Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions

The paper presents results of studies on the possibility of using the ultrafiltration method supported by sorption on low-cost, easily accessible aluminosilicates to purify water contaminated with radionuclides. An aqueous solution contaminated with radionuclides in the form of cations at different...

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Main Authors: Leon Fuks, Agnieszka Miśkiewicz, Grażyna Zakrzewska-Kołtuniewicz
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Chemistry
Subjects:
Online Access:https://www.mdpi.com/2624-8549/4/3/73
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author Leon Fuks
Agnieszka Miśkiewicz
Grażyna Zakrzewska-Kołtuniewicz
author_facet Leon Fuks
Agnieszka Miśkiewicz
Grażyna Zakrzewska-Kołtuniewicz
author_sort Leon Fuks
collection DOAJ
description The paper presents results of studies on the possibility of using the ultrafiltration method supported by sorption on low-cost, easily accessible aluminosilicates to purify water contaminated with radionuclides. An aqueous solution contaminated with radionuclides in the form of cations at different oxidation states—Cs(I)-137, Co(II)-60 and Am(III)-241—as well as pertechnetate anions—TcO<sub>4</sub><sup>−</sup>-99m—was treated by the proposed hybrid method. In the presented work, the influence of the important process parameters (i.e., pH, sorbent dosage, temperature and feed flow rate) on the removal efficiency of radionuclides was studied. The obtained results showed that hazardous impurities, both in the form of cations and anions, may be effectively removed from water by the application of sorption-assisted UF (SAUF) using the clay-salt slimes as a sorbent. As a final stage of the work, we treated the simulated liquid radioactive waste using the SAUF method, also showing satisfactory results in its purification efficiency.
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spelling doaj.art-beab95fc5d3c43fc97f49ce9d71260912023-11-23T15:35:32ZengMDPI AGChemistry2624-85492022-09-01431076109110.3390/chemistry4030073Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous SolutionsLeon Fuks0Agnieszka Miśkiewicz1Grażyna Zakrzewska-Kołtuniewicz2Centre for Radiochemistry and Nuclear Chemistry, Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warszawa, PolandCentre for Radiochemistry and Nuclear Chemistry, Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warszawa, PolandCentre for Radiochemistry and Nuclear Chemistry, Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warszawa, PolandThe paper presents results of studies on the possibility of using the ultrafiltration method supported by sorption on low-cost, easily accessible aluminosilicates to purify water contaminated with radionuclides. An aqueous solution contaminated with radionuclides in the form of cations at different oxidation states—Cs(I)-137, Co(II)-60 and Am(III)-241—as well as pertechnetate anions—TcO<sub>4</sub><sup>−</sup>-99m—was treated by the proposed hybrid method. In the presented work, the influence of the important process parameters (i.e., pH, sorbent dosage, temperature and feed flow rate) on the removal efficiency of radionuclides was studied. The obtained results showed that hazardous impurities, both in the form of cations and anions, may be effectively removed from water by the application of sorption-assisted UF (SAUF) using the clay-salt slimes as a sorbent. As a final stage of the work, we treated the simulated liquid radioactive waste using the SAUF method, also showing satisfactory results in its purification efficiency.https://www.mdpi.com/2624-8549/4/3/73water contaminationradioactive wastedecontaminationsorption-assisted ultrafiltrationSAUFlow-cost adsorbent
spellingShingle Leon Fuks
Agnieszka Miśkiewicz
Grażyna Zakrzewska-Kołtuniewicz
Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions
Chemistry
water contamination
radioactive waste
decontamination
sorption-assisted ultrafiltration
SAUF
low-cost adsorbent
title Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions
title_full Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions
title_fullStr Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions
title_full_unstemmed Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions
title_short Sorption-Assisted Ultrafiltration Hybrid Method for Treatment of the Radioactive Aqueous Solutions
title_sort sorption assisted ultrafiltration hybrid method for treatment of the radioactive aqueous solutions
topic water contamination
radioactive waste
decontamination
sorption-assisted ultrafiltration
SAUF
low-cost adsorbent
url https://www.mdpi.com/2624-8549/4/3/73
work_keys_str_mv AT leonfuks sorptionassistedultrafiltrationhybridmethodfortreatmentoftheradioactiveaqueoussolutions
AT agnieszkamiskiewicz sorptionassistedultrafiltrationhybridmethodfortreatmentoftheradioactiveaqueoussolutions
AT grazynazakrzewskakołtuniewicz sorptionassistedultrafiltrationhybridmethodfortreatmentoftheradioactiveaqueoussolutions