Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines

The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, ca...

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Main Authors: Ana R. L. Araújo, Augusto C. Tomé, Carla I. M. Santos, Maria A. F. Faustino, Maria G. P. M. S. Neves, Mário M. Q. Simões, Nuno M. M. Moura, Sultan T. Abu-Orabi, José A. S. Cavaleiro
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/25/7/1745
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author Ana R. L. Araújo
Augusto C. Tomé
Carla I. M. Santos
Maria A. F. Faustino
Maria G. P. M. S. Neves
Mário M. Q. Simões
Nuno M. M. Moura
Sultan T. Abu-Orabi
José A. S. Cavaleiro
author_facet Ana R. L. Araújo
Augusto C. Tomé
Carla I. M. Santos
Maria A. F. Faustino
Maria G. P. M. S. Neves
Mário M. Q. Simões
Nuno M. M. Moura
Sultan T. Abu-Orabi
José A. S. Cavaleiro
author_sort Ana R. L. Araújo
collection DOAJ
description The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step.
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spelling doaj.art-be277da79f014894a805acde34811f4e2023-11-19T21:16:43ZengMDPI AGMolecules1420-30492020-04-01257174510.3390/molecules25071745Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and PorphyrazinesAna R. L. Araújo0Augusto C. Tomé1Carla I. M. Santos2Maria A. F. Faustino3Maria G. P. M. S. Neves4Mário M. Q. Simões5Nuno M. M. Moura6Sultan T. Abu-Orabi7José A. S. Cavaleiro8LAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalChemistry Department, Yarmouk University, Irbid 211-63, JordanLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalThe reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step.https://www.mdpi.com/1420-3049/25/7/1745azidesphthalocyaninessubphthalocyaninesporphyrazinesclick chemistryphotodynamic therapy
spellingShingle Ana R. L. Araújo
Augusto C. Tomé
Carla I. M. Santos
Maria A. F. Faustino
Maria G. P. M. S. Neves
Mário M. Q. Simões
Nuno M. M. Moura
Sultan T. Abu-Orabi
José A. S. Cavaleiro
Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
Molecules
azides
phthalocyanines
subphthalocyanines
porphyrazines
click chemistry
photodynamic therapy
title Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_full Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_fullStr Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_full_unstemmed Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_short Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
title_sort azides and porphyrinoids synthetic approaches and applications part 2 azides phthalocyanines subphthalocyanines and porphyrazines
topic azides
phthalocyanines
subphthalocyanines
porphyrazines
click chemistry
photodynamic therapy
url https://www.mdpi.com/1420-3049/25/7/1745
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