Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate

The title complex, [Ni2(C4H8N4O2)6](NO3)4·2CH4O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the NiII atoms is 3.962 (1) Å. The Ni atoms are in a sligh...

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Main Authors: Yu-Peng Pan, Da-Cheng Li, Da-Qi Wang
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807064148
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author Yu-Peng Pan
Da-Cheng Li
Da-Qi Wang
author_facet Yu-Peng Pan
Da-Cheng Li
Da-Qi Wang
author_sort Yu-Peng Pan
collection DOAJ
description The title complex, [Ni2(C4H8N4O2)6](NO3)4·2CH4O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the NiII atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octahedral coordination. Intermolecular N—H...O, N—H...N and O—H...O hydrogen bonds connect the ligands, solvent molecules and nitrate ions.
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spelling doaj.art-be30d6a08221457ca4e1bc714a0ae1862022-12-21T19:42:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m96m9710.1107/S1600536807064148Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvateYu-Peng PanDa-Cheng LiDa-Qi WangThe title complex, [Ni2(C4H8N4O2)6](NO3)4·2CH4O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the NiII atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octahedral coordination. Intermolecular N—H...O, N—H...N and O—H...O hydrogen bonds connect the ligands, solvent molecules and nitrate ions.http://scripts.iucr.org/cgi-bin/paper?S1600536807064148
spellingShingle Yu-Peng Pan
Da-Cheng Li
Da-Qi Wang
Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
Acta Crystallographica Section E
title Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
title_full Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
title_fullStr Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
title_full_unstemmed Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
title_short Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
title_sort bis 956 4 amino 3 5 bis hydroxymethyl 1 2 4 triazole bis bis 4 amino 3 5 bis hydroxymethyl 1 2 4 triazole nickel ii tetranitrate methanol disolvate
url http://scripts.iucr.org/cgi-bin/paper?S1600536807064148
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AT dachengli bis9564amino35bishydroxymethyl124triazolebisbis4amino35bishydroxymethyl124triazolenickeliitetranitratemethanoldisolvate
AT daqiwang bis9564amino35bishydroxymethyl124triazolebisbis4amino35bishydroxymethyl124triazolenickeliitetranitratemethanoldisolvate