Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3
Electron magnetic resonance (EMR) spectra of gadolinium-doped barium titanate (BaTiO3) have been studied at room temperature for gadolinium concentrations between 0.20 and 2.00 mol%. The results suggest that the Gd3+ ions occupy substitutional sites, replacing the Ba2+ ion, that the electron magneti...
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| Format: | Article |
| Language: | English |
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Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)
2015-04-01
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| Series: | Materials Research |
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| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000200288&tlng=en |
| _version_ | 1798020820858044416 |
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| author | Ronaldo Sergio de Biasi Maria Lúcia Netto Grillo |
| author_facet | Ronaldo Sergio de Biasi Maria Lúcia Netto Grillo |
| author_sort | Ronaldo Sergio de Biasi |
| collection | DOAJ |
| description | Electron magnetic resonance (EMR) spectra of gadolinium-doped barium titanate (BaTiO3) have been studied at room temperature for gadolinium concentrations between 0.20 and 2.00 mol%. The results suggest that the Gd3+ ions occupy substitutional sites, replacing the Ba2+ ion, that the electron magnetic resonance linewidth increases with increasing gadolinium concentration, and that the range of the exchange interaction between Gd3+ ions is about 0.98 nm, of the same order as that of the same ion in other host lattices, such as strontium titanate (SrTiO3), strontia (SrO), quicklime (CaO), magnesia (MgO) and zircon (ZrSiO4). The fact that the electron magnetic resonance linewidth of the Gd3+ ion increases, regularly and predictably, with Gd concentration, shows that the Gd3+ ion can be used as a probe to study, rapidly and non-destructively, the crystallinity and degradation of BaTiO3. |
| first_indexed | 2024-04-11T17:03:57Z |
| format | Article |
| id | doaj.art-c0038875b0734ac79eb51ec539464872 |
| institution | Directory Open Access Journal |
| issn | 1516-1439 |
| language | English |
| last_indexed | 2024-04-11T17:03:57Z |
| publishDate | 2015-04-01 |
| publisher | Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
| record_format | Article |
| series | Materials Research |
| spelling | doaj.art-c0038875b0734ac79eb51ec5394648722022-12-22T04:13:06ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392015-04-0118228829110.1590/1516-1439.298214Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3Ronaldo Sergio de BiasiMaria Lúcia Netto GrilloElectron magnetic resonance (EMR) spectra of gadolinium-doped barium titanate (BaTiO3) have been studied at room temperature for gadolinium concentrations between 0.20 and 2.00 mol%. The results suggest that the Gd3+ ions occupy substitutional sites, replacing the Ba2+ ion, that the electron magnetic resonance linewidth increases with increasing gadolinium concentration, and that the range of the exchange interaction between Gd3+ ions is about 0.98 nm, of the same order as that of the same ion in other host lattices, such as strontium titanate (SrTiO3), strontia (SrO), quicklime (CaO), magnesia (MgO) and zircon (ZrSiO4). The fact that the electron magnetic resonance linewidth of the Gd3+ ion increases, regularly and predictably, with Gd concentration, shows that the Gd3+ ion can be used as a probe to study, rapidly and non-destructively, the crystallinity and degradation of BaTiO3.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000200288&tlng=enceramicselectron magnetic resonancebarium titanategadolinium |
| spellingShingle | Ronaldo Sergio de Biasi Maria Lúcia Netto Grillo Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3 Materials Research ceramics electron magnetic resonance barium titanate gadolinium |
| title | Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3 |
| title_full | Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3 |
| title_fullStr | Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3 |
| title_full_unstemmed | Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3 |
| title_short | Electron Magnetic Resonance of Diluted Solid Solutions of Gd3+ in BaTiO3 |
| title_sort | electron magnetic resonance of diluted solid solutions of gd3 in batio3 |
| topic | ceramics electron magnetic resonance barium titanate gadolinium |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392015000200288&tlng=en |
| work_keys_str_mv | AT ronaldosergiodebiasi electronmagneticresonanceofdilutedsolidsolutionsofgd3inbatio3 AT marialucianettogrillo electronmagneticresonanceofdilutedsolidsolutionsofgd3inbatio3 |