Synthesis of new chiral auxiliares from carbohydrates for Et2AlCl-promoted Diels-Alder reactions

Synthesis of new chiral auxiliares from carbohydrates for Et2AlCl-promoted Diels-Alder reactions

Acrylates 3-O-acryloyl-4,5-di-O-benzoyl-1,2- O-isopropylidene-beta-D-fructopyranose (6) and 3-O-benzyl-5-O-acryloyl-1,2-O -isopropylidene-alpha-D-xylofuranose (8) were synthesized in few steps from carbohydrates to construct chiral dienophiles for asymmetric Diels-Alder reaction with cyclopentadiene...

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Bibliographic Details
Main Authors: Ferreira Vitor F., Pinheiro Sergio, Perrone Clarissa C., Costa Paulo R. R.
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2000-01-01
Series:Journal of the Brazilian Chemical Society
Subjects:
asymmetric Diels-Alder reactions
chiral dienophiles
carbohydrates
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300012

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http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532000000300012

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