Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines
The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, ca...
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MDPI AG
2020-04-01
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author | Ana R. L. Araújo Augusto C. Tomé Carla I. M. Santos Maria A. F. Faustino Maria G. P. M. S. Neves Mário M. Q. Simões Nuno M. M. Moura Sultan T. Abu-Orabi José A. S. Cavaleiro |
author_facet | Ana R. L. Araújo Augusto C. Tomé Carla I. M. Santos Maria A. F. Faustino Maria G. P. M. S. Neves Mário M. Q. Simões Nuno M. M. Moura Sultan T. Abu-Orabi José A. S. Cavaleiro |
author_sort | Ana R. L. Araújo |
collection | DOAJ |
description | The reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step. |
first_indexed | 2024-03-10T20:33:17Z |
format | Article |
id | doaj.art-be277da79f014894a805acde34811f4e |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-03-10T20:33:17Z |
publishDate | 2020-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-be277da79f014894a805acde34811f4e2023-11-19T21:16:43ZengMDPI AGMolecules1420-30492020-04-01257174510.3390/molecules25071745Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and PorphyrazinesAna R. L. Araújo0Augusto C. Tomé1Carla I. M. Santos2Maria A. F. Faustino3Maria G. P. M. S. Neves4Mário M. Q. Simões5Nuno M. M. Moura6Sultan T. Abu-Orabi7José A. S. Cavaleiro8LAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalChemistry Department, Yarmouk University, Irbid 211-63, JordanLAQV-REQUIMTE, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, PortugalThe reaction between organic azides and alkyne derivatives via the Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) is an efficient strategy to combine phthalocyanines and analogues with different materials. As examples of such materials, it can be considered the following ones: graphene oxide, carbon nanotubes, silica nanoparticles, gold nanoparticles, and quantum dots. This approach is also being relevant to conjugate phthalocyanines with carbohydrates and to obtain new sophisticated molecules; in such way, new systems with significant potential applications become available. This review highlights recent developments on the synthesis of phthalocyanine, subphthalocyanine, and porphyrazine derivatives where CuAAC reactions are the key synthetic step.https://www.mdpi.com/1420-3049/25/7/1745azidesphthalocyaninessubphthalocyaninesporphyrazinesclick chemistryphotodynamic therapy |
spellingShingle | Ana R. L. Araújo Augusto C. Tomé Carla I. M. Santos Maria A. F. Faustino Maria G. P. M. S. Neves Mário M. Q. Simões Nuno M. M. Moura Sultan T. Abu-Orabi José A. S. Cavaleiro Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines Molecules azides phthalocyanines subphthalocyanines porphyrazines click chemistry photodynamic therapy |
title | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_full | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_fullStr | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_full_unstemmed | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_short | Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 2—Azides, Phthalocyanines, Subphthalocyanines and Porphyrazines |
title_sort | azides and porphyrinoids synthetic approaches and applications part 2 azides phthalocyanines subphthalocyanines and porphyrazines |
topic | azides phthalocyanines subphthalocyanines porphyrazines click chemistry photodynamic therapy |
url | https://www.mdpi.com/1420-3049/25/7/1745 |
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