The present work reports facile synthesis of CuFe2O4 nanoparticles via co-precipitation method and formulation of its nanohybrids with polythiophene (PTh). The structural and morphological properties were investigated using fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy coupled with energy dispersive spectra (SEM-EDS) and UV–Vis spectroscopy. The band gap was found to decrease with increase in the loading of PTh and was found to be 2.52 eV for 1-PTh/CuFe2O4, 2.15 eV for 3-PTh/CuFe2O4 and 1.89 eV for 5-PTh/CuFe2O4. The nanohybrids were utilized as photocatalysts for visible light induced degradation of diphenyl urea. Diphenyl urea showed 65% degradation using 150 mg catalyst within 120 min. Polyethylene (PE) was also degraded using these nanohybrids under visible light as well as microwave irradiation to compare its catalytic efficiency under both conditions. Almost 50% of PE was degraded under microwave and 22% under visible light irradiation using 5-PTh/CuFe2O4. The degraded diphenyl urea fragments were analyzed using LCMS and a tentative mechanism of degradation was proposed. |
| first_indexed | 2024-04-09T19:57:53Z |
| format | Article |
| id | doaj.art-be234bb87d454dd1808ed6388c544c55 |
| institution | Directory Open Access Journal |
| issn | 2045-2322 |
| language | English |
| last_indexed | 2024-04-09T19:57:53Z |
| publishDate | 2023-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj.art-be234bb87d454dd1808ed6388c544c552023-04-03T05:23:46ZengNature PortfolioScientific Reports2045-23222023-03-0113111110.1038/s41598-023-30669-xVisible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybridsUfana Riaz0Shayista Gaffar1Kristen Hauser2Fei Yan3Department of Chemistry and Biochemistry, North Carolina Central UniversityMaterials Research Laboratory, Department of Chemistry, Jamia Millia IslamiaDepartment of Chemistry and Biochemistry, North Carolina Central UniversityDepartment of Chemistry and Biochemistry, North Carolina Central UniversityAbstract The present work reports facile synthesis of CuFe2O4 nanoparticles via co-precipitation method and formulation of its nanohybrids with polythiophene (PTh). The structural and morphological properties were investigated using fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy coupled with energy dispersive spectra (SEM-EDS) and UV–Vis spectroscopy. The band gap was found to decrease with increase in the loading of PTh and was found to be 2.52 eV for 1-PTh/CuFe2O4, 2.15 eV for 3-PTh/CuFe2O4 and 1.89 eV for 5-PTh/CuFe2O4. The nanohybrids were utilized as photocatalysts for visible light induced degradation of diphenyl urea. Diphenyl urea showed 65% degradation using 150 mg catalyst within 120 min. Polyethylene (PE) was also degraded using these nanohybrids under visible light as well as microwave irradiation to compare its catalytic efficiency under both conditions. Almost 50% of PE was degraded under microwave and 22% under visible light irradiation using 5-PTh/CuFe2O4. The degraded diphenyl urea fragments were analyzed using LCMS and a tentative mechanism of degradation was proposed.https://doi.org/10.1038/s41598-023-30669-x |
| spellingShingle | Ufana Riaz Shayista Gaffar Kristen Hauser Fei Yan Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids Scientific Reports |
| title | Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids |
| title_full | Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids |
| title_fullStr | Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids |
| title_full_unstemmed | Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids |
| title_short | Visible-light induced degradation of diphenyl urea and polyethylene using polythiophene decorated CuFe2O4 nanohybrids |
| title_sort | visible light induced degradation of diphenyl urea and polyethylene using polythiophene decorated cufe2o4 nanohybrids |
| url | https://doi.org/10.1038/s41598-023-30669-x |
| work_keys_str_mv | AT ufanariaz visiblelightinduceddegradationofdiphenylureaandpolyethyleneusingpolythiophenedecoratedcufe2o4nanohybrids AT shayistagaffar visiblelightinduceddegradationofdiphenylureaandpolyethyleneusingpolythiophenedecoratedcufe2o4nanohybrids AT kristenhauser visiblelightinduceddegradationofdiphenylureaandpolyethyleneusingpolythiophenedecoratedcufe2o4nanohybrids AT feiyan visiblelightinduceddegradationofdiphenylureaandpolyethyleneusingpolythiophenedecoratedcufe2o4nanohybrids |