Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications

In this paper magnetic properties of six TiO2 powders doped with 1, 5 and 10 mol% Fe and prepared by sol-gel method in two different ways were analysed. The size of the obtained TiO2:Fe particles was in the range 200–350 nm as it was confirmed by SEM and AFM techniques. The magnetization of nanopowd...

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Main Authors: Karen Oganisian, Agnieszka Hreniak, Andrzej Sikora, Dominika Gaworska-Koniarek, Agnieszka Iwan
Format: Article
Language:English
Published: University of Novi Sad 2015-03-01
Series:Processing and Application of Ceramics
Subjects:
Online Access:http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2027%2006.pdf
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author Karen Oganisian
Agnieszka Hreniak
Andrzej Sikora
Dominika Gaworska-Koniarek
Agnieszka Iwan
author_facet Karen Oganisian
Agnieszka Hreniak
Andrzej Sikora
Dominika Gaworska-Koniarek
Agnieszka Iwan
author_sort Karen Oganisian
collection DOAJ
description In this paper magnetic properties of six TiO2 powders doped with 1, 5 and 10 mol% Fe and prepared by sol-gel method in two different ways were analysed. The size of the obtained TiO2:Fe particles was in the range 200–350 nm as it was confirmed by SEM and AFM techniques. The magnetization of nanopowders was measured as a function of temperature (1.8–300 K) and applied magnetic field. The samples with low Fe content manifest superparamagnetic dependence of magnetization. Whereas, the other compounds exhibit the paramagnetic behaviour with the negative Curie temperature, that suggests the antiferromagnetic ordering. Mass susceptibility decreased with the increase of Fe content as an effect of reduction of the mobility and number of charge carriers. The measurements showed that magnetic properties are correlated much stronger with the synthesis method than with the grain size.
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spelling doaj.art-bee883ab86e64c019d9977b3a29e04482022-12-22T01:16:33ZengUniversity of Novi SadProcessing and Application of Ceramics1820-61312406-10342015-03-0191435110.2298/PAC1501043OSynthesis of iron doped titanium dioxide by sol-gel method for magnetic applicationsKaren Oganisian0Agnieszka Hreniak1Andrzej Sikora2Dominika Gaworska-Koniarek3Agnieszka Iwan4Institute of Low Temperature and Structure Research, PAS, Okolna 2, 50-422 Wroclaw, PolandElectrotechnical Institute, Division of Electrotechnology and Materials Science, M. Sklodowskiej-Curie 55/61 Street, 50-369 Wroclaw, PolandElectrotechnical Institute, Division of Electrotechnology and Materials Science, M. Sklodowskiej-Curie 55/61 Street, 50-369 Wroclaw, PolandElectrotechnical Institute, Division of Electrotechnology and Materials Science, M. Sklodowskiej-Curie 55/61 Street, 50-369 Wroclaw, PolandElectrotechnical Institute, Division of Electrotechnology and Materials Science, M. Sklodowskiej-Curie 55/61 Street, 50-369 Wroclaw, PolandIn this paper magnetic properties of six TiO2 powders doped with 1, 5 and 10 mol% Fe and prepared by sol-gel method in two different ways were analysed. The size of the obtained TiO2:Fe particles was in the range 200–350 nm as it was confirmed by SEM and AFM techniques. The magnetization of nanopowders was measured as a function of temperature (1.8–300 K) and applied magnetic field. The samples with low Fe content manifest superparamagnetic dependence of magnetization. Whereas, the other compounds exhibit the paramagnetic behaviour with the negative Curie temperature, that suggests the antiferromagnetic ordering. Mass susceptibility decreased with the increase of Fe content as an effect of reduction of the mobility and number of charge carriers. The measurements showed that magnetic properties are correlated much stronger with the synthesis method than with the grain size.http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2027%2006.pdfTiO2Fe-dopingnanoparticlesAFMmagnetic properties
spellingShingle Karen Oganisian
Agnieszka Hreniak
Andrzej Sikora
Dominika Gaworska-Koniarek
Agnieszka Iwan
Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications
Processing and Application of Ceramics
TiO2
Fe-doping
nanoparticles
AFM
magnetic properties
title Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications
title_full Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications
title_fullStr Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications
title_full_unstemmed Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications
title_short Synthesis of iron doped titanium dioxide by sol-gel method for magnetic applications
title_sort synthesis of iron doped titanium dioxide by sol gel method for magnetic applications
topic TiO2
Fe-doping
nanoparticles
AFM
magnetic properties
url http://www.tf.uns.ac.rs/publikacije/PAC/pdf/PAC%2027%2006.pdf
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AT andrzejsikora synthesisofirondopedtitaniumdioxidebysolgelmethodformagneticapplications
AT dominikagaworskakoniarek synthesisofirondopedtitaniumdioxidebysolgelmethodformagneticapplications
AT agnieszkaiwan synthesisofirondopedtitaniumdioxidebysolgelmethodformagneticapplications