Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario

A photochemical-transport two-dimensional model has been used to assess the impact of a projected fleet of high-speed stratospheric aircraft using different emissions scenarios. It is shown that the presence in the background atmosphere of nitric acid trihydrate aerosols is responsible for a low...

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Main Authors: G. Pitari, S. Palermi, G. Visconti
Format: Article
Language:English
Published: Copernicus Publications 1994-08-01
Series:Annales Geophysicae
Online Access:https://www.ann-geophys.net/12/996/1994/angeo-12-996-1994.pdf
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author G. Pitari
S. Palermi
G. Visconti
author_facet G. Pitari
S. Palermi
G. Visconti
author_sort G. Pitari
collection DOAJ
description A photochemical-transport two-dimensional model has been used to assess the impact of a projected fleet of high-speed stratospheric aircraft using different emissions scenarios. It is shown that the presence in the background atmosphere of nitric acid trihydrate aerosols is responsible for a lower stratospheric denoxification in addition to that caused by the sulfate aerosol layer. This has the effect of further decreasing the relative role of the odd nitrogen catalytic cycle for ozone destruction, so that the lower stratosphere is primarily controlled by chlorine species. The effect of aircraft injection of nitric oxides is that of decreasing the level of ClO, so that the lower stratospheric ozone (below about 20-25 km altitude) increases. The net effect on global ozone is that of a small increase even at Mach 2.4, and is enhanced by adopting emission scenarios including altitude restriction at 15 or 18 km. Reductions of the emission index (EI) of nitric oxides below relatively small values (about 15) are shown to reduce the aircraft-induced ozone increase, because of the associated smaller decrease of ClO. This conclusion is no more valid when the emission index is raised at the present values (about 45).
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spelling doaj.art-bf682a45af2a45ae90716d3abfa8d3162022-12-21T22:49:13ZengCopernicus PublicationsAnnales Geophysicae0992-76891432-05761994-08-0112996100510.1007/s00585-994-0996-1Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenarioG. PitariS. PalermiG. ViscontiA photochemical-transport two-dimensional model has been used to assess the impact of a projected fleet of high-speed stratospheric aircraft using different emissions scenarios. It is shown that the presence in the background atmosphere of nitric acid trihydrate aerosols is responsible for a lower stratospheric denoxification in addition to that caused by the sulfate aerosol layer. This has the effect of further decreasing the relative role of the odd nitrogen catalytic cycle for ozone destruction, so that the lower stratosphere is primarily controlled by chlorine species. The effect of aircraft injection of nitric oxides is that of decreasing the level of ClO, so that the lower stratospheric ozone (below about 20-25 km altitude) increases. The net effect on global ozone is that of a small increase even at Mach 2.4, and is enhanced by adopting emission scenarios including altitude restriction at 15 or 18 km. Reductions of the emission index (EI) of nitric oxides below relatively small values (about 15) are shown to reduce the aircraft-induced ozone increase, because of the associated smaller decrease of ClO. This conclusion is no more valid when the emission index is raised at the present values (about 45).https://www.ann-geophys.net/12/996/1994/angeo-12-996-1994.pdf
spellingShingle G. Pitari
S. Palermi
G. Visconti
Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario
Annales Geophysicae
title Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario
title_full Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario
title_fullStr Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario
title_full_unstemmed Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario
title_short Impact on ozone of high-speed stratospheric aircraft: effects of the emission scenario
title_sort impact on ozone of high speed stratospheric aircraft effects of the emission scenario
url https://www.ann-geophys.net/12/996/1994/angeo-12-996-1994.pdf
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