On Higher Order Structures in Thermodynamics

We present the development of the approach to thermodynamics based on measurement. First of all, we recall that considering classical thermodynamics as a theory of measurement of extensive variables one gets the description of thermodynamic states as Legendrian or Lagrangian manifolds representing t...

Full description

Bibliographic Details
Main Authors: Valentin Lychagin, Mikhail Roop
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/22/10/1147
_version_ 1797551240400338944
author Valentin Lychagin
Mikhail Roop
author_facet Valentin Lychagin
Mikhail Roop
author_sort Valentin Lychagin
collection DOAJ
description We present the development of the approach to thermodynamics based on measurement. First of all, we recall that considering classical thermodynamics as a theory of measurement of extensive variables one gets the description of thermodynamic states as Legendrian or Lagrangian manifolds representing the average of measurable quantities and extremal measures. Secondly, the variance of random vectors induces the Riemannian structures on the corresponding manifolds. Computing higher order central moments, one drives to the corresponding higher order structures, namely the cubic and the fourth order forms. The cubic form is responsible for the skewness of the extremal distribution. The condition for it to be zero gives us so-called symmetric processes. The positivity of the fourth order structure gives us an additional requirement to thermodynamic state.
first_indexed 2024-03-10T15:41:46Z
format Article
id doaj.art-bf535edcf4034eadb0b4b3e554434fa1
institution Directory Open Access Journal
issn 1099-4300
language English
last_indexed 2024-03-10T15:41:46Z
publishDate 2020-10-01
publisher MDPI AG
record_format Article
series Entropy
spelling doaj.art-bf535edcf4034eadb0b4b3e554434fa12023-11-20T16:47:48ZengMDPI AGEntropy1099-43002020-10-012210114710.3390/e22101147On Higher Order Structures in ThermodynamicsValentin Lychagin0Mikhail Roop1V.A. Trapeznikov Institute of Control Sciences of Russian Academy of Sciences, 65 Profsoyuznaya Str., 117997 Moscow, RussiaV.A. Trapeznikov Institute of Control Sciences of Russian Academy of Sciences, 65 Profsoyuznaya Str., 117997 Moscow, RussiaWe present the development of the approach to thermodynamics based on measurement. First of all, we recall that considering classical thermodynamics as a theory of measurement of extensive variables one gets the description of thermodynamic states as Legendrian or Lagrangian manifolds representing the average of measurable quantities and extremal measures. Secondly, the variance of random vectors induces the Riemannian structures on the corresponding manifolds. Computing higher order central moments, one drives to the corresponding higher order structures, namely the cubic and the fourth order forms. The cubic form is responsible for the skewness of the extremal distribution. The condition for it to be zero gives us so-called symmetric processes. The positivity of the fourth order structure gives us an additional requirement to thermodynamic state.https://www.mdpi.com/1099-4300/22/10/1147thermodynamic statesLegendrian and Lagrangian manifoldsvarianceskewness
spellingShingle Valentin Lychagin
Mikhail Roop
On Higher Order Structures in Thermodynamics
Entropy
thermodynamic states
Legendrian and Lagrangian manifolds
variance
skewness
title On Higher Order Structures in Thermodynamics
title_full On Higher Order Structures in Thermodynamics
title_fullStr On Higher Order Structures in Thermodynamics
title_full_unstemmed On Higher Order Structures in Thermodynamics
title_short On Higher Order Structures in Thermodynamics
title_sort on higher order structures in thermodynamics
topic thermodynamic states
Legendrian and Lagrangian manifolds
variance
skewness
url https://www.mdpi.com/1099-4300/22/10/1147
work_keys_str_mv AT valentinlychagin onhigherorderstructuresinthermodynamics
AT mikhailroop onhigherorderstructuresinthermodynamics