Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery
NiMn<sub>2</sub>O<sub>4</sub> (NMO) is a good alternative anode material for lithium-ion battery (LIB) application, due to its superior electrochemical activity. Current research shows that synthesis of NMO via citric acid-based combustion method envisaged application in the...
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MDPI AG
2021-03-01
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| Series: | Journal of Composites Science |
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| Online Access: | https://www.mdpi.com/2504-477X/5/3/69 |
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| author | Swapnil J. Rajoba Rajendra D. Kale Sachin B. Kulkarni Vinayak G. Parale Rohan Patil Håkan Olin Hyung-Ho Park Rushikesh P. Dhavale Manisha Phadatare |
| author_facet | Swapnil J. Rajoba Rajendra D. Kale Sachin B. Kulkarni Vinayak G. Parale Rohan Patil Håkan Olin Hyung-Ho Park Rushikesh P. Dhavale Manisha Phadatare |
| author_sort | Swapnil J. Rajoba |
| collection | DOAJ |
| description | NiMn<sub>2</sub>O<sub>4</sub> (NMO) is a good alternative anode material for lithium-ion battery (LIB) application, due to its superior electrochemical activity. Current research shows that synthesis of NMO via citric acid-based combustion method envisaged application in the LIB, due to its good reversibility and rate performance. Phase purity and crystallinity of the material is controlled by calcination at different temperatures, and its structural properties are investigated by X-ray diffraction (XRD). Composition and oxidation state of NMO are further investigated by X-ray photoelectron spectroscopy (XPS). For LIB application, lithiation delithiation potential and phase transformation of NMO are studied by cyclic voltammetry curve. As an anode material, initially, the average discharge capacity delivered by NMO is 983 mA·h/g at 0.1 A/g. In addition, the NMO electrode delivers an average discharge capacity of 223 mA·h/g after cell cycled at various current densities up to 10 A/g. These results show the potential applications of NMO electrodes for LIBs. |
| first_indexed | 2024-03-09T05:38:00Z |
| format | Article |
| id | doaj.art-c0333ec0c3484a71bfc37bca9336eebc |
| institution | Directory Open Access Journal |
| issn | 2504-477X |
| language | English |
| last_indexed | 2024-03-09T05:38:00Z |
| publishDate | 2021-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Journal of Composites Science |
| spelling | doaj.art-c0333ec0c3484a71bfc37bca9336eebc2023-12-03T12:27:37ZengMDPI AGJournal of Composites Science2504-477X2021-03-01536910.3390/jcs5030069Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion BatterySwapnil J. Rajoba0Rajendra D. Kale1Sachin B. Kulkarni2Vinayak G. Parale3Rohan Patil4Håkan Olin5Hyung-Ho Park6Rushikesh P. Dhavale7Manisha Phadatare8Post Graduate Research Centre, Department of Physics, Tuljaram Chaturchand, College, Baramati 413 102, IndiaPost Graduate Research Centre, Department of Physics, Tuljaram Chaturchand, College, Baramati 413 102, IndiaPost Graduate Research Centre, Department of Physics, Tuljaram Chaturchand, College, Baramati 413 102, IndiaDepartment of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, KoreaDepartment of Natural Sciences, Mid Sweden University, 851 10 Sundsvall, SwedenDepartment of Natural Sciences, Mid Sweden University, 851 10 Sundsvall, SwedenDepartment of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, KoreaDepartment of Materials Science and Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, KoreaDepartment of Natural Sciences, Mid Sweden University, 851 10 Sundsvall, SwedenNiMn<sub>2</sub>O<sub>4</sub> (NMO) is a good alternative anode material for lithium-ion battery (LIB) application, due to its superior electrochemical activity. Current research shows that synthesis of NMO via citric acid-based combustion method envisaged application in the LIB, due to its good reversibility and rate performance. Phase purity and crystallinity of the material is controlled by calcination at different temperatures, and its structural properties are investigated by X-ray diffraction (XRD). Composition and oxidation state of NMO are further investigated by X-ray photoelectron spectroscopy (XPS). For LIB application, lithiation delithiation potential and phase transformation of NMO are studied by cyclic voltammetry curve. As an anode material, initially, the average discharge capacity delivered by NMO is 983 mA·h/g at 0.1 A/g. In addition, the NMO electrode delivers an average discharge capacity of 223 mA·h/g after cell cycled at various current densities up to 10 A/g. These results show the potential applications of NMO electrodes for LIBs.https://www.mdpi.com/2504-477X/5/3/69energy storage and conversionNiMn<sub>2</sub>O<sub>4</sub>XPSlithium-ion batteryelectrochemical performance |
| spellingShingle | Swapnil J. Rajoba Rajendra D. Kale Sachin B. Kulkarni Vinayak G. Parale Rohan Patil Håkan Olin Hyung-Ho Park Rushikesh P. Dhavale Manisha Phadatare Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery Journal of Composites Science energy storage and conversion NiMn<sub>2</sub>O<sub>4</sub> XPS lithium-ion battery electrochemical performance |
| title | Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery |
| title_full | Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery |
| title_fullStr | Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery |
| title_full_unstemmed | Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery |
| title_short | Synthesis and Electrochemical Performance of Mesoporous NiMn<sub>2</sub>O<sub>4</sub> Nanoparticles as an Anode for Lithium-Ion Battery |
| title_sort | synthesis and electrochemical performance of mesoporous nimn sub 2 sub o sub 4 sub nanoparticles as an anode for lithium ion battery |
| topic | energy storage and conversion NiMn<sub>2</sub>O<sub>4</sub> XPS lithium-ion battery electrochemical performance |
| url | https://www.mdpi.com/2504-477X/5/3/69 |
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