Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate
The hydrated title salt, [CoCl(C6H6FN)(C2H8N2)2]Cl2·H2O, comprises of one chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) cation, two chloride counter-anions and a water molecule of crystallization. The CoIII ion has a distorted octahedral environment and is surrounded by four N atoms in...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-03-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619003274 |
| _version_ | 1818974950280658944 |
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| author | A. SubbiahPandi Y. AaminaNaaz C. Maharaja Mahalakshmi K. Anbalagan |
| author_facet | A. SubbiahPandi Y. AaminaNaaz C. Maharaja Mahalakshmi K. Anbalagan |
| author_sort | A. SubbiahPandi |
| collection | DOAJ |
| description | The hydrated title salt, [CoCl(C6H6FN)(C2H8N2)2]Cl2·H2O, comprises of one chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) cation, two chloride counter-anions and a water molecule of crystallization. The CoIII ion has a distorted octahedral environment and is surrounded by four N atoms in the equatorial plane, with a fifth N atom and one Cl− ligand occupying the axial positions. One of the methylene C groups in one of the ethane-1,2-diamine ligands is disordered over two set of sites in a 0.832 (10):0.168 (10) ratio. In the crystal, the complex cation, the two counter-anions and the water molecule of crystallization are linked via N—H...Cl, O—H...Cl and C—H...Cl hydrogen bonds, generating rings with R42(8), R21(6), R42(10) and R22(6) graph-set motifs within a three-dimensional network. |
| first_indexed | 2024-12-20T15:48:12Z |
| format | Article |
| id | doaj.art-bef821468d144dbe8750a3287c42fa56 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T15:48:12Z |
| publishDate | 2019-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-bef821468d144dbe8750a3287c42fa562022-12-21T19:34:49ZengInternational Union of CrystallographyIUCrData2414-31462019-03-0143x19032710.1107/S2414314619003274wm4097Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrateA. SubbiahPandi0Y. AaminaNaaz1C. Maharaja Mahalakshmi2K. Anbalagan3Department of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaDepartment of Chemistry, Chellammal Womens College, Chennai 600 032, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaThe hydrated title salt, [CoCl(C6H6FN)(C2H8N2)2]Cl2·H2O, comprises of one chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) cation, two chloride counter-anions and a water molecule of crystallization. The CoIII ion has a distorted octahedral environment and is surrounded by four N atoms in the equatorial plane, with a fifth N atom and one Cl− ligand occupying the axial positions. One of the methylene C groups in one of the ethane-1,2-diamine ligands is disordered over two set of sites in a 0.832 (10):0.168 (10) ratio. In the crystal, the complex cation, the two counter-anions and the water molecule of crystallization are linked via N—H...Cl, O—H...Cl and C—H...Cl hydrogen bonds, generating rings with R42(8), R21(6), R42(10) and R22(6) graph-set motifs within a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S2414314619003274crystal structureethane-1,2-diaminefluoroaniline ligandcobalt(III) complexhydrogen bondingC—H...Cl interactions |
| spellingShingle | A. SubbiahPandi Y. AaminaNaaz C. Maharaja Mahalakshmi K. Anbalagan Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate IUCrData crystal structure ethane-1,2-diamine fluoroaniline ligand cobalt(III) complex hydrogen bonding C—H...Cl interactions |
| title | Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate |
| title_full | Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate |
| title_fullStr | Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate |
| title_full_unstemmed | Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate |
| title_short | Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate |
| title_sort | chloridobis ethane 1 2 diamine 4 fluoroaniline cobalt iii dichloride monohydrate |
| topic | crystal structure ethane-1,2-diamine fluoroaniline ligand cobalt(III) complex hydrogen bonding C—H...Cl interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619003274 |
| work_keys_str_mv | AT asubbiahpandi chloridobisethane12diamine4fluoroanilinecobaltiiidichloridemonohydrate AT yaaminanaaz chloridobisethane12diamine4fluoroanilinecobaltiiidichloridemonohydrate AT cmaharajamahalakshmi chloridobisethane12diamine4fluoroanilinecobaltiiidichloridemonohydrate AT kanbalagan chloridobisethane12diamine4fluoroanilinecobaltiiidichloridemonohydrate |