Crystal structure of catena-poly[[copper(II)-μ2-salicylato-[diaquacopper(II)]-μ2-salicylato] dihydrate]
The title compound, {[Cu2(C7H4O3)2(H2O)2]·2H2O}n, contains two copper(II) cations in special positions (one on a twofold rotation axis and one on an inversion centre) and the the salicylate ligand in its dianionic form. By four- and six-coordinate metal coordination, chains are formed parallel to [0...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017000883 |
| Summary: | The title compound, {[Cu2(C7H4O3)2(H2O)2]·2H2O}n, contains two copper(II) cations in special positions (one on a twofold rotation axis and one on an inversion centre) and the the salicylate ligand in its dianionic form. By four- and six-coordinate metal coordination, chains are formed parallel to [001], which are extended by O—H...O hydrogen bonding into sheets extending parallel to (100). These sheets are weakly connected by O—H...O hydrogen bonding via the non-coordinating lattice water molecules into a three-dimensional network. |
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| ISSN: | 2056-9890 |