Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials

The Co<sub>3</sub>O<sub>4</sub> is a typical p-type metal oxide semiconductor (MOS) that attracted great attention for hydrogen detection. In this work, porous, urchin-like Co<sub>3</sub>O<sub>4</sub> was synthesized using a hydrothermal method with th...

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Main Authors: Xin Deng, Xiao Zhang, Xiaochuan Long, Xiaopeng Liu
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Materials
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Online Access:https://www.mdpi.com/1996-1944/17/6/1364
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author Xin Deng
Xiao Zhang
Xiaochuan Long
Xiaopeng Liu
author_facet Xin Deng
Xiao Zhang
Xiaochuan Long
Xiaopeng Liu
author_sort Xin Deng
collection DOAJ
description The Co<sub>3</sub>O<sub>4</sub> is a typical p-type metal oxide semiconductor (MOS) that attracted great attention for hydrogen detection. In this work, porous, urchin-like Co<sub>3</sub>O<sub>4</sub> was synthesized using a hydrothermal method with the assistance of glucose and a subsequent calcination process. Urchin-like Co<sub>3</sub>O<sub>4</sub> has a large specific surface area of 81.4 m<sup>2</sup>/g. The response value of urchin-like Co<sub>3</sub>O<sub>4</sub> to 200 ppm hydrogen at 200 °C is 36.5 (R<sub>g</sub>/R<sub>a</sub>), while the low-detection limit is as low as 100 ppb. The obtained Co<sub>3</sub>O<sub>4</sub> also exhibited good reproducibility, long-term stability, and selectivity towards various gases (e.g., ammonia, hydrogen, carbon monoxide, and methane). Porous, urchin-like Co<sub>3</sub>O<sub>4</sub> is expected to become a potential candidate for low-concentration hydrogen-sensing materials with the above advantages.
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spelling doaj.art-c066ca9141e149989f7824f2fbb32cdb2024-03-27T13:52:38ZengMDPI AGMaterials1996-19442024-03-01176136410.3390/ma17061364Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing MaterialsXin Deng0Xiao Zhang1Xiaochuan Long2Xiaopeng Liu3State Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Advanced Materials for Smart Sensing, China GRINM Group Co., Ltd., Beijing 100088, ChinaThe Co<sub>3</sub>O<sub>4</sub> is a typical p-type metal oxide semiconductor (MOS) that attracted great attention for hydrogen detection. In this work, porous, urchin-like Co<sub>3</sub>O<sub>4</sub> was synthesized using a hydrothermal method with the assistance of glucose and a subsequent calcination process. Urchin-like Co<sub>3</sub>O<sub>4</sub> has a large specific surface area of 81.4 m<sup>2</sup>/g. The response value of urchin-like Co<sub>3</sub>O<sub>4</sub> to 200 ppm hydrogen at 200 °C is 36.5 (R<sub>g</sub>/R<sub>a</sub>), while the low-detection limit is as low as 100 ppb. The obtained Co<sub>3</sub>O<sub>4</sub> also exhibited good reproducibility, long-term stability, and selectivity towards various gases (e.g., ammonia, hydrogen, carbon monoxide, and methane). Porous, urchin-like Co<sub>3</sub>O<sub>4</sub> is expected to become a potential candidate for low-concentration hydrogen-sensing materials with the above advantages.https://www.mdpi.com/1996-1944/17/6/1364Co<sub>3</sub>O<sub>4</sub>urchin-likeglucosehydrogengas sensing
spellingShingle Xin Deng
Xiao Zhang
Xiaochuan Long
Xiaopeng Liu
Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
Materials
Co<sub>3</sub>O<sub>4</sub>
urchin-like
glucose
hydrogen
gas sensing
title Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
title_full Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
title_fullStr Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
title_full_unstemmed Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
title_short Glucose-Assisted Synthesis of Porous, Urchin-like Co<sub>3</sub>O<sub>4</sub> Hierarchical Structures for Low-Concentration Hydrogen Sensing Materials
title_sort glucose assisted synthesis of porous urchin like co sub 3 sub o sub 4 sub hierarchical structures for low concentration hydrogen sensing materials
topic Co<sub>3</sub>O<sub>4</sub>
urchin-like
glucose
hydrogen
gas sensing
url https://www.mdpi.com/1996-1944/17/6/1364
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AT xiaochuanlong glucoseassistedsynthesisofporousurchinlikecosub3subosub4subhierarchicalstructuresforlowconcentrationhydrogensensingmaterials
AT xiaopengliu glucoseassistedsynthesisofporousurchinlikecosub3subosub4subhierarchicalstructuresforlowconcentrationhydrogensensingmaterials