Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
The Co<sub>3</sub>O<sub>4</sub> is a typical p-type metal oxide semiconductor (MOS) that attracted great attention for hydrogen detection. In this work, porous, urchin-like Co<sub>3</sub>O<sub>4</sub> was synthesized using a hydrothermal method with th...
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author | Xin Deng Xiao Zhang Xiaochuan Long Xiaopeng Liu |
author_facet | Xin Deng Xiao Zhang Xiaochuan Long Xiaopeng Liu |
author_sort | Xin Deng |
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description | The Co<sub>3</sub>O<sub>4</sub> is a typical p-type metal oxide semiconductor (MOS) that attracted great attention for hydrogen detection. In this work, porous, urchin-like Co<sub>3</sub>O<sub>4</sub> was synthesized using a hydrothermal method with the assistance of glucose and a subsequent calcination process. Urchin-like Co<sub>3</sub>O<sub>4</sub> has a large specific surface area of 81.4 m<sup>2</sup>/g. The response value of urchin-like Co<sub>3</sub>O<sub>4</sub> to 200 ppm hydrogen at 200 °C is 36.5 (R<sub>g</sub>/R<sub>a</sub>), while the low-detection limit is as low as 100 ppb. The obtained Co<sub>3</sub>O<sub>4</sub> also exhibited good reproducibility, long-term stability, and selectivity towards various gases (e.g., ammonia, hydrogen, carbon monoxide, and methane). Porous, urchin-like Co<sub>3</sub>O<sub>4</sub> is expected to become a potential candidate for low-concentration hydrogen-sensing materials with the above advantages. |
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spelling | doaj.art-c066ca9141e149989f7824f2fbb32cdb2024-03-27T13:52:38ZengMDPI AGMaterials1996-19442024-03-01176136410.3390/ma17061364Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing MaterialsXin Deng0Xiao Zhang1Xiaochuan Long2Xiaopeng Liu3State Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaThe Co<sub>3</sub>O<sub>4</sub> is a typical p-type metal oxide semiconductor (MOS) that attracted great attention for hydrogen detection. In this work, porous, urchin-like Co<sub>3</sub>O<sub>4</sub> was synthesized using a hydrothermal method with the assistance of glucose and a subsequent calcination process. Urchin-like Co<sub>3</sub>O<sub>4</sub> has a large specific surface area of 81.4 m<sup>2</sup>/g. The response value of urchin-like Co<sub>3</sub>O<sub>4</sub> to 200 ppm hydrogen at 200 °C is 36.5 (R<sub>g</sub>/R<sub>a</sub>), while the low-detection limit is as low as 100 ppb. The obtained Co<sub>3</sub>O<sub>4</sub> also exhibited good reproducibility, long-term stability, and selectivity towards various gases (e.g., ammonia, hydrogen, carbon monoxide, and methane). Porous, urchin-like Co<sub>3</sub>O<sub>4</sub> is expected to become a potential candidate for low-concentration hydrogen-sensing materials with the above advantages.https://www.mdpi.com/1996-1944/17/6/1364Co<sub>3</sub>O<sub>4</sub>urchin-likeglucosehydrogengas sensing |
spellingShingle | Xin Deng Xiao Zhang Xiaochuan Long Xiaopeng Liu Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials Materials Co<sub>3</sub>O<sub>4</sub> urchin-like glucose hydrogen gas sensing |
title | Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials |
title_full | Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials |
title_fullStr | Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials |
title_full_unstemmed | Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials |
title_short | Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials |
title_sort | glucose assisted synthesis of porous urchin like co sub 3 sub o sub 4 sub hierarchical structures for low concentration hydrogen sensing materials |
topic | Co<sub>3</sub>O<sub>4</sub> urchin-like glucose hydrogen gas sensing |
url | https://www.mdpi.com/1996-1944/17/6/1364 |
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