Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs

Among solution-processable techniques, inkjet printing is a potential method for manufacturing low-cost and high-resolution polymer organic light-emitting diodes (PLEDs) for displays/solid-state lighting applications. Herein, we demonstrate use of the inkjet printed cesium carbonate (Cs<sub>2&...

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Main Authors: Amruth C, Beata Luszczynska, Wassima Rekab, Marek Zdzislaw Szymanski, Jacek Ulanski
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/13/1/80
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author Amruth C
Beata Luszczynska
Wassima Rekab
Marek Zdzislaw Szymanski
Jacek Ulanski
author_facet Amruth C
Beata Luszczynska
Wassima Rekab
Marek Zdzislaw Szymanski
Jacek Ulanski
author_sort Amruth C
collection DOAJ
description Among solution-processable techniques, inkjet printing is a potential method for manufacturing low-cost and high-resolution polymer organic light-emitting diodes (PLEDs) for displays/solid-state lighting applications. Herein, we demonstrate use of the inkjet printed cesium carbonate (Cs<sub>2</sub>CO<sub>3</sub>) film as an electron injection interlayer. We have elaborated the Cs<sub>2</sub>CO<sub>3</sub> ink using an alcohol-based solvent for the industrial-grade printhead. The printed Cs<sub>2</sub>CO<sub>3</sub> layer morphology was investigated by means of an optical microscope and an atomic force microscope. The PLEDs based on emissive polymer (Super Yellow) with printed Cs<sub>2</sub>CO<sub>3</sub> interlayer show a remarkable current efficiency and luminance compared to the PLEDs made without the Cs<sub>2</sub>CO<sub>3</sub> layer. Such results suggest that the Cs<sub>2</sub>CO<sub>3</sub> is a promising material for the formulation of the electron injecting inkjet inks. The possibility of inkjet printing of an efficient electron injecting layer enables in situ patterning of PLEDs’ emission area. Such a simple and flexible technique can be applied for a wide range of applications such as signage, pictograms, advertising, smart packaging, etc.
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spelling doaj.art-bffad4d5cf75465e95465a72b843572e2023-11-21T02:46:55ZengMDPI AGPolymers2073-43602020-12-011318010.3390/polym13010080Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDsAmruth C0Beata Luszczynska1Wassima Rekab2Marek Zdzislaw Szymanski3Jacek Ulanski4Department of Molecular Physics, Faculty of Chemistry, Lodz University of Technology, 90-924 Lodz, PolandDepartment of Molecular Physics, Faculty of Chemistry, Lodz University of Technology, 90-924 Lodz, PolandDepartment of Molecular Physics, Faculty of Chemistry, Lodz University of Technology, 90-924 Lodz, PolandDepartment of Molecular Physics, Faculty of Chemistry, Lodz University of Technology, 90-924 Lodz, PolandDepartment of Molecular Physics, Faculty of Chemistry, Lodz University of Technology, 90-924 Lodz, PolandAmong solution-processable techniques, inkjet printing is a potential method for manufacturing low-cost and high-resolution polymer organic light-emitting diodes (PLEDs) for displays/solid-state lighting applications. Herein, we demonstrate use of the inkjet printed cesium carbonate (Cs<sub>2</sub>CO<sub>3</sub>) film as an electron injection interlayer. We have elaborated the Cs<sub>2</sub>CO<sub>3</sub> ink using an alcohol-based solvent for the industrial-grade printhead. The printed Cs<sub>2</sub>CO<sub>3</sub> layer morphology was investigated by means of an optical microscope and an atomic force microscope. The PLEDs based on emissive polymer (Super Yellow) with printed Cs<sub>2</sub>CO<sub>3</sub> interlayer show a remarkable current efficiency and luminance compared to the PLEDs made without the Cs<sub>2</sub>CO<sub>3</sub> layer. Such results suggest that the Cs<sub>2</sub>CO<sub>3</sub> is a promising material for the formulation of the electron injecting inkjet inks. The possibility of inkjet printing of an efficient electron injecting layer enables in situ patterning of PLEDs’ emission area. Such a simple and flexible technique can be applied for a wide range of applications such as signage, pictograms, advertising, smart packaging, etc.https://www.mdpi.com/2073-4360/13/1/80printed PLEDsinkjet printingcesium carbonateinterlayeremission area patterningprinted/organic/flexible electronics
spellingShingle Amruth C
Beata Luszczynska
Wassima Rekab
Marek Zdzislaw Szymanski
Jacek Ulanski
Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs
Polymers
printed PLEDs
inkjet printing
cesium carbonate
interlayer
emission area patterning
printed/organic/flexible electronics
title Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs
title_full Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs
title_fullStr Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs
title_full_unstemmed Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs
title_short Inkjet Printing of an Electron Injection Layer: New Role of Cesium Carbonate Interlayer in Polymer OLEDs
title_sort inkjet printing of an electron injection layer new role of cesium carbonate interlayer in polymer oleds
topic printed PLEDs
inkjet printing
cesium carbonate
interlayer
emission area patterning
printed/organic/flexible electronics
url https://www.mdpi.com/2073-4360/13/1/80
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AT wassimarekab inkjetprintingofanelectroninjectionlayernewroleofcesiumcarbonateinterlayerinpolymeroleds
AT marekzdzislawszymanski inkjetprintingofanelectroninjectionlayernewroleofcesiumcarbonateinterlayerinpolymeroleds
AT jacekulanski inkjetprintingofanelectroninjectionlayernewroleofcesiumcarbonateinterlayerinpolymeroleds