SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)

Seven molybdato and hydrogenomolybdato new adducts with HgPh2, HgCl2, HgBr2, CdCl2, CdBr2 and SbF3 have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the oxyanions behaving as polychelating ligands. When non symmetrical cations are involved, supr...

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Main Authors: Mounirou Ciss, Djibril Fall, Libasse Diop, Ibrahima Cissé, Serigne Fallou Pouye
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2012-03-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/dwnl.php?id=CSCC6201201V01S01A0005
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author Mounirou Ciss
Djibril Fall
Libasse Diop
Ibrahima Cissé
Serigne Fallou Pouye
author_facet Mounirou Ciss
Djibril Fall
Libasse Diop
Ibrahima Cissé
Serigne Fallou Pouye
author_sort Mounirou Ciss
collection DOAJ
description Seven molybdato and hydrogenomolybdato new adducts with HgPh2, HgCl2, HgBr2, CdCl2, CdBr2 and SbF3 have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the oxyanions behaving as polychelating ligands. When non symmetrical cations are involved, supramolecular architectures are obtained.
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language English
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publishDate 2012-03-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj.art-bfa660d960f54b3cbeb1090dcd5d85c12025-03-02T00:48:04ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2012-03-011314348SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)Mounirou CissDjibril FallLibasse DiopIbrahima CisséSerigne Fallou PouyeSeven molybdato and hydrogenomolybdato new adducts with HgPh2, HgCl2, HgBr2, CdCl2, CdBr2 and SbF3 have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the oxyanions behaving as polychelating ligands. When non symmetrical cations are involved, supramolecular architectures are obtained.http://pubs.ub.ro/dwnl.php?id=CSCC6201201V01S01A0005coordinating molybdatediscrete structureIR spectra
spellingShingle Mounirou Ciss
Djibril Fall
Libasse Diop
Ibrahima Cissé
Serigne Fallou Pouye
SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
coordinating molybdate
discrete structure
IR spectra
title SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)
title_full SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)
title_fullStr SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)
title_full_unstemmed SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)
title_short SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2 (M = Cd, Hg; X = Cl, Br)
title_sort synthesis and infrared study of some hydrogenomolybdato and molybdato adducts of sbf3 hgph2 and mx2 m cd hg x cl br
topic coordinating molybdate
discrete structure
IR spectra
url http://pubs.ub.ro/dwnl.php?id=CSCC6201201V01S01A0005
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