Environmental Life Cycle Assessment of Ammonia-Based Electricity

In recent years, several researchers have studied the potential use of ammonia (NH<sub>3</sub>) as an energy vector, focused on the techno-economic advantages and challenges for full global deployment. The use of ammonia as fuel is seen as a strategy to support decarbonization; however,...

Full description

Bibliographic Details
Main Authors: Andrea J. Boero, Kevin Kardux, Marina Kovaleva, Daniel A. Salas, Jacco Mooijer, Syed Mashruk, Michael Townsend, Kevin Rouwenhorst, Agustin Valera-Medina, Angel D. Ramirez
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/14/20/6721
_version_ 1797514735362506752
author Andrea J. Boero
Kevin Kardux
Marina Kovaleva
Daniel A. Salas
Jacco Mooijer
Syed Mashruk
Michael Townsend
Kevin Rouwenhorst
Agustin Valera-Medina
Angel D. Ramirez
author_facet Andrea J. Boero
Kevin Kardux
Marina Kovaleva
Daniel A. Salas
Jacco Mooijer
Syed Mashruk
Michael Townsend
Kevin Rouwenhorst
Agustin Valera-Medina
Angel D. Ramirez
author_sort Andrea J. Boero
collection DOAJ
description In recent years, several researchers have studied the potential use of ammonia (NH<sub>3</sub>) as an energy vector, focused on the techno-economic advantages and challenges for full global deployment. The use of ammonia as fuel is seen as a strategy to support decarbonization; however, to confirm the sustainability of the shift to ammonia as fuel in thermal engines, a study of the environmental profile is needed. This paper aims to assess the environmental life cycle impacts of ammonia-based electricity generated in a combined heat and power cycle for different ammonia production pathways. A cradle-to-gate assessment was developed for both ammonia production and ammonia-based electricity generation. The results show that electrolysis-based ammonia from renewable and nuclear energy have a better profile in terms of global warming potential (0.09–0.70 t CO<sub>2</sub>-eq/t NH<sub>3</sub>), fossil depletion potential (3.62–213.56 kg oil-eq/t NH<sub>3</sub>), and ozone depletion potential (0.001–0.082 g CFC-11-eq/t NH<sub>3</sub>). In addition, surplus heat for district or industrial applications offsets some of the environmental burden, such as a more than 29% reduction in carbon footprint. In general, ammonia-based combined heat and power production presents a favorable environmental profile, for example, the carbon footprint ranges from −0.480 to 0.003 kg CO<sub>2</sub>-eq/kWh.
first_indexed 2024-03-10T06:35:57Z
format Article
id doaj.art-bf4fb83d262c4ff4a6e31fe7e400db9b
institution Directory Open Access Journal
issn 1996-1073
language English
last_indexed 2024-03-10T06:35:57Z
publishDate 2021-10-01
publisher MDPI AG
record_format Article
series Energies
spelling doaj.art-bf4fb83d262c4ff4a6e31fe7e400db9b2023-11-22T18:07:43ZengMDPI AGEnergies1996-10732021-10-011420672110.3390/en14206721Environmental Life Cycle Assessment of Ammonia-Based ElectricityAndrea J. Boero0Kevin Kardux1Marina Kovaleva2Daniel A. Salas3Jacco Mooijer4Syed Mashruk5Michael Townsend6Kevin Rouwenhorst7Agustin Valera-Medina8Angel D. Ramirez9Facultad de Ingeniería en Mecánica y Ciencias de la Producción, Escuela Superior Politecnica del Litoral, ESPOL, Campus Gustavo Galindo, Km 30.5 Vía Perimetral, P.O. Box 13 09-01-5863, Guayaquil 090902, EcuadorProton Ventures, Karel Doormanweg 5, 3115 JD Schiedam, The NetherlandsCollege of Physical Sciences and Engineering, Cardiff University, Cardiff CF24 3AA, UKFacultad de Ingeniería en Mecánica y Ciencias de la Producción, Escuela Superior Politecnica del Litoral, ESPOL, Campus Gustavo Galindo, Km 30.5 Vía Perimetral, P.O. Box 13 09-01-5863, Guayaquil 090902, EcuadorProton Ventures, Karel Doormanweg 5, 3115 JD Schiedam, The NetherlandsCollege of Physical Sciences and Engineering, Cardiff University, Cardiff CF24 3AA, UKFacultad de Ingeniería en Mecánica y Ciencias de la Producción, Escuela Superior Politecnica del Litoral, ESPOL, Campus Gustavo Galindo, Km 30.5 Vía Perimetral, P.O. Box 13 09-01-5863, Guayaquil 090902, EcuadorProton Ventures, Karel Doormanweg 5, 3115 JD Schiedam, The NetherlandsCollege of Physical Sciences and Engineering, Cardiff University, Cardiff CF24 3AA, UKFacultad de Ingeniería en Mecánica y Ciencias de la Producción, Escuela Superior Politecnica del Litoral, ESPOL, Campus Gustavo Galindo, Km 30.5 Vía Perimetral, P.O. Box 13 09-01-5863, Guayaquil 090902, EcuadorIn recent years, several researchers have studied the potential use of ammonia (NH<sub>3</sub>) as an energy vector, focused on the techno-economic advantages and challenges for full global deployment. The use of ammonia as fuel is seen as a strategy to support decarbonization; however, to confirm the sustainability of the shift to ammonia as fuel in thermal engines, a study of the environmental profile is needed. This paper aims to assess the environmental life cycle impacts of ammonia-based electricity generated in a combined heat and power cycle for different ammonia production pathways. A cradle-to-gate assessment was developed for both ammonia production and ammonia-based electricity generation. The results show that electrolysis-based ammonia from renewable and nuclear energy have a better profile in terms of global warming potential (0.09–0.70 t CO<sub>2</sub>-eq/t NH<sub>3</sub>), fossil depletion potential (3.62–213.56 kg oil-eq/t NH<sub>3</sub>), and ozone depletion potential (0.001–0.082 g CFC-11-eq/t NH<sub>3</sub>). In addition, surplus heat for district or industrial applications offsets some of the environmental burden, such as a more than 29% reduction in carbon footprint. In general, ammonia-based combined heat and power production presents a favorable environmental profile, for example, the carbon footprint ranges from −0.480 to 0.003 kg CO<sub>2</sub>-eq/kWh.https://www.mdpi.com/1996-1073/14/20/6721ammoniahydrogenLCAcarbon footprintenvironmental impactgreen ammonia
spellingShingle Andrea J. Boero
Kevin Kardux
Marina Kovaleva
Daniel A. Salas
Jacco Mooijer
Syed Mashruk
Michael Townsend
Kevin Rouwenhorst
Agustin Valera-Medina
Angel D. Ramirez
Environmental Life Cycle Assessment of Ammonia-Based Electricity
Energies
ammonia
hydrogen
LCA
carbon footprint
environmental impact
green ammonia
title Environmental Life Cycle Assessment of Ammonia-Based Electricity
title_full Environmental Life Cycle Assessment of Ammonia-Based Electricity
title_fullStr Environmental Life Cycle Assessment of Ammonia-Based Electricity
title_full_unstemmed Environmental Life Cycle Assessment of Ammonia-Based Electricity
title_short Environmental Life Cycle Assessment of Ammonia-Based Electricity
title_sort environmental life cycle assessment of ammonia based electricity
topic ammonia
hydrogen
LCA
carbon footprint
environmental impact
green ammonia
url https://www.mdpi.com/1996-1073/14/20/6721
work_keys_str_mv AT andreajboero environmentallifecycleassessmentofammoniabasedelectricity
AT kevinkardux environmentallifecycleassessmentofammoniabasedelectricity
AT marinakovaleva environmentallifecycleassessmentofammoniabasedelectricity
AT danielasalas environmentallifecycleassessmentofammoniabasedelectricity
AT jaccomooijer environmentallifecycleassessmentofammoniabasedelectricity
AT syedmashruk environmentallifecycleassessmentofammoniabasedelectricity
AT michaeltownsend environmentallifecycleassessmentofammoniabasedelectricity
AT kevinrouwenhorst environmentallifecycleassessmentofammoniabasedelectricity
AT agustinvaleramedina environmentallifecycleassessmentofammoniabasedelectricity
AT angeldramirez environmentallifecycleassessmentofammoniabasedelectricity