Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy

In the hunt of new sustainable release agents for concrete removal with improved demoulding efficacy, oil-in-dispersion (OD) release agents have appeared as favourable emulsions, since they display augmented performance in contrast to conventional oil-in-water (O/W) emulsions. This work presents a n...

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Main Authors: Ansar Abbas, Chen Zhang, Guangwei Hu, Sameer Hussain, Ruixia Gao, Jing Li, Yang li, Silong Xu
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Chemical Engineering Journal Advances
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666821122001545
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author Ansar Abbas
Chen Zhang
Guangwei Hu
Sameer Hussain
Ruixia Gao
Jing Li
Yang li
Silong Xu
author_facet Ansar Abbas
Chen Zhang
Guangwei Hu
Sameer Hussain
Ruixia Gao
Jing Li
Yang li
Silong Xu
author_sort Ansar Abbas
collection DOAJ
description In the hunt of new sustainable release agents for concrete removal with improved demoulding efficacy, oil-in-dispersion (OD) release agents have appeared as favourable emulsions, since they display augmented performance in contrast to conventional oil-in-water (O/W) emulsions. This work presents a novel and facile methodology for sustainable preparation of OD release agent employing emulsifiers as active components to produce stable emulsion, leading to a superior and easier commercial product formulation. The new type of OD release agent is optimized by varying the composition of two food grade emulsifiers named as span-80 and AEO-3 from 2.4 to 7.4% in the formulation. The stability and performance of new OD release agents are studied comprehensively through various parameters like creaming index, viscosity, density, pH tests, water contact angle, droplet size and shape. After dilution five times with water, the OD based release agent containing 5.4–7.4% mixed emulsifier concentrations demonstrate excellent stability even after six months of storage and performed well in physico-chemical lab testing. Moreover, OD release agents showed good application results during on-field industrial trials on iron mould surfaces. The formulated OD release agents on the mould took only 12–15 min to generate a smooth and uniform film that was demoulded easily by sledgehammering about 3–5 times. Thus, easily prepared and highly stable OD release agent could be revolutionary in construction industry for sustainable and rapid removal of mould concrete with high efficacy.
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spelling doaj.art-be7e54c90cbf43b4a25e5a882f1dc79d2022-12-22T04:36:15ZengElsevierChemical Engineering Journal Advances2666-82112022-11-0112100394Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacyAnsar Abbas0Chen Zhang1Guangwei Hu2Sameer Hussain3Ruixia Gao4Jing Li5Yang li6Silong Xu7School of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, ChinaSchool of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, ChinaXi'an Saturn Technology Co., LTD., Xi'an 710049, ChinaSchool of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, ChinaSchool of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, ChinaSchool of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, ChinaSchool of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, China; Corresponding authors.School of Chemistry, and Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, Xi'an Jiaotong University, Xi'an 710049, China; Corresponding authors.In the hunt of new sustainable release agents for concrete removal with improved demoulding efficacy, oil-in-dispersion (OD) release agents have appeared as favourable emulsions, since they display augmented performance in contrast to conventional oil-in-water (O/W) emulsions. This work presents a novel and facile methodology for sustainable preparation of OD release agent employing emulsifiers as active components to produce stable emulsion, leading to a superior and easier commercial product formulation. The new type of OD release agent is optimized by varying the composition of two food grade emulsifiers named as span-80 and AEO-3 from 2.4 to 7.4% in the formulation. The stability and performance of new OD release agents are studied comprehensively through various parameters like creaming index, viscosity, density, pH tests, water contact angle, droplet size and shape. After dilution five times with water, the OD based release agent containing 5.4–7.4% mixed emulsifier concentrations demonstrate excellent stability even after six months of storage and performed well in physico-chemical lab testing. Moreover, OD release agents showed good application results during on-field industrial trials on iron mould surfaces. The formulated OD release agents on the mould took only 12–15 min to generate a smooth and uniform film that was demoulded easily by sledgehammering about 3–5 times. Thus, easily prepared and highly stable OD release agent could be revolutionary in construction industry for sustainable and rapid removal of mould concrete with high efficacy.http://www.sciencedirect.com/science/article/pii/S2666821122001545OD release agentEmulsionsSustainable formulationSurfactantsConcrete removalMould surface
spellingShingle Ansar Abbas
Chen Zhang
Guangwei Hu
Sameer Hussain
Ruixia Gao
Jing Li
Yang li
Silong Xu
Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy
Chemical Engineering Journal Advances
OD release agent
Emulsions
Sustainable formulation
Surfactants
Concrete removal
Mould surface
title Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy
title_full Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy
title_fullStr Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy
title_full_unstemmed Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy
title_short Facile formulation of sustainable and stable oil-in-dispersion emulsion: A release agent with high demoulding efficacy
title_sort facile formulation of sustainable and stable oil in dispersion emulsion a release agent with high demoulding efficacy
topic OD release agent
Emulsions
Sustainable formulation
Surfactants
Concrete removal
Mould surface
url http://www.sciencedirect.com/science/article/pii/S2666821122001545
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