UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal
Antibiotics are the most common pharmaceutical compounds, and they have been extensively used for the prevention and treatment of bacterial diseases for more than 50 years. However, merely a small fraction of antibiotics is metabolized in the body, while the rest is discharged into the environment t...
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2022-03-01
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author | Yeji Park Sanghyeon Kim Jungyeon Kim Sanaullah Khan Changseok Han |
author_facet | Yeji Park Sanghyeon Kim Jungyeon Kim Sanaullah Khan Changseok Han |
author_sort | Yeji Park |
collection | DOAJ |
description | Antibiotics are the most common pharmaceutical compounds, and they have been extensively used for the prevention and treatment of bacterial diseases for more than 50 years. However, merely a small fraction of antibiotics is metabolized in the body, while the rest is discharged into the environment through excretion, which can cause potential ecological problems and human health risks. In this study, the elimination of seventeen antibiotics from real livestock wastewater effluents was investigated by UV/TiO<sub>2</sub> advanced oxidation process. The effect of process parameters, such as TiO<sub>2</sub> loadings, solution pHs, and antibiotic concentrations, on the efficiency of the UV/TiO<sub>2</sub> process was assessed. The degradation efficiency was affected by the solution pH, and higher removal efficiency was observed at pH 5.8 and 9.9, while the catalyst loading had no significant effect on the degradation efficiency at these experimental conditions. UV photolysis showed a good removal efficiency of the antibiotics. However, the highest removal efficiency was shown by the UV/photocatalyst system due to their synergistic effects. The results showed that more than 90% of antibiotics were removed by UV/TiO<sub>2</sub> system during the 60 min illumination, while the corresponding TOC and COD removal was only 10 and 13%, respectively. The results of the current study indicated that UV/TiO<sub>2</sub> advanced oxidation process is a promising method for the elimination of various types of antibiotics from real livestock wastewater effluents. |
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spelling | doaj.art-be2eab1f9efb48cdbd60b4baab6992dd2023-11-30T22:49:48ZengMDPI AGWater2073-44412022-03-0114695810.3390/w14060958UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics RemovalYeji Park0Sanghyeon Kim1Jungyeon Kim2Sanaullah Khan3Changseok Han4Department of Environmental Engineering, INHA University, Incheon 22212, KoreaProgram in Environmental & Polymer Engineering, Graduate School of INHA University, INHA University, Incheon 22212, KoreaProgram in Environmental & Polymer Engineering, Graduate School of INHA University, INHA University, Incheon 22212, KoreaDepartment of Chemistry, Women University, Swabi 23430, PakistanDepartment of Environmental Engineering, INHA University, Incheon 22212, KoreaAntibiotics are the most common pharmaceutical compounds, and they have been extensively used for the prevention and treatment of bacterial diseases for more than 50 years. However, merely a small fraction of antibiotics is metabolized in the body, while the rest is discharged into the environment through excretion, which can cause potential ecological problems and human health risks. In this study, the elimination of seventeen antibiotics from real livestock wastewater effluents was investigated by UV/TiO<sub>2</sub> advanced oxidation process. The effect of process parameters, such as TiO<sub>2</sub> loadings, solution pHs, and antibiotic concentrations, on the efficiency of the UV/TiO<sub>2</sub> process was assessed. The degradation efficiency was affected by the solution pH, and higher removal efficiency was observed at pH 5.8 and 9.9, while the catalyst loading had no significant effect on the degradation efficiency at these experimental conditions. UV photolysis showed a good removal efficiency of the antibiotics. However, the highest removal efficiency was shown by the UV/photocatalyst system due to their synergistic effects. The results showed that more than 90% of antibiotics were removed by UV/TiO<sub>2</sub> system during the 60 min illumination, while the corresponding TOC and COD removal was only 10 and 13%, respectively. The results of the current study indicated that UV/TiO<sub>2</sub> advanced oxidation process is a promising method for the elimination of various types of antibiotics from real livestock wastewater effluents.https://www.mdpi.com/2073-4441/14/6/958livestock wastewater treatmentantibioticsadvanced oxidation processesUV/TiO<sub>2</sub> photocatalysis |
spellingShingle | Yeji Park Sanghyeon Kim Jungyeon Kim Sanaullah Khan Changseok Han UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal Water livestock wastewater treatment antibiotics advanced oxidation processes UV/TiO<sub>2</sub> photocatalysis |
title | UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal |
title_full | UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal |
title_fullStr | UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal |
title_full_unstemmed | UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal |
title_short | UV/TiO<sub>2</sub> Photocatalysis as an Efficient Livestock Wastewater Quaternary Treatment for Antibiotics Removal |
title_sort | uv tio sub 2 sub photocatalysis as an efficient livestock wastewater quaternary treatment for antibiotics removal |
topic | livestock wastewater treatment antibiotics advanced oxidation processes UV/TiO<sub>2</sub> photocatalysis |
url | https://www.mdpi.com/2073-4441/14/6/958 |
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