Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3

The efficiency of LaFeO3 and Cu-doped LaFeO3 nanopowders in the photocatalytic degradation of ibuprofen (IBP) has been investigated. Aqueous solutions of IBP were irradiated under visible-light in the presence of the catalyst and H2O2. The experiments were carried out on aqueous suspensions containi...

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Main Authors: Renato Pelosato, Veronica Carrara, Isabella Natali Sora
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2019-04-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/9641
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author Renato Pelosato
Veronica Carrara
Isabella Natali Sora
author_facet Renato Pelosato
Veronica Carrara
Isabella Natali Sora
author_sort Renato Pelosato
collection DOAJ
description The efficiency of LaFeO3 and Cu-doped LaFeO3 nanopowders in the photocatalytic degradation of ibuprofen (IBP) has been investigated. Aqueous solutions of IBP were irradiated under visible-light in the presence of the catalyst and H2O2. The experiments were carried out on aqueous suspensions containing 5.0 x 10-5 M of IBP, 0.003 M of H2O2, 0.130 g L-1 (5.0 x 10-4 M) of catalyst. The composition of the reaction solution was monitored during the experiments by UV-Vis spectroscopy and HPLC. The results showed a higher photocatalytic activity of Cu-doped LaFeO3 (5 and 10 mol%) compared to pure LaFeO3. The concentration of 4-isobutylacetophenone (4-IBAP), an harmful by-product of the degradation of IBP was the lowest when using 5 mol% Cu-doped LaFeO3 catalyst, i.e. ( 2 % and
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spelling doaj.art-c063218318074503acf982d6ebb5c75c2022-12-21T21:03:21ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162019-04-017310.3303/CET1973031Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3Renato PelosatoVeronica CarraraIsabella Natali SoraThe efficiency of LaFeO3 and Cu-doped LaFeO3 nanopowders in the photocatalytic degradation of ibuprofen (IBP) has been investigated. Aqueous solutions of IBP were irradiated under visible-light in the presence of the catalyst and H2O2. The experiments were carried out on aqueous suspensions containing 5.0 x 10-5 M of IBP, 0.003 M of H2O2, 0.130 g L-1 (5.0 x 10-4 M) of catalyst. The composition of the reaction solution was monitored during the experiments by UV-Vis spectroscopy and HPLC. The results showed a higher photocatalytic activity of Cu-doped LaFeO3 (5 and 10 mol%) compared to pure LaFeO3. The concentration of 4-isobutylacetophenone (4-IBAP), an harmful by-product of the degradation of IBP was the lowest when using 5 mol% Cu-doped LaFeO3 catalyst, i.e. ( 2 % andhttps://www.cetjournal.it/index.php/cet/article/view/9641
spellingShingle Renato Pelosato
Veronica Carrara
Isabella Natali Sora
Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3
Chemical Engineering Transactions
title Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3
title_full Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3
title_fullStr Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3
title_full_unstemmed Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3
title_short Enhanced Photocatalytic Degradation of Ibuprofen in Aqueous Solution Under Visible-light Irradiation: Effects of Lafeo3 and Cu/lafeo3
title_sort enhanced photocatalytic degradation of ibuprofen in aqueous solution under visible light irradiation effects of lafeo3 and cu lafeo3
url https://www.cetjournal.it/index.php/cet/article/view/9641
work_keys_str_mv AT renatopelosato enhancedphotocatalyticdegradationofibuprofeninaqueoussolutionundervisiblelightirradiationeffectsoflafeo3andculafeo3
AT veronicacarrara enhancedphotocatalyticdegradationofibuprofeninaqueoussolutionundervisiblelightirradiationeffectsoflafeo3andculafeo3
AT isabellanatalisora enhancedphotocatalyticdegradationofibuprofeninaqueoussolutionundervisiblelightirradiationeffectsoflafeo3andculafeo3