| Summary: | Aggregate stability is a key factor in the evaluation of soil structure and erosion resistance, which is largely influenced by soil electric field and particle interaction. However, there are few studies on how different organic and inorganic soil conditioners change the surface electric field and interaction force of reclaimed soil to improve the aggregate stability. Therefore, a five-year field experiment was conducted to quantitatively study the effects of FeSO<sub>4</sub> (TM), organic fertilizer (TO), fly ash (TF), maturing agent + organic fertilizer (TMO) and fly ash + organic fertilizer (TFO), compared with control (CK) treatment, on the reclaimed soil internal force and the aggregate crushing strength. The results showed that the reclaimed soil surface potential and electric field intensity increased after 5 years of application of organic and inorganic soil conditioners. Under the same electrolyte concentration and electric field conditions, the crushing strength of aggregates (<5 μm) treated with TFO, TMO, TO, TF and TM decreased by 43.70%, 35.51%, 25.97%, 8.28% and 5.49%, respectively, compared with the control treatment, and the combination of organic and inorganic treatment (TFO and TMO) had a better effect on improving the aggregate crushing resistance. With the application of soil conditioners, the reclaimed soil DLVO force and net resultant force gradually decreased, and the order of magnitude was TFO < TMO < TO < TF < TM < CK, indicating that the application of organic and inorganic soil conditioners enhanced the van der Waals attractive force and net attractive force between reclaimed soil particles, and reduced the net repulsive force between particles. The theoretical calculation results of the reclaimed soil internal force well explain the experimental results of aggregate stability against crushing, and the relationship between aggregate crushing strength and net resultant force is exponential (<i>p</i> < 0.01). Generally speaking, the soil conditioners increase the net attractive force between particles, reduce the possibility of violent crushing of aggregates due to the increase of electric field intensity and improve the aggregate structural stability, among which the combined application of organic and inorganic soil conditioners has a better improvement effect. The results of this study will lay a theoretical foundation for clarifying the improvement of different soil conditioners on the reclaimed soil structural stability and erosion resistance.
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