(5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1)
The asymmetric unit of the title compound, [Co(C44H28N4)]·C12H24O6, contains one half of a CoII(TPP) (TPP is tetraphenylporphyrin) complex and one half of an 18-crown-6 molecule of crystallization, both lying on inversion centers. The CoII(TPP) complex exhibits a nearly planar conformat...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810012080 |
| _version_ | 1818887119494447104 |
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| author | Anissa Mansour Mohamed Salah Belkhiria Jean-Claude Daran Habib Nasri |
| author_facet | Anissa Mansour Mohamed Salah Belkhiria Jean-Claude Daran Habib Nasri |
| author_sort | Anissa Mansour |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Co(C44H28N4)]·C12H24O6, contains one half of a CoII(TPP) (TPP is tetraphenylporphyrin) complex and one half of an 18-crown-6 molecule of crystallization, both lying on inversion centers. The CoII(TPP) complex exhibits a nearly planar conformation of the porphyrinate core [maximum deviation = 0.069 (2) Å] with an average Co—N distance of 1.971 (4) Å. The distance between the Co atom and the closest O atom of the 18-crown-6 molecule is 2.533 (2) Å, indicating a short non-bonded contact between the Co atom and the crown ether molecule. An ethylene group of the 18-crown-6 molecule is disordered over two sites with occupancies of 0.565 (7) and 0.435 (7). |
| first_indexed | 2024-12-19T16:32:10Z |
| format | Article |
| id | doaj.art-be41cd8f46a04d3087804e685ae4acf1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:32:10Z |
| publishDate | 2010-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-be41cd8f46a04d3087804e685ae4acf12022-12-21T20:14:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m509m51010.1107/S1600536810012080(5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1)Anissa MansourMohamed Salah BelkhiriaJean-Claude DaranHabib NasriThe asymmetric unit of the title compound, [Co(C44H28N4)]·C12H24O6, contains one half of a CoII(TPP) (TPP is tetraphenylporphyrin) complex and one half of an 18-crown-6 molecule of crystallization, both lying on inversion centers. The CoII(TPP) complex exhibits a nearly planar conformation of the porphyrinate core [maximum deviation = 0.069 (2) Å] with an average Co—N distance of 1.971 (4) Å. The distance between the Co atom and the closest O atom of the 18-crown-6 molecule is 2.533 (2) Å, indicating a short non-bonded contact between the Co atom and the crown ether molecule. An ethylene group of the 18-crown-6 molecule is disordered over two sites with occupancies of 0.565 (7) and 0.435 (7).http://scripts.iucr.org/cgi-bin/paper?S1600536810012080 |
| spellingShingle | Anissa Mansour Mohamed Salah Belkhiria Jean-Claude Daran Habib Nasri (5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1) Acta Crystallographica Section E |
| title | (5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1) |
| title_full | (5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1) |
| title_fullStr | (5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1) |
| title_full_unstemmed | (5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1) |
| title_short | (5,10,15,20-Tetraphenylporphyrinato-κ4N)cobalt(II)–18-crown-6 (1/1) |
| title_sort | 5 10 15 20 tetraphenylporphyrinato amp 954 4n cobalt ii amp 8211 18 crown 6 1 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810012080 |
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