Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China

The properties of soil at disposal sites are very important for geological disposal of very low level radioactive waste in terms of U(VI). In this study, soil from a candidate very low level radioactive waste disposal site in China was evaluated for its capacity on uranium sorption. Specifi...

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Main Authors: Zuo Rui, Liu Li, Jiang Xiaoyan, Guan Xin, Teng Yanguo, Ding Fei, Yang Jie, Wang Jinsheng
Format: Article
Language:English
Published: VINCA Institute of Nuclear Sciences 2016-01-01
Series:Nuclear Technology and Radiation Protection
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1451-3994/2016/1451-39941603268Z.pdf
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author Zuo Rui
Liu Li
Jiang Xiaoyan
Guan Xin
Teng Yanguo
Ding Fei
Yang Jie
Wang Jinsheng
author_facet Zuo Rui
Liu Li
Jiang Xiaoyan
Guan Xin
Teng Yanguo
Ding Fei
Yang Jie
Wang Jinsheng
author_sort Zuo Rui
collection DOAJ
description The properties of soil at disposal sites are very important for geological disposal of very low level radioactive waste in terms of U(VI). In this study, soil from a candidate very low level radioactive waste disposal site in China was evaluated for its capacity on uranium sorption. Specifically, the equilibrium time, initial concentration, soil particle, pH, temperature, and carbonate were evaluated. The results indicated that after 15-20 days of sorption, the Kd value fluctuated and stabilized at 355-360 mL/g. The adsorptive capacity of uranium was increased as the initial uranium concentration increased, while it decreased as the soil particle size increased. The pH value played an important role in the U(VI) sorption onto soil, especially under alkaline conditions, and had a great effect on the sorption capacity of soil for uranium. Moreover, the presence of carbonate decreased the sorption of U(VI) onto soil because of the role of the strong complexation of carbonate with U(VI) in the groundwater. Overall, this study assessed the behavior of U(VI) sorption onto natural soil, which would be an important factor in the geological barrier of the repository, has contribution on mastering the characteristic of the adsorption of uranium in the particular soil media for the process of very low level radioactive waste disposal.
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spelling doaj.art-bfeecd8a012f41268fe65696f345f5832022-12-21T23:20:50ZengVINCA Institute of Nuclear SciencesNuclear Technology and Radiation Protection1451-39941452-81852016-01-0131326827610.2298/NTRP1603268Z1451-39941603268ZFactors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in ChinaZuo Rui0Liu Li1Jiang Xiaoyan2Guan Xin3Teng Yanguo4Ding Fei5Yang Jie6Wang Jinsheng7College of Water Sciences, Beijing Normal University, Beijing, China + Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing, ChinaCollege of Water Sciences, Beijing Normal University, Beijing, China + Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing, ChinaNational Institute for Radiological Protection, Chinese Centre for Disease Control and Prevention, Beijing, China,College of Water Sciences, Beijing Normal University, Beijing, China + Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing, ChinaCollege of Water Sciences, Beijing Normal University, Beijing, China + Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing, ChinaKey Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, College of Architecture and Civil Engineering, Beijing University of Technology, Beijing, ChinaCollege of Water Sciences, Beijing Normal University, Beijing, China + Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing, ChinaCollege of Water Sciences, Beijing Normal University, Beijing, China + Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing, ChinaThe properties of soil at disposal sites are very important for geological disposal of very low level radioactive waste in terms of U(VI). In this study, soil from a candidate very low level radioactive waste disposal site in China was evaluated for its capacity on uranium sorption. Specifically, the equilibrium time, initial concentration, soil particle, pH, temperature, and carbonate were evaluated. The results indicated that after 15-20 days of sorption, the Kd value fluctuated and stabilized at 355-360 mL/g. The adsorptive capacity of uranium was increased as the initial uranium concentration increased, while it decreased as the soil particle size increased. The pH value played an important role in the U(VI) sorption onto soil, especially under alkaline conditions, and had a great effect on the sorption capacity of soil for uranium. Moreover, the presence of carbonate decreased the sorption of U(VI) onto soil because of the role of the strong complexation of carbonate with U(VI) in the groundwater. Overall, this study assessed the behavior of U(VI) sorption onto natural soil, which would be an important factor in the geological barrier of the repository, has contribution on mastering the characteristic of the adsorption of uranium in the particular soil media for the process of very low level radioactive waste disposal.http://www.doiserbia.nb.rs/img/doi/1451-3994/2016/1451-39941603268Z.pdfuraniumsoiladsorptioninfluencing factorbatch testvery low level radioactive waste
spellingShingle Zuo Rui
Liu Li
Jiang Xiaoyan
Guan Xin
Teng Yanguo
Ding Fei
Yang Jie
Wang Jinsheng
Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China
Nuclear Technology and Radiation Protection
uranium
soil
adsorption
influencing factor
batch test
very low level radioactive waste
title Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China
title_full Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China
title_fullStr Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China
title_full_unstemmed Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China
title_short Factors influencing U(VI) adsorption onto soil from a candidate very low level radioactive waste disposal site in China
title_sort factors influencing u vi adsorption onto soil from a candidate very low level radioactive waste disposal site in china
topic uranium
soil
adsorption
influencing factor
batch test
very low level radioactive waste
url http://www.doiserbia.nb.rs/img/doi/1451-3994/2016/1451-39941603268Z.pdf
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