Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS

Volatile compounds in flowers of <i>Rhododendron delavayi</i>, <i>R. agastum</i>, <i>R. annae</i>, and <i>R. irroratum</i> were analyzed using comprehensive two-dimensional gas chromatography-mass spectrometry (GC&#215;GC) coupled with high-resolut...

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Main Authors: Chen-Yu Qian, Wen-Xuan Quan, Zhang-Min Xiang, Chao-Chan Li
Format: Article
Language:English
Published: MDPI AG 2019-09-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/24/18/3327
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author Chen-Yu Qian
Wen-Xuan Quan
Zhang-Min Xiang
Chao-Chan Li
author_facet Chen-Yu Qian
Wen-Xuan Quan
Zhang-Min Xiang
Chao-Chan Li
author_sort Chen-Yu Qian
collection DOAJ
description Volatile compounds in flowers of <i>Rhododendron delavayi</i>, <i>R. agastum</i>, <i>R. annae</i>, and <i>R. irroratum</i> were analyzed using comprehensive two-dimensional gas chromatography-mass spectrometry (GC&#215;GC) coupled with high-resolution quadrupole time-of-flight mass spectrometry (QTOFMS). A significantly increased number of compounds was separated by GC&#215;GC compared to conventional one-dimensional GC (1DGC), allowing more comprehensive understanding of the volatile composition of <i>Rhododendron</i> flowers. In total, 129 volatile compounds were detected and quantified. Among them, hexanal, limonene, benzeneacetaldehyde, 2-nonen-1-ol, phenylethyl alcohol, citronellal, isopulegol, 3,5-dimethoxytoluene, and pyridine are the main compounds with different content levels in all flower samples. 1,2,3-trimethoxy-5-methyl-benzene exhibits significantly higher content in <i>R. irroratum</i> compared to in the other three species, while isopulegol is only found in <i>R. irroratum</i> and <i>R. agastum</i>.
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spelling doaj.art-c094a9c0ceef423bb73d3f5caf442fae2022-12-21T23:07:30ZengMDPI AGMolecules1420-30492019-09-012418332710.3390/molecules24183327molecules24183327Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMSChen-Yu Qian0Wen-Xuan Quan1Zhang-Min Xiang2Chao-Chan Li3Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals/Guangdong Engineering and Technology Research Center for Ambient Mass Spectrometry, Guangdong Institute of Analysis, Guangzhou 510070, ChinaGuizhou Provincial Key Laboratory of Mountainous Environmental Protection, Guizhou Normal University, Guiyang 550001, ChinaGuangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals/Guangdong Engineering and Technology Research Center for Ambient Mass Spectrometry, Guangdong Institute of Analysis, Guangzhou 510070, ChinaGuizhou Provincial Key Laboratory of Mountainous Environmental Protection, Guizhou Normal University, Guiyang 550001, ChinaVolatile compounds in flowers of <i>Rhododendron delavayi</i>, <i>R. agastum</i>, <i>R. annae</i>, and <i>R. irroratum</i> were analyzed using comprehensive two-dimensional gas chromatography-mass spectrometry (GC&#215;GC) coupled with high-resolution quadrupole time-of-flight mass spectrometry (QTOFMS). A significantly increased number of compounds was separated by GC&#215;GC compared to conventional one-dimensional GC (1DGC), allowing more comprehensive understanding of the volatile composition of <i>Rhododendron</i> flowers. In total, 129 volatile compounds were detected and quantified. Among them, hexanal, limonene, benzeneacetaldehyde, 2-nonen-1-ol, phenylethyl alcohol, citronellal, isopulegol, 3,5-dimethoxytoluene, and pyridine are the main compounds with different content levels in all flower samples. 1,2,3-trimethoxy-5-methyl-benzene exhibits significantly higher content in <i>R. irroratum</i> compared to in the other three species, while isopulegol is only found in <i>R. irroratum</i> and <i>R. agastum</i>.https://www.mdpi.com/1420-3049/24/18/3327<i>Rhododendron</i> flowersvolatile compoundscomprehensive two-dimensional gas chromatography-mass spectrometryquadrupole time-of-flight mass spectrometryodor description
spellingShingle Chen-Yu Qian
Wen-Xuan Quan
Zhang-Min Xiang
Chao-Chan Li
Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS
Molecules
<i>Rhododendron</i> flowers
volatile compounds
comprehensive two-dimensional gas chromatography-mass spectrometry
quadrupole time-of-flight mass spectrometry
odor description
title Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS
title_full Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS
title_fullStr Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS
title_full_unstemmed Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS
title_short Characterization of Volatile Compounds in Four Different <i>Rhododendron</i> Flowers by GC×GC-QTOFMS
title_sort characterization of volatile compounds in four different i rhododendron i flowers by gc gc qtofms
topic <i>Rhododendron</i> flowers
volatile compounds
comprehensive two-dimensional gas chromatography-mass spectrometry
quadrupole time-of-flight mass spectrometry
odor description
url https://www.mdpi.com/1420-3049/24/18/3327
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AT wenxuanquan characterizationofvolatilecompoundsinfourdifferentirhododendroniflowersbygcgcqtofms
AT zhangminxiang characterizationofvolatilecompoundsinfourdifferentirhododendroniflowersbygcgcqtofms
AT chaochanli characterizationofvolatilecompoundsinfourdifferentirhododendroniflowersbygcgcqtofms