Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate]
In the title polymer, {[Cu(C8H12N2O6P2)]·2H2O}n, the geometry of the five-coordinate CuII ion can best be described as slightly distorted square-pyramidal formed by one N and two O atoms of an N(CH2PO3H)2 group and one N atom from a pyridine ring. The elongated apex of the pyramid is oc...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811052512 |
| _version_ | 1819290624714604544 |
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| author | Shi-Yong Zhang Zhong-Gao Zhou Ke-Jun Wang |
| author_facet | Shi-Yong Zhang Zhong-Gao Zhou Ke-Jun Wang |
| author_sort | Shi-Yong Zhang |
| collection | DOAJ |
| description | In the title polymer, {[Cu(C8H12N2O6P2)]·2H2O}n, the geometry of the five-coordinate CuII ion can best be described as slightly distorted square-pyramidal formed by one N and two O atoms of an N(CH2PO3H)2 group and one N atom from a pyridine ring. The elongated apex of the pyramid is occupied by one O atom from a third diphosphonate ligand. The interconnection of Cu2+ ions by the diphosphonate ligands results in the formation of a double-chain array along the b axis, in which the two sub-chains are interlocked by pairs of PO3 groups. The outside of each sub-chain is decorated by other PO3 groups. These double chains are further assembled into a three-dimensional supramolecular architecture via a large number of O—H...O hydrogen bonds between the phosphonate groups and lattice water molecules. |
| first_indexed | 2024-12-24T03:25:42Z |
| format | Article |
| id | doaj.art-be2bccfd1e0343caa9256f4c57d34d85 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:25:42Z |
| publishDate | 2012-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-be2bccfd1e0343caa9256f4c57d34d852022-12-21T17:17:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681m38m3910.1107/S1600536811052512Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate]Shi-Yong ZhangZhong-Gao ZhouKe-Jun WangIn the title polymer, {[Cu(C8H12N2O6P2)]·2H2O}n, the geometry of the five-coordinate CuII ion can best be described as slightly distorted square-pyramidal formed by one N and two O atoms of an N(CH2PO3H)2 group and one N atom from a pyridine ring. The elongated apex of the pyramid is occupied by one O atom from a third diphosphonate ligand. The interconnection of Cu2+ ions by the diphosphonate ligands results in the formation of a double-chain array along the b axis, in which the two sub-chains are interlocked by pairs of PO3 groups. The outside of each sub-chain is decorated by other PO3 groups. These double chains are further assembled into a three-dimensional supramolecular architecture via a large number of O—H...O hydrogen bonds between the phosphonate groups and lattice water molecules.http://scripts.iucr.org/cgi-bin/paper?S1600536811052512 |
| spellingShingle | Shi-Yong Zhang Zhong-Gao Zhou Ke-Jun Wang Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate] Acta Crystallographica Section E |
| title | Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate] |
| title_full | Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate] |
| title_fullStr | Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate] |
| title_full_unstemmed | Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate] |
| title_short | Poly[[{μ3-dihydrogen [(pyridin-4-ylmethylimino)bis(methylene)]diphosphonato-κ5O:O′,N,O′′:N′}copper(II)] dihydrate] |
| title_sort | poly amp 956 3 dihydrogen pyridin 4 ylmethylimino bis methylene diphosphonato amp 954 5o o amp 8242 n o amp 8242 amp 8242 n amp 8242 copper ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811052512 |
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