CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n
The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n wit...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020-07-01
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| Series: | Journal of Engineering Studies and Research |
| Subjects: | |
| Online Access: | https://jesr.ub.ro/1/article/view/226 |
| _version_ | 1797202276038737920 |
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| author | MODOU SARR MOUHAMADOU BIRAME DIOP AMINATA DIASSE-SARR AI WANG ULLRICH ENGLERT |
| author_facet | MODOU SARR MOUHAMADOU BIRAME DIOP AMINATA DIASSE-SARR AI WANG ULLRICH ENGLERT |
| author_sort | MODOU SARR |
| collection | DOAJ |
| description |
The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement.
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| first_indexed | 2024-03-07T17:28:30Z |
| format | Article |
| id | doaj.art-c07b2735f1b74ea5a7d979367115492a |
| institution | Directory Open Access Journal |
| issn | 2068-7559 2344-4932 |
| language | English |
| last_indexed | 2024-04-24T08:00:52Z |
| publishDate | 2020-07-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj.art-c07b2735f1b74ea5a7d979367115492a2024-04-17T19:34:55ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322020-07-01263CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)nMODOU SARRMOUHAMADOU BIRAME DIOPAMINATA DIASSE-SARRAI WANGULLRICH ENGLERT The title polymer [HCO2Sn(C6H5)3]n was isolated by serendipitous from reaction in ethanol 96 % between bis-(monocyclohexyl ammonium) 2-carboxyethyl hydrogen phosphonate, {(CyNH3)2[CO2CH2CH2PO2(OH)]} and triphenyltin chloride, SnPh3Cl. The polymer crystallizes in the monoclinic space group P21/n with Z = 4, a = 14.7091 (18) Å, b = 15.4133 (19) Å, c = 14.7639 (18) Å, β = 94.242 (2)° and V = 3338.0 (7) Å3. The structure consists of an infinite chain propagating along the crystallographic a-axis direction with bidentate formate anions. The O2SnC3 core is organized into a trans-trigonal bipyramidal like-arrangement. https://jesr.ub.ro/1/article/view/226infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin |
| spellingShingle | MODOU SARR MOUHAMADOU BIRAME DIOP AMINATA DIASSE-SARR AI WANG ULLRICH ENGLERT CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n Journal of Engineering Studies and Research infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin |
| title | CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n |
| title_full | CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n |
| title_fullStr | CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n |
| title_full_unstemmed | CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n |
| title_short | CRYSTAL STRUCTURE OF TRIPHENYLTIN (IV) FORMATE POLYMER, (HCO2SnPh3)n |
| title_sort | crystal structure of triphenyltin iv formate polymer hco2snph3 n |
| topic | infinite chain, trans-trigonal bipyramidal, bidentate formate anions, triphenyltin |
| url | https://jesr.ub.ro/1/article/view/226 |
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