Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate
In the molecule of the title compound, C9H11N3O5S, the thiazole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral ang...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809007661 |
| _version_ | 1818791843127623680 |
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| author | Shahzad Sharif M. Nawaz Tahir Islam Ullah Khan Sarfraz Ahmad Manan Ayub Salariya |
| author_facet | Shahzad Sharif M. Nawaz Tahir Islam Ullah Khan Sarfraz Ahmad Manan Ayub Salariya |
| author_sort | Shahzad Sharif |
| collection | DOAJ |
| description | In the molecule of the title compound, C9H11N3O5S, the thiazole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, intermolecular N—H...N, N—H...O and C—H...O hydrogen bonds link the molecules along the a axis, through R22(8) and R22(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thiazole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure. |
| first_indexed | 2024-12-18T15:17:47Z |
| format | Article |
| id | doaj.art-bf20a6359380457f9bb92ef1de9d548b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T15:17:47Z |
| publishDate | 2009-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-bf20a6359380457f9bb92ef1de9d548b2022-12-21T21:03:29ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654o713o71310.1107/S1600536809007661Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoateShahzad SharifM. Nawaz TahirIslam Ullah KhanSarfraz AhmadManan Ayub SalariyaIn the molecule of the title compound, C9H11N3O5S, the thiazole ring is oriented at dihedral angles of 87.33 (3) and 87.18 (3)° with respect to the planar (r.m.s. deviations 0.0136 and 0.0139 Å) methyl ester groups. The dihedral angle between the methyl ester groups is 44.20 (3)°. In the crystal structure, intermolecular N—H...N, N—H...O and C—H...O hydrogen bonds link the molecules along the a axis, through R22(8) and R22(22) ring motifs, forming infinite two-dimensional polymeric sheets. π–π Contacts between the thiazole rings [centroid–centroid distance = 3.536 (2) Å] may further stabilize the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809007661 |
| spellingShingle | Shahzad Sharif M. Nawaz Tahir Islam Ullah Khan Sarfraz Ahmad Manan Ayub Salariya Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate Acta Crystallographica Section E |
| title | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
| title_full | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
| title_fullStr | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
| title_full_unstemmed | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
| title_short | Methyl 2-(2-amino-1,3-thiazol-4-yl)-2-[(Z)-methoxycarbonylmethoxyimino]ethanoate |
| title_sort | methyl 2 2 amino 1 3 thiazol 4 yl 2 z methoxycarbonylmethoxyimino ethanoate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809007661 |
| work_keys_str_mv | AT shahzadsharif methyl22amino13thiazol4yl2zmethoxycarbonylmethoxyiminoethanoate AT mnawaztahir methyl22amino13thiazol4yl2zmethoxycarbonylmethoxyiminoethanoate AT islamullahkhan methyl22amino13thiazol4yl2zmethoxycarbonylmethoxyiminoethanoate AT sarfrazahmad methyl22amino13thiazol4yl2zmethoxycarbonylmethoxyiminoethanoate AT mananayubsalariya methyl22amino13thiazol4yl2zmethoxycarbonylmethoxyiminoethanoate |