Visualizing the origin of rotational entropy effects in coadsorbed systems

Visualizing the origin of rotational entropy effects in coadsorbed systems

We demonstrate that significant entropic effects govern the stability of rotationally constrained molecular complexes on surfaces. Using a complementary combination of low-temperature scanning tunneling microscopy, temperature programmed desorption, and density functional theory calculations, we pro...

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Bibliographic Details
Main Authors:	Ryan T. Hannagan, Kyle Groden, Amanda M. Larson, Andrew J. Therrien, Theodore Thuening, Alex C. Schilling, Jean-Sabin McEwen, E. Charles H. Sykes
Format:	Article
Language:	English
Published:	American Physical Society 2020-06-01
Series:	Physical Review Research
Online Access:	http://doi.org/10.1103/PhysRevResearch.2.023326

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