Graphene-Based Contacts for Optoelectronic Devices

Hybrid transparent contacts based on combinations of a transparent conductive oxide and a few graphene monolayers were developed in order to evaluate their optical and electrical performance with the main aim to use them as front contacts in optoelectronic devices. The assessment of the most suitabl...

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Main Authors: Susana Fernández, Antonio Molinero, David Sanz, José Pablo González, Marina de la Cruz, José Javier Gandía, Julio Cárabe
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/11/10/919
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author Susana Fernández
Antonio Molinero
David Sanz
José Pablo González
Marina de la Cruz
José Javier Gandía
Julio Cárabe
author_facet Susana Fernández
Antonio Molinero
David Sanz
José Pablo González
Marina de la Cruz
José Javier Gandía
Julio Cárabe
author_sort Susana Fernández
collection DOAJ
description Hybrid transparent contacts based on combinations of a transparent conductive oxide and a few graphene monolayers were developed in order to evaluate their optical and electrical performance with the main aim to use them as front contacts in optoelectronic devices. The assessment of the most suitable strategies for their fabrication was performed by testing different protocols addressing such issues as the protection of the device structure underneath, the limitation of sample temperature during the graphene-monolayer transfer process and the determination of the most suitable stacking structure. Suitable metal ohmic electrodes were also evaluated. Among a number of options tested, the metal contact based on Ti + Ag showed the highest reproducibility and the lowest contact resistivity. Finally, with the objective of extracting the current generated from optoelectronic devices to the output pins of an external package, focusing on a near future commercial application, the electrical properties of the connections made with an ultrasonic bonding machine (sonic welding) between the optimized Ti + Ag metal contacts and Al or Au micro-wires were also evaluated. All these results have an enormous potential as hybrid electrodes based on graphene to be used in novel designs of a future generation of optoelectronic devices, such as solar cells.
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spelling doaj.art-be31498099b84ddeb789f8be1b4c45ce2023-11-20T15:49:14ZengMDPI AGMicromachines2072-666X2020-10-01111091910.3390/mi11100919Graphene-Based Contacts for Optoelectronic DevicesSusana Fernández0Antonio Molinero1David Sanz2José Pablo González3Marina de la Cruz4José Javier Gandía5Julio Cárabe6CIEMAT, Departamento de Energía, Unidad de Energía Solar Fotovoltaica, Avda. Complutense 40, 28040 Madrid, SpainCIEMAT, Departamento de Electrónica, Avda. Complutense 40, 28040 Madrid, SpainCIEMAT, Departamento de Electrónica, Avda. Complutense 40, 28040 Madrid, SpainCIEMAT, Departamento de Energía, Unidad de Energía Solar Fotovoltaica, Avda. Complutense 40, 28040 Madrid, SpainCIEMAT, Departamento de Energía, Unidad de Energía Solar Fotovoltaica, Avda. Complutense 40, 28040 Madrid, SpainCIEMAT, Departamento de Energía, Unidad de Energía Solar Fotovoltaica, Avda. Complutense 40, 28040 Madrid, SpainCIEMAT, Departamento de Energía, Unidad de Energía Solar Fotovoltaica, Avda. Complutense 40, 28040 Madrid, SpainHybrid transparent contacts based on combinations of a transparent conductive oxide and a few graphene monolayers were developed in order to evaluate their optical and electrical performance with the main aim to use them as front contacts in optoelectronic devices. The assessment of the most suitable strategies for their fabrication was performed by testing different protocols addressing such issues as the protection of the device structure underneath, the limitation of sample temperature during the graphene-monolayer transfer process and the determination of the most suitable stacking structure. Suitable metal ohmic electrodes were also evaluated. Among a number of options tested, the metal contact based on Ti + Ag showed the highest reproducibility and the lowest contact resistivity. Finally, with the objective of extracting the current generated from optoelectronic devices to the output pins of an external package, focusing on a near future commercial application, the electrical properties of the connections made with an ultrasonic bonding machine (sonic welding) between the optimized Ti + Ag metal contacts and Al or Au micro-wires were also evaluated. All these results have an enormous potential as hybrid electrodes based on graphene to be used in novel designs of a future generation of optoelectronic devices, such as solar cells.https://www.mdpi.com/2072-666X/11/10/919grapheneohmic contactoptoelectronic devices
spellingShingle Susana Fernández
Antonio Molinero
David Sanz
José Pablo González
Marina de la Cruz
José Javier Gandía
Julio Cárabe
Graphene-Based Contacts for Optoelectronic Devices
Micromachines
graphene
ohmic contact
optoelectronic devices
title Graphene-Based Contacts for Optoelectronic Devices
title_full Graphene-Based Contacts for Optoelectronic Devices
title_fullStr Graphene-Based Contacts for Optoelectronic Devices
title_full_unstemmed Graphene-Based Contacts for Optoelectronic Devices
title_short Graphene-Based Contacts for Optoelectronic Devices
title_sort graphene based contacts for optoelectronic devices
topic graphene
ohmic contact
optoelectronic devices
url https://www.mdpi.com/2072-666X/11/10/919
work_keys_str_mv AT susanafernandez graphenebasedcontactsforoptoelectronicdevices
AT antoniomolinero graphenebasedcontactsforoptoelectronicdevices
AT davidsanz graphenebasedcontactsforoptoelectronicdevices
AT josepablogonzalez graphenebasedcontactsforoptoelectronicdevices
AT marinadelacruz graphenebasedcontactsforoptoelectronicdevices
AT josejaviergandia graphenebasedcontactsforoptoelectronicdevices
AT juliocarabe graphenebasedcontactsforoptoelectronicdevices