SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS
In the paper submicroparticles of strontium oxide and barium oxide were obtained by thermal decomposition of aerosols. The nature of the synthesized compounds was proved by IR spectroscopy. The characteristic linear dimensions were determined and the surface morphology of the particles was studied...
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| Format: | Article |
| Language: | English |
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Voronezh State University
2018-12-01
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| Series: | Конденсированные среды и межфазные границы |
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| _version_ | 1818152772400316416 |
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| author | Aleksandr I. Gorshkov Eugene N. Gribanov Emma R. Osckotskaya |
| author_facet | Aleksandr I. Gorshkov Eugene N. Gribanov Emma R. Osckotskaya |
| author_sort | Aleksandr I. Gorshkov |
| collection | DOAJ |
| description | In the paper submicroparticles of strontium oxide and barium oxide were obtained by thermal decomposition of aerosols. The nature of the synthesized compounds was proved by IR
spectroscopy. The characteristic linear dimensions were determined and the surface morphology of the particles was studied by atomic force microscopy. Analysis of the obtained AFM-frames shows that the formed particles have a shape close to spherical, and their size varies in the range of 115–560 nm, depending on the initial concentration of precursors. It is shown that during the pyrolysis the splitting of a drop of liquid occurs, and the resulting solid phase is hollow spheres. The optical band gap of the particles of strontium and barium oxides was determined on the basis of their diffuse refl ection spectra (DRS) along the edge of the main optical absorption band. It is in the ranges of
3.15–3.19 eV and 2.95–3.16 eV, respectively. We found a manifestation of the size effect associated with the interrelation of reducing the diameter of SrO and BaO particles and the narrowing of the characteristic absorption bands in the IR spectra, as well as the shift of the absorption edge in the DRS-spectra to the shortwave region, i.e. increasing the optical band gap. The data obtained are of interest in the further study of the properties of submicro- and nanostructures based on strontium oxide and barium oxide, as well as in the synthesis of new functional materials with improved complex properties. |
| first_indexed | 2024-12-11T14:00:02Z |
| format | Article |
| id | doaj.art-bec77360c2db480f8e43c2e945f281c1 |
| institution | Directory Open Access Journal |
| issn | 1606-867X 1606-867X |
| language | English |
| last_indexed | 2024-12-11T14:00:02Z |
| publishDate | 2018-12-01 |
| publisher | Voronezh State University |
| record_format | Article |
| series | Конденсированные среды и межфазные границы |
| spelling | doaj.art-bec77360c2db480f8e43c2e945f281c12022-12-22T01:03:54ZengVoronezh State UniversityКонденсированные среды и межфазные границы1606-867X1606-867X2018-12-0120457458010.17308/kcmf.2018.20/631SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLSAleksandr I. Gorshkov0Eugene N. Gribanov1Emma R. Osckotskaya2Graduate Student, Department of Сhemistry, Turgenev Orel State University, Orel, RussiaCand. Sci. (Chem.), Associate Professor of the Department of Сhemistry, Turgenev Orel State University, Orel, RussiaDr, Sci, (Chem.), Professor, Head of the Department of Сhemistry, Turgenev Orel State University, Orel, RussiaIn the paper submicroparticles of strontium oxide and barium oxide were obtained by thermal decomposition of aerosols. The nature of the synthesized compounds was proved by IR spectroscopy. The characteristic linear dimensions were determined and the surface morphology of the particles was studied by atomic force microscopy. Analysis of the obtained AFM-frames shows that the formed particles have a shape close to spherical, and their size varies in the range of 115–560 nm, depending on the initial concentration of precursors. It is shown that during the pyrolysis the splitting of a drop of liquid occurs, and the resulting solid phase is hollow spheres. The optical band gap of the particles of strontium and barium oxides was determined on the basis of their diffuse refl ection spectra (DRS) along the edge of the main optical absorption band. It is in the ranges of 3.15–3.19 eV and 2.95–3.16 eV, respectively. We found a manifestation of the size effect associated with the interrelation of reducing the diameter of SrO and BaO particles and the narrowing of the characteristic absorption bands in the IR spectra, as well as the shift of the absorption edge in the DRS-spectra to the shortwave region, i.e. increasing the optical band gap. The data obtained are of interest in the further study of the properties of submicro- and nanostructures based on strontium oxide and barium oxide, as well as in the synthesis of new functional materials with improved complex properties.strontium oxidebarium oxideband gappyrolysis. |
| spellingShingle | Aleksandr I. Gorshkov Eugene N. Gribanov Emma R. Osckotskaya SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS Конденсированные среды и межфазные границы strontium oxide barium oxide band gap pyrolysis. |
| title | SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS |
| title_full | SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS |
| title_fullStr | SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS |
| title_full_unstemmed | SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS |
| title_short | SYNTHESIS OF SrO AND BaO SUBMICROPARTICLES BY THE METHOD OF THERMAL DECOMPOSITION OF AEROSOLS |
| title_sort | synthesis of sro and bao submicroparticles by the method of thermal decomposition of aerosols |
| topic | strontium oxide barium oxide band gap pyrolysis. |
| work_keys_str_mv | AT aleksandrigorshkov synthesisofsroandbaosubmicroparticlesbythemethodofthermaldecompositionofaerosols AT eugenengribanov synthesisofsroandbaosubmicroparticlesbythemethodofthermaldecompositionofaerosols AT emmarosckotskaya synthesisofsroandbaosubmicroparticlesbythemethodofthermaldecompositionofaerosols |